Composition for removal of sulfur-containing compounds

Patent metadata

Field	Value
Publication number	US-10119079-B2
Application number	US-201515126191-A
Country	US
Kind code	B2
Filing date	Mar 11, 2015
Priority date	Mar 17, 2014
Publication date	Nov 6, 2018
Grant date	Nov 6, 2018

Abstract

Disclosed is a composition capable of removing safely and efficiently a sulfur-containing compound contained in a hydrocarbon, particularly hydrogen sulfide, an —SH group-containing compound, or a mixture thereof. Provided is a composition for removal of a sulfur-containing compound in a hydrocarbon, the sulfur-containing compound being hydrogen sulfide, an —SH group-containing compound or a mixture thereof: the composition containing a dialdehyde having 6 to 16 carbon atoms as an active ingredient.

First claim

The invention claimed is:

1. A method for removing a sulfur-containing compound in a hydrocarbon, the method comprising contacting the hydrocarbon with a composition consisting of 1) 1,9-nonanedial, 2-methyl-1,8-octanedial, or both; 2) optionally, a solvent selected from water, toluene, xylene, heavy aromatic naphtha, petroleum distillate, or a monoalcohol or diol having 1 to 10 carbon atoms; and 3) optionally, a nitrogen-containing compound selected from α-amino ether compounds, alkoxy-hexahydrotriazine compounds, alkyl-hexahydrotriazine compounds, hydroxyalkyl-hexahydrotriazine compounds, monoamine compounds, diamine compounds, reaction products between an alkylenepolyamine and formaldehyde, quaternary ammonium salt compounds, imine compounds, imidazoline compounds, hydroxyaminoalkyl ether compounds, morpholine compounds, pyrrolidone compounds, piperidone compounds, alkylpyridine compounds, 1H-hexahydroazepine, polyvalent metal chelate compounds of an aminocarboxylic acid, polyethyleneimine, polyallylamine, polyvinylamine, amino carbinol compounds, aminal compounds, and bisoxazolidine compounds, wherein the sulfur-containing compound is hydrogen sulfide, an —SH group-containing compound, or a mixture thereof.

2. The method according to claim 1 , comprising further contacting the hydrocarbon with a nitrogen-containing compound.

3. The method according to claim 1 , wherein the hydrocarbon is one or more selected from the group consisting of natural gas, liquefied natural gas, sour gas, crude oil, naphtha, heavy aromatic naphtha, gasoline, kerosene, diesel oil, light oil, heavy oil, FCC slurry, asphalt, and an oil field concentrate.

4. The method according to claim 1 , wherein an amount of the composition is from 1 to 10,000 ppm relative to a mass of the hydrocarbon.

5. The method according to claim 1 , wherein the composition and the hydrocarbon are brought into contact with each other at a temperature of from 20° C. to 200° C.

6. A method for removing a sulfur-containing compound in a hydrocarbon, the method comprising contacting the hydrocarbon with a composition consisting of 1) 3-methylglutaraldehyde; 2) optionally, a solvent selected from water, toluene, xylene, heavy aromatic naphtha, petroleum distillate, or a monoalcohol or diol having 1 to 10 carbon atoms; and 3) optionally, a nitrogen-containing compound selected from α-amino ether compounds, alkoxy-hexahydrotriazine compounds, alkyl-hexahydrotriazine compounds, hydroxyalkyl-hexahydrotriazine compounds, monoamine compounds, diamine compounds, reaction products between an alkylenepolyamine and formaldehyde, and quaternary ammonium salt compounds, imine compounds, imidazoline compounds, hydroxyaminoalkyl ether compounds, morpholine compounds, pyrrolidone compounds, piperidone compounds, alkylpyridine compounds, 1H-hexahydroazepine, polyvalent metal chelate compounds of an aminocarboxylic acid, polyethyleneimine, polyallylamine, polyvinylamine, amino carbinol compounds, aminal compounds, and bisoxazolidine compounds, wherein the sulfur-containing compound is hydrogen sulfide, an SH group-containing compound, or a mixture thereof.

7. The method according to claim 6 , comprising further contacting the hydrocarbon with a nitrogen-containing compound.

8. The method according to claim 6 , wherein the hydrocarbon is one or more selected from the group consisting of natural gas, liquefied natural gas, sour gas, crude oil, naphtha, heavy aromatic naphtha, gasoline, kerosene, diesel oil, light oil, heavy oil, FCC slurry, asphalt, and an oil field concentrate.

9. The method according to any of claim 6 , wherein an amount of the composition is from 1 to 10,000 ppm relative to a mass of the hydrocarbon.

10. The method according to any of claim 6 , wherein the composition and the hydrocarbon are brought into contact with each other at a temperature of from 20° C. to 200° C.

Assignees

• Kuraray Co

Inventors

• Fuji Junichi
• Miyazaki Ryoko
• Suzuki Takahiro

Classifications

• C10L3/103

  Sulfur containing contaminants · CPC title

• C10G29/24 Primary

  Aldehydes or ketones · CPC title

• C10G2300/202

  Heteroatoms content, i.e. S, N, O, P · CPC title

• C10G29/20

  Organic compounds not containing metal atoms · CPC title

• C23F11/122

  Alcohols; Aldehydes; Ketones · CPC title