Resin composition and molded article thereof

Patent metadata

Field	Value
Publication number	US-10119024-B2
Application number	US-201715673953-A
Country	US
Kind code	B2
Filing date	Aug 10, 2017
Priority date	Apr 14, 2015
Publication date	Nov 6, 2018
Grant date	Nov 6, 2018

Abstract

Disclosed is a resin composition including at least a polyamide (A) and a polyrotaxane (B) whose cyclic molecule is modified with a graft chain, which are mixed together, wherein 80 parts by weight or more and 99.9 parts by weight or less of the polyamide (A) and 0.1 part by weight or more and 20 parts by weight or less of the polyrotaxane (B) are mixed together relative to 100 parts by weight of the total amount of the polyamide (A) and the polyrotaxane (B). To provide a resin composition capable of affording a molded article having excellent balance between rigidity and toughness.

First claim

The invention claimed is:

1. A resin composition comprising a mixture of: (A) a polyamide and (B) a polyrotaxane, wherein the cyclic molecule of the polyrotaxane is modified with a graft chain, and wherein
80 parts by weight or more and 99.9 parts by weight or less of the polyamide (A) and 0.1 part by weight or more and 20 parts by weight or less of the polyrotaxane (B) are mixed together relative to 100 parts by weight of the total amount of the polyamide (A) and the polyrotaxane (B), and
the resin composition has an islands-in-sea structure composed of a sea phase including the polyamide (A) as a main component and an island phase including the polyrotaxane (B) as a main component, as well as a lakes-in-islands-in-sea structure with a lake phase including the polyamide (A) and/or a reaction product of the polyamide (A) and the polyrotaxane (B) as main component(s), the lake phase being disposed in the island phase.

2. The resin composition according to claim 1 , wherein the graft chain is a graft chain having at least one functional group selected from the group consisting of a carboxyl group, an isocyanate group, a glycidyl group, and an amino group at the end of the graft chain.

3. The resin composition according to claim 2 , wherein a concentration of functional group at the end of the graft chain of the polyrotaxane (B) is 2×10 −5 mol/g or more and 5×10 −4 mol/g or less.

4. The resin composition according to claim 1 , which contains 3 parts by weight or more and 25 parts by weight or less of a reaction product of the polyamide (A) and the polyrotaxane (B) relative to 100 parts by weight of the total amount of the polyamide (A) and the polyrotaxane (B).

5. The resin composition according to claim 1 , wherein the island phase has an average diameter of 10 μm or less.

6. A molded article comprising the resin composition according to claim 1 .

Assignees

• Toray Industries

Inventors

• Nomura Keiichiro
• Morioka Nobuhiro
• Kobayashi Sadayuki

Classifications

• C08L71/02

  Polyalkylene oxides · CPC title

• C08G83/007

  Polyrotaxanes; Polycatenanes · CPC title

• C08G81/00

  Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers (involving only carbon-to-carbon unsaturated bond reactions C08F299/00 {; polyester-amides C08G69/44; polyester-imides C08G73/16; polyamides-imides C08G73/14; block- or graft polymers containing polysiloxane sequences C08G77/42}) · CPC title

• C08L77/02 Primary

  Polyamides derived from omega-amino carboxylic acids or from lactams thereof (C08L77/10 takes precedence) · CPC title

• C08L51/08

  grafted on to macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds · CPC title