Polyvinyl acetate latex

Patent metadata

Field	Value
Publication number	US-10119018-B2
Application number	US-201615338530-A
Country	US
Kind code	B2
Filing date	Oct 31, 2016
Priority date	Nov 2, 2015
Publication date	Nov 6, 2018
Grant date	Nov 6, 2018

Abstract

The present invention relates to a process for preparing an aqueous dispersion of a vinyl acetate polymer comprising the step of polymerizing vinyl acetate under emulsion polymerization conditions in the presence of a chain transfer agent which is a hypophosphite salt or X—R 1 —SH, where R 1 is a C 1 -C 4 alkyl group and X is sulfonate, hydroxyl, sulfate, phosphate, phosphonate, carboxylic acid or a salt thereof, or C 1 -C 3 -alkyl carboxylate. The process provides a way of lowering the viscosity of the vinyl acetate polymer at a given solids content.

First claim

The invention claimed is:

1. A composition comprising vinyl acetate polymer particles dispersed in an aqueous phase, wherein the aqueous phase comprises, based on the weight of the aqueous phase 1) 0.01 to 1 weight percent of a chain transfer agent; and 2) 0.05 to 2.5 weight percent of a vinyl acetate oligomer comprising:
a) from 40 to 90 weight percent structural units of vinyl acetate,
b) from 5 to 40 weight percent structural units of butyl acrylate,
c) from 0.2 to 3 weight percent structural units of phosphoethyl methacrylate, and
d) from 0.1 to 3 weight percent, based on the weight of the aqueous phase, structural units of a sulfur acid monomer selected from the group consisting of 2-acrylamido-2-methylpropane sulfonic acid, a salt of 2-acrylamido-2-methylpropane sulfonic acid, and sodium vinyl sulfonate;
wherein the chain transfer agent is selected from the group consisting of sodium hypophosphite, potassium hypophosphite, mercaptoethanesulfonate, mercaptopropionic acid, a salt of mercaptopropionic acid, mercaptoethanol, and methyl mercaptoproprionate; and wherein the vinyl acetate oligomer has a weight average molecular weight (M w ) in the range of from 1000 to 7000 Daltons.

2. The composition of claim 1 , wherein the chain transfer agent is sodium hypophosphite or potassium hypophosphite, wherein the weight average molecular weight of the oligomer is from 2000 to 5500 Daltons.

3. The composition of claim 1 wherein the chain transfer agent is sodium hypophosphite at a concentration of from 0.02 to 0.5 weight percent, and the sulfur acid monomer is 2-acrylamido-2-methylpropane sulfonic acid or a salt of 2-acrylamido-2-methylpropane sulfonic acid.

4. The composition of claim 1 wherein the chain transfer agent is selected from the group consisting of mercaptoethanesulfonate, mercaptopropionic acid, a salt of mercaptopropionic acid, mercaptoethanol, and methyl mercaptoproprionate at a concentration of from 0.02 to 0.5 weight percent, and the sulfur acid monomer is 2-acrylamido-2-methylpropane sulfonic acid or a salt of 2-acrylamido-2-methylpropane sulfonic acid.

5. The composition of claim 4 , wherein the chain transfer agent is mercaptopropionic acid or a salt thereof, wherein the weight average molecular weight of the oligomer is from 2000 to 4000 Daltons.

6. The composition of claim 4 , wherein the chain transfer agent is mercaptoethane sulfonate, wherein the weight average molecular weight of the oligomer is from 2000 to 5500 Daltons.

7. The composition of claim 4 , wherein the chain transfer agent is mercaptoethanol, wherein the weight average molecular weight of the oligomer is from 2000 to 5500 Daltons.

Assignees

• Rohm & Haas

Inventors

• Beshah Kebede
• Bohling James C
• Luo Pu

Classifications

• C08L2205/025

  containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure · CPC title

• C09D131/04

  Homopolymers or copolymers of vinyl acetate · CPC title

• C08F230/02

  containing phosphorus · CPC title

• C08F18/08

  Vinyl acetate · CPC title

• C08L31/04 Primary

  Homopolymers or copolymers of vinyl acetate · CPC title