Flowability of polycarbonate compositions

Patent metadata

Field	Value
Publication number	US-10119009-B2
Application number	US-201515532207-A
Country	US
Kind code	B2
Filing date	Nov 26, 2015
Priority date	Dec 1, 2014
Publication date	Nov 6, 2018
Grant date	Nov 6, 2018

Abstract

The present invention relates to the use of diglycerol esters for enhancing the flowability of transparent polycarbonate compositions. Melt viscosities and melt volume flow rates are improved. In addition, the diglycerol esters also exert a positive effect on the optical properties by increasing the transmission of the compositions and reducing the yellowness index.

First claim

The invention claimed is:

1. A method comprising enhancing the flowability of a transparent polycarbonate composition comprising utilizing at least one diglycerol ester in combination with at least one phosphate, wherein the transparent polycarbonate composition exhibits a transmission, determined to ISO 13468 for a thickness of 4 mm, of at least 88% in the range from 400 nm to 800 nm.

2. The method according to claim 1 , wherein the diglycerol ester is an ester of formula (I)

where R═COC n H 2n+1 and/or R═COR′,
wherein n is an integer and R′ is a branched alkyl radical or a branched or unbranched alkenyl radical and C n H 2n+1 is an aliphatic, saturated linear alkyl radical.

3. The method according to claim 2 , wherein R═COC n H 2n+1 , wherein n is an integer of 6-24.

4. The method according to claim 1 , wherein after addition of the diglycerol ester and the phosphate the polycarbonate composition comprises
A) 20.0 wt % to 99.0 wt % of aromatic polycarbonate,
B) 0.01 wt % to 3.0 wt % of diglycerol ester and
C) 0.0 wt % to 1.0 wt % of heat stabilizer.

5. The method according to claim 1 , wherein after addition of the diglycerol ester and the phosphate the polycarbonate composition comprises the constituents:
A) 20.0 wt % to 99.0 wt % of aromatic polycarbonate,
B) 0.01 wt % to 3.0 wt % of diglycerol ester and
C) optionally up to 1.0 wt % of heat stabilizer and
D) optionally up to 10.0 wt % of one or more further additives from the group of antioxidants, UV absorbers, IR absorbers, antistatics, optical brighteners, light-scattering agents, colorants from the group of organic pigments, inorganic pigments, carbon black and/or dyes and the inorganic fillers titanium dioxide, barium sulphate and/or additives for laser marking and
D-2) 0.001 to 0.1 wt % of phosphate,
wherein the components A) to E), including D-2), sum to 100 wt %.

6. The method according to claim 4 , wherein the amount of the diglycerol ester is from 0.2 to 1.0 wt %.

7. The method according to claim 4 , wherein the amount of the diglycerol ester is from 0.3 to 0.6 wt %.

8. The method according to claim 1 , wherein the melt viscosity of the polycarbonate compositions determined to ISO 11443 is reduced by the diglycerol ester.

9. The method according to claim 1 , wherein the at least one phosphate is triisooctyl phosphate.

Assignees

• Covestro Deutschland Ag

Inventors

• Wehrmann Rolf
• Heuer Helmut Werner
• Boumans Anke

Classifications

• C08L69/00 Primary

  Compositions of polycarbonates; Compositions of derivatives of polycarbonates · CPC title

• C08K5/521

  Esters of phosphoric acids, e.g. of H3PO4 · CPC title

• C08L2205/025

  containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure · CPC title

• C08K5/103 Primary

  with polyalcohols · CPC title

• C08L2203/20

  use in electrical or conductive gadgets · CPC title