Golf balls incorporating HNP ionomers based on highly diverse mixtures of organic acids

Patent metadata

Field	Value
Publication number	US-10119008-B2
Application number	US-201615216751-A
Country	US
Kind code	B2
Filing date	Jul 22, 2016
Priority date	Dec 15, 2005
Publication date	Nov 6, 2018
Grant date	Nov 6, 2018

Abstract

Golf ball incorporating an HNP composition consisting of a mixture of: at least one ethylene acid copolymer; sufficient amount of cation source to neutralize greater than about 100% of all acid groups present; and a highly diverse mixture of at least four organic acids having different characteristics such as relating to: carbon chain lengths, number of double bonds on carbon chains, positioning of double bonds on carbon chains, number of branches, types of branches, positioning of branches on carbon chains, positioning of acid groups on carbon chains, configurations (cis/trans), functional groups on carbon chains, being saturated/unsaturated, being conjugated/non-conjugated; presence/absence of functional group(s) on carbon chain; being aliphatic/aromatic, or combinations thereof. No organic acid is present in highly diverse mixture in a concentration greater than 80%, or, in some embodiments, greater than 60%, or greater than 40%. HNP composition may be relatively soft/relatively low modulus, relatively hard/relatively high modulus, or blends thereof.

First claim

What is claimed is:

1. A golf ball having at least one layer comprising a highly neutralized acid polymer composition consisting of a mixture of:
at least one ethylene acid copolymer;
a sufficient amount of cation source to neutralize greater than about 100% of all acid groups present; and
a highly diverse mixture of at least 20 organic acids exhibiting the chromatogram of FIG. 1 .

2. The golf ball of claim 1 , wherein all organic acids of the highly diverse mixture are carboxylic acids.

3. The golf ball of claim 1 , wherein at least 90% of the organic acids of the highly diverse mixture are fatty acids.

4. The golf ball of claim 1 , wherein at least two organic acids of the highly diverse mixture have different carbon chain lengths.

5. The golf ball of claim 4 , wherein the carbon chain lengths differ by at least two carbon atoms.

6. The golf ball of claim 1 , wherein at least three organic acids of the highly diverse mixture have different carbon chain lengths.

7. The golf ball of claim 6 , wherein the carbon chain lengths differ by at least two carbon atoms.

8. The golf ball of claim 1 , wherein no single organic acid is present in the highly diverse mixture in a concentration greater than 40%.

9. The golf ball of claim 1 , wherein the highly diverse mixture contains saturated organic acids and unsaturated organic acids.

10. The golf balls of claim 9 , wherein one organic acid has a carbon chain having a different number of carbon-carbon double bonds than a carbon chain of at least one other organic acid.

11. The golf ball of claim 1 , wherein a first organic acid has a first carbon chain and a second organic acid has a second carbon chain having the same number of carbon-carbon double bonds as the first carbon chain; and wherein at least one carbon-carbon double bond position on the first carbon chain is not a carbon-carbon double bond position on the second carbon chain.

12. The golf ball of claim 10 , wherein at least one organic acid has a cis-type carbon-carbon double bond configuration and at least one other organic acid has a trans-type carbon-carbon double bond configuration.

13. The golf ball of claim 1 , wherein at least one organic acid has a carbon chain that is branched differently than a carbon chain of at least one other organic acid.

14. The golf ball of claim 13 , wherein one organic acid has a carbon chain having a different number of branches than a carbon chain of at least one other organic acid.

15. The golf ball of claim 1 , wherein a first organic acid has a first carbon chain and a second organic acid has a second carbon chain having the same number of branches as the first carbon chain; and wherein at least one branch position on the first carbon chain is not a branch position on the second carbon chain.

16. The golf ball of claim 1 , wherein at least two organic acids have different functional groups.

17. The golf ball of claim 16 , wherein one functional group is carboxylic acid.

18. The golf ball of claim 1 , wherein the highly diverse mixture comprises at least one aliphatic organic acid and at least one aromatic organic acid.

19. The golf ball of claim 1 , wherein the highly diverse mixture contains organic acids having two or more different characteristics.

20. The golf ball of claim 1 , wherein the highly diverse mixture contains organic acids having three or more different characteristics.

21. The golf ball of claim 1 , wherein the highly diverse mixture contains organic acids having four or more different characteristics.

22. The golf ball of claim 1 , wherein the highly diverse mixture contains organic acids having five or more different characteristics.

23. A golf ball having at least one layer comprising a highly neutralized acid polymer composition consisting of a mixture of:
at least one ethylene acid copolymer;
a sufficient amount of cation source to neutralize greater than about 100% of all acid groups present; and
a highly diverse mixture of at least 14 organic acids exhibiting the chromatogram of FIG. 2 .

24. A golf ball having at least one layer comprising a highly neutralized acid polymer composition consisting of a mixture of:
at least one ethylene acid copolymer;
a sufficient amount of cation source to neutralize greater than about 100% of all acid groups present; and
a highly diverse mixture of at least 15 organic acids exhibiting the chromatogram of FIG. 3 .

Assignees

• Acushnet Co

Inventors

• Bulpett David A
• Blink Robert
• Sullivan Michael J

Classifications

• A63B37/0043

  Hardness · CPC title

• C08K5/09 Primary

  Carboxylic acids; Metal salts thereof; Anhydrides thereof · CPC title

• A63B37/0092

  Hardness distribution amongst different ball layers · CPC title

• A63B37/0075

  Three piece balls, i.e. cover, intermediate layer and core · CPC title

• A63B37/0023 Primary

  Covers · CPC title