Process for increasing xylene isomer to benzene ratio

Patent metadata

Field	Value
Publication number	US-10118878-B2
Application number	US-201715668535-A
Country	US
Kind code	B2
Filing date	Aug 3, 2017
Priority date	Sep 20, 2016
Publication date	Nov 6, 2018
Grant date	Nov 6, 2018

Abstract

Apparatuses and processes are provided for regulating C7 and C8 feed to an aromatics complex to increase the ratio of a selected xylene isomer to benzene ratio. Reformate may be split into three cuts in a splitter column. A side cut stream comprises predominantly C7 hydrocarbons and a bottoms steam from the splitter column comprises predominantly C8+ hydrocarbons. The relative proportion of the C7 and C8+ hydrocarbon streams sent to the aromatics complex are metered to determine the resulting ratio of a selected xylene isomer to benzene produced by the aromatics complex.

First claim

The invention claimed is:

1. A process for producing aromatics in an aromatics complex comprising:
fractionating a naphtha stream to provide a C7 stream and a C8+ aromatics stream;
feeding a first C7 stream taken from the C7 stream to the aromatics complex comprising an aromatics extraction unit, a BTX fractionation zone, a xylene fractionation zone, and a transalkylation unit and/or an isomerization unit;
feeding a first C8+ aromatics stream taken from the C8+ aromatics stream to the aromatics complex; and
feeding a second C7 stream taken from the C7 stream away from the aromatics complex; or
feeding a second C8+ aromatics stream taken from the C8+ aromatics stream away from the aromatics complex.

2. The process of claim 1 comprising feeding the first C7 stream taken from the C7 stream to the aromatics extraction unit in the aromatics complex to extract a non-aromatic C7 raffinate stream from a toluene stream.

3. The process of claim 2 comprising feeding the C7 raffinate stream to a gasoline pool.

4. The process of claim 2 comprising fractionating the toluene stream to separate a benzene stream from a concentrated toluene stream.

5. The process of claim 4 comprising feeding the concentrated toluene stream to the transalkylation unit to produce xylene and benzene.

6. The process of claim 5 further comprising fractionating a transalkylation effluent with the toluene stream to obtain a xylene stream in addition to the benzene stream and the concentrated toluene stream.

7. The process of claim 6 comprising feeding the xylene stream to the xylene fractionation zone in the aromatics complex to separate a concentrated xylene stream.

8. The process of claim 7 comprising feeding the concentrated xylene stream to a xylene extraction unit to extract a selected xylene isomer stream from a xylene raffinate stream.

9. The process of claim 8 comprising isomerizing the xylene raffinate stream in the isomerization unit to produce more selected xylene isomer and recycling an isomerate stream to said xylene extraction unit via said xylene fractionation zone.

10. The process of claim 1 comprising calculating a selected xylene isomer product to benzene product ratio and changing a flow rate of the second C7 stream and/or the second C8+ aromatics stream in response to the calculated selected xylene isomer product to benzene product ratio.

11. The process of claim 10 comprising fractionating said C8+ aromatics stream to provide said first C8+ aromatics stream comprising C8 aromatics and said second C8+ aromatics stream comprising C9 aromatics.

12. The process of claim 1 comprising recovering paraxylene and benzene from the aromatics complex at a mass ratio of paraxylene to benzene of at least 85:15.

13. A process for producing aromatics in an aromatics complex comprising an aromatics extraction unit, a BTX fractionation zone, a xylene fractionation zone, and a transalkylation unit and/or an isomerization unit, the process comprising the steps of:
fractionating a naphtha stream to provide an intermediate stream and a heavy stream;
feeding a first intermediate stream taken from the intermediate stream to an aromatics extraction unit to extract a raffinate stream from a toluene stream;
feeding all or a first portion of the heavy stream to a xylene column; and
feeding a second intermediate stream taken from the intermediate stream to a gasoline pool; or
feeding a second portion of the heavy stream to a the gasoline pool.

14. The process of claim 13 comprising feeding the raffinate stream to the gasoline pool.

15. The process of claim 13 comprising feeding the second portion of the heavy stream to the gasoline pool.

16. The process of claim 15 comprising fractionating said heavy stream to provide said first portion of the heavy stream comprising C8 aromatics and a second portion of the heavy stream comprising C9 aromatics.

17. The process of claim 13 comprising feeding the toluene stream to a BTX fractionation zone to separate a benzene stream from a concentrated toluene stream and a xylene stream; feeding the concentrated toluene stream to a transalkylation unit to produce xylene and benzene; passing the xylene stream to a xylene fractionation zone to produce a concentrated xylene stream; and passing the concentrated xylene stream to an xylene extraction unit to extract a selected xylene isomer.

18. A process for producing aromatics comprising:
fractionating a naphtha stream to provide a C7 stream and a C8+ aromatics stream;
feeding a first C7 stream taken from the C7 stream to an aromatics complex comprising an aromatics extraction unit, a BTX fractionation zone, a xylene fractionation zone, and a transalkylation unit and/or an isomerization unit;
feeding a second C7 stream taken from the C7 stream to a gasoline pool;
feeding a first C8+ aromatics stream taken from the C8+ aromatics stream to the aromatics complex; and
feeding a second C8+ aromatics stream taken from the C8+ aromatics stream to the gasoline pool.

19. The process of claim 18 comprising feeding the first C7 stream to the aromatics extraction unit in said aromatics complex to extract a C7 raffinate stream from a toluene stream and passing said C7 raffinate stream to the gasoline pool.

20. The process of claim 18 comprising fractionating said C8+ aromatics stream to provide said first C8+ aromatics stream taken from the C8+ aromatics stream comprising C8 aromatics and a second C8+ aromatics stream taken from the C8+ aromatics stream comprising C9 aromatics.

Assignees

• Uop Llc

Inventors

• Gattupalli Rajeswar R
• Shakur Mohamed S M
• Rashid Naiyl A

Classifications

• B01D3/143

  by two or more of a fractionation, separation or rectification step · CPC title

• C07C5/2737 Primary

  with crystalline alumino-silicates, e.g. molecular sieves · CPC title

• C10G45/58

  to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins (C10G32/00 takes precedence; improving or increasing the octane number or aromatic content of naphtha C10G35/00) · CPC title

• C07C15/06

  Toluene · CPC title

• C07C15/04

  Benzene · CPC title