Aluminum salt containing high percentage of Al30

Patent metadata

Field	Value
Publication number	US-10118832-B2
Application number	US-201615272357-A
Country	US
Kind code	B2
Filing date	Sep 21, 2016
Priority date	Nov 2, 2010
Publication date	Nov 6, 2018
Grant date	Nov 6, 2018

Abstract

A composition comprising an aluminum chlorohydrate salt, the aluminum chlorohydrate salt having at least 50 mole % Al 30 polyhydroxyoxoaluminum cation of all polyhydroxyoxoaluminum cations detectable by quantitative 27 Al NMR within the aluminum chlorohydrate salt, and a buffer. The composition can optionally include zirconium. Also disclosed are a method of making an aluminum salt using an increased molar concentration of a starting aluminum salt with a buffer, a method of reducing perspiration with the aluminum chlorohydrate salt, and a method of treating water with the aluminum chlorohydrate salt.

First claim

What is claimed is:

1. A method of making an aluminum chlorohydrate salt comprising:
I) heating an aqueous solution containing a first aluminum salt and a buffer, wherein the first aluminum salt is present in a molar concentration of at least 0.75M, wherein the buffer is an amino acid or betaine and a molar ratio of buffer to aluminum is at least 0.1:1, at a temperature of 50° C. to 100° C. for a period of time of 1 hour to 6 hours to obtain a first aluminum salt solution;
II) adding to the first aluminum salt solution an aqueous solution of an inorganic base to obtain a first aluminum chlorohydrate salt solution having an OH:Al molar ratio of at most 2.6:1 and a pH of 2 to 5; and
III) heating the first aluminum chlorohydrate salt solution at a temperature of 50° C. to 100° C. for a period of time of at least 8 hours to obtain a second aluminum chlorohydrate salt solution containing an aluminum chlorohydrate salt having at least 50 mole % Al 30 polyhydroxyoxoaluminum cation of all polyhydroxyoxoaluminum cations detectable by quantitative 27 Al NMR within the aluminum chlorohydrate salt.

2. The method of claim 1 , wherein the molar concentration of the first aluminum salt is at least 1M.

3. The method of claim 1 further comprising adding an aqueous solution containing a zirconium compound to the second aluminum chlorohydrate salt solution to thereby obtain an aluminum-zirconium salt solution, optionally having a molar ratio of aluminum to zirconium of 5:1 to 10:1, optionally the zirconium compound is ZrOCl 2 .8H 2 O.

4. The method of claim 1 , wherein heating in step III is at least at 90° C.

5. The method of claim 1 , wherein the period of time in step III is at least 12 hours.

6. The method of claim 1 , wherein the aluminum chlorohydrate salt exhibits a SEC chromatogram having a SEC Peak 4 area of at least 90% of a total area of Peaks 1, 2, 3, 4 and 5 in the SEC chromatogram.

7. The method of claim 1 , wherein the buffer is glycine.

8. The method of claim 1 , wherein the inorganic base includes at least one member chosen from calcium hydroxide, strontium hydroxide, barium hydroxide, calcium oxide, strontium oxide, barium oxide, calcium carbonate, barium carbonate, strontium carbonate, yttrium hydroxide, yttrium oxide, and yttrium carbonate.

9. The method of claim 8 , wherein the inorganic base is calcium hydroxide.

10. The method of claim 1 , wherein the second aluminum chlorohydrate salt has an aluminum to chloride molar ratio of 0.3:1 to 3:1.

11. The method of claim 1 , wherein the second aluminum chlorohydrate salt has an OH to Al molar ratio of 2:1 to 2.5:1, or optionally 2.3:1 to 2.5:1.

12. The method of claim 1 , wherein the first aluminum salt is an aluminum chloride compound chosen from aluminum trichloride, aluminum chlorohexahydrate, and aluminum dichlorohydrate.

13. The method of claim 1 , wherein the buffer is glycine present in a glycine to aluminum molar ration of 0.1:1 to 2:1, the inorganic base is calcium hydroxide, and the heating in step III is at least at 90° C. for at least 12 hours.

14. The method of claim 1 , wherein the 27 Al NMR spectrum has a species distribution including at most 5 mole % Al 13 polyhydroxyoxoaluminum cation of all polyhydroxyoxoaluminum cations detectable by quantitative 27 Al NMR in the aluminum chlorohydrate salt.

15. The method of claim 14 , wherein the 27 Al NMR spectrum has a species distribution including no Al 13 polyhydroxyoxoaluminum cation of all polyhydroxyoxoaluminum cations detectable by quantitative 27 Al NMR in the aluminum chlorohydrate salt.

16. The method of claim 1 , wherein the aluminum chlorohydrate salt exhibits a SEC chromatogram having a SEC Peak 4 area of at least 95% of a total area of Peaks 1, 2, 3, 4 and 5 in the SEC chromatogram.

17. The method of claim 1 , wherein the aluminum chlorohydrate salt has a SEC Peak 3 area of less than 5% of a total area of Peaks 1, 2, 3, 4 and 5 in the SEC chromatogram.

18. The method of claim 17 , wherein the aluminum chlorohydrate salt has no SEC Peak 3 area in the SEC chromatogram.

19. The method of claim 1 , wherein the aluminum chlorohydrate salt has a SEC Peak 5 area of less than 5% of a total area of Peaks 1, 2, 3, 4 and 5 in the SEC chromatogram.

Assignees

• Colgate Palmolive Co

Inventors

• Pappas Iraklis
• Vaughn John
• Pan Long

Classifications

• C01F7/78

  Compounds containing aluminium, with or without oxygen or hydrogen, and containing two or more other elements (aluminates C01F7/02; compounds containing aluminium, fluorine and alkali or alkaline earth metals C01F7/54; nitrates containing other cations besides aluminium C01F7/66; sulfides, sulfites or sulfates containing other cations besides aluminium C01F7/70 - C01F7/74) · CPC title

• C01F7/57

  Basic aluminium chlorides, e.g. polyaluminium chlorides · CPC title

• C01F7/56 Primary

  Chlorides (containing fluorine C01F7/52) · CPC title

• C01F7/002

  Chemistry & Metallurgy · mapped topic

• A61K8/44

  Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof · CPC title