Extruded deposition of polymers having continuous carbon nanotube reinforcements

Patent metadata

Field	Value
Publication number	US-10118375-B2
Application number	US-201514602964-A
Country	US
Kind code	B2
Filing date	Jan 22, 2015
Priority date	Sep 18, 2014
Publication date	Nov 6, 2018
Grant date	Nov 6, 2018

Abstract

A composite part is fabricated by rastering a deposition head over a substrate, and additively forming part features by extruding a polymer having an entrained continuous nanotube reinforcement from the deposition head onto a substrate.

First claim

What is claimed is:

1. A deposition fabrication method, comprising:
establishing a pressurized stream of a first polymer through a tube, wherein the first polymer has a first melt temperature;
entraining a carbon nanotube reinforcement within the pressurized stream, wherein the carbon nanotube reinforcement is pre-impregnated with a second polymer that has a second melt temperature, wherein the second melt temperature is higher than the first melt temperature, and wherein entraining is performed above the first melt temperature but below the second melt temperature, wherein as a result of entraining a combined polymer is formed;
maintaining a third temperature at a material supply end of an entrainment barrel that contains the tube at a higher temperature than a fourth temperature at a material deposition end of the entrainment barrel; and
depositing a bead of the combined polymer from the tube onto a substrate.

2. The deposition fabrication method of claim 1 , wherein entraining the carbon nanotube reinforcement includes feeding a carbon nanotube yarn into the tube.

3. The deposition fabrication method of claim 1 , wherein entraining the carbon nanotube reinforcement includes feeding aligned carbon nanotubes into the tube.

4. The deposition fabrication method of claim 1 , wherein entraining the carbon nanotube reinforcement includes feeding a continuous length of mechanically interlocked carbon nanotubes into the pressurized stream.

5. The deposition fabrication method of claim 1 , further comprising:
drawing the carbon nanotube reinforcement through the tube using the pressurized stream and capillary action.

6. The deposition fabrication method of claim 1 , further comprising:
pre-impregnating the carbon nanotube reinforcement with a polymer, and
wherein entraining the carbon nanotube reinforcement includes continuously feeding the carbon nanotube reinforcement into the pressurized stream.

7. The deposition fabrication method of claim 1 , further comprising:
heating the carbon nanotube reinforcement to a glass transition of the first polymer.

8. The method of claim 1 , wherein the first polymer is different than the second polymer.

9. A method of fabricating a composite part, comprising:
providing a length of a carbon nanotube yarn;
providing a liquefied polymer;
feeding the carbon nanotube yarn and the liquefied polymer into a deposition head, including entraining, through an entrainment barrel, the carbon nanotube yarn within the liquified polymer, and wherein feeding and entraining further comprises:
feeding the carbon nanotube yarn into a guide tube disposed inside an annular inlet of the entrainment barrel, wherein the guide tube ends at an entrance to a capillary tube disposed inside the entrainment barrel;
flowing the liquified polymer into the annular inlet and around the guide tube, including flowing the liquified polymer past the guide tube and into the capillary tube via a convergence region in which the liquified polymer is allowed to flow onto the carbon nanotube yarn just as the carbon nanotube yarn enters the capillary tube;

rastering the deposition head over a substrate; and
additively forming features of the composite part by extruding the liquefied polymer having the carbon nanotube yarn entrained therein from the deposition head onto the substrate, wherein extruding includes extruding from the capillary tube that extends past an end of the entrainment barrel.

10. The method of claim 9 , wherein the extruding includes forcing the liquefied polymer having the carbon nanotube yarn entrained therein through a tube and a die.

11. The method of claim 9 , further comprising:
cutting the liquefied polymer having the carbon nanotube yarn entrained therein during rastering of the deposition head.

12. The method of claim 9 , wherein extruding the liquefied polymer and the carbon nanotube yarn includes:
introducing the liquefied polymer and the carbon nanotube yarn into an upstream end of a tube,
forcing the liquefied polymer to flow through the tube to a downstream end of the tube, and
drawing the carbon nanotube yarn through the tube to the downstream end of the tube by using the flow through the tube to drag the carbon nanotube yarn along with the flow through the tube.

13. The method of claim 12 , further comprising:
using capillary action to assist in drawing the carbon nanotube yarn through the tube.

14. The method of claim 12 , wherein introducing the liquefied polymer and the carbon nanotube yarn includes injecting the liquefied polymer under pressure around the carbon nanotube yarn.

15. The method of claim 9 , wherein providing a length of carbon nanotube yarn includes:
producing a plurality of carbon nanotube threads, and
mechanically interlocking the carbon nanotube threads.

16. The method of claim 15 , wherein mechanically interlocking the carbon nanotube threads is performed by spinning the carbon nanotube threads together.

17. The method of claim 16 , wherein producing the plurality of carbon nanotube threads includes aligning and coupling together a plurality of carbon nanotubes.

18. The method of claim 17 , wherein producing the plurality of carbon nanotube threads includes impregnating the carbon nanotubes with a polymer.

Assignees

• Boeing Co

Inventors

• Hickman Gregory James Schoepen
• Bogucki Gregg Robert

Classifications

• B29C70/24

  oriented in at least three directions forming a three-dimensional [3D] structure · CPC title

• B29K2307/04

  Carbon · CPC title

• B29C67/0055

  Operations & Transport · mapped topic

• B33Y30/00

  Apparatus for additive manufacturing; Details thereof or accessories therefor · CPC title

• B29K2105/12

  of short lengths, e.g. chopped filaments, staple fibres or bristles · CPC title