Device for regulating the passage of energy

Patent metadata

Field	Value
Publication number	US-10114264-B2
Application number	US-201414772422-A
Country	US
Kind code	B2
Filing date	Feb 7, 2014
Priority date	Mar 5, 2013
Publication date	Oct 30, 2018
Grant date	Oct 30, 2018

Abstract

The present application relates to a device for regulating the passage of light through a light-transmitting area which comprises a switching layer comprising a liquid-crystalline medium comprising at least one dichroic dye, where the parameters degree of light transmission and degree of anisotropy of the device are selected in a certain manner.

First claim

The invention claimed is:

1. A device for regulating the passage of light through a light-transmitting area, said device comprising:
one or more glass layers and at least one switching layer which comprises a liquid-crystalline medium comprising at least one dichroic dye,
wherein said switching layer has a bright state τ v bright and a dark state τ v dark , and
wherein said switching layer has a degree of anisotropy R of at least 0.65 and a degree of light transmission in the bright state τ v bright in accordance with Standard EN410 of 40% to 90%,
wherein said device is a component of a window,
wherein said switching layer comprises three or more different dichroic dyes, and
wherein the liquid-crystalline medium has a clearing point in the temperature range from 70° C. to 170° C.

2. The device according to claim 1 , further comprising one or more alignment layers which are arranged directly adjacent to the switching layer.

3. The device according to claim 1 , further comprising precisely two alignment layers, one of said alignment layers which is adjacent to one side of the switching layer and the other of said alignment layers is adjacent to the opposite side of the switching layer, and where the two alignment layers cause a parallel or 90°-rotated preferential direction of the molecules of the liquid-crystalline medium on both sides of the switching layer.

4. The device according to claim 1 , wherein homogeneous alignment of the molecules of the liquid-crystalline medium is present in the voltage-free state, where the molecules are aligned parallel to one another on both sides of the switching layer.

5. The device according to claim 1 , further comprising means for the alignment of the molecules of the liquid-crystalline medium of the switching layer by electrical voltage.

6. The device according to claim 1 , further comprising a light-guide system which conducts light from the switching layer to a unit which converts light energy into electrical energy or heat energy.

7. The device according to claim 1 , further comprising an element for the conversion of light energy into electrical energy which is electrically connected to said device.

8. The device according to claim 1 , wherein said one or more glass layers have an antireflection design.

9. The device according to claim 1 , wherein said device comprises precisely one switching layer.

10. The device according to claim 1 , wherein at least one of said dichroic dyes is luminescent.

11. The device according to claim 1 , wherein at least one of the dichroic dyes is an azo compound, an anthraquinone, a methine compound, an azomethine compound, a merocyanine compound, an naphthoquinone, a tetrazine, a perylene, a terrylene, a quaterrylenes, a higher rylene or a pyrromethene.

12. The device according to claim 1 , wherein said device has an area of at least 0.05 m 2 .

13. The device according to claim 1 , wherein said switching layer has a degree of anisotropy R of 0.7 to 0.9.

14. The device according to claim 1 , wherein said switching layer has a degree of light transmission in the bright state τ v bright of 60% to 85%.

15. The device according to claim 1 , wherein the following applies to the parameter T v bright of the switching layer for a given parameter R of the switching layer:
τ v bright min <τ v bright <τ v bright max and

τ v bright min =0.8*(67 *R+ 30) and τ v bright max =1.2*(67 *R+ 30).

16. The device according to claim 1 , wherein the following applies to the parameter R of the switching layer for a given parameter T v bright :
R min <R<R max and
R min =0.8*(0.015*τ v bright −0.45) and R max =1.2*(0.015*τ v bright −0.45).

17. The device according to claim 1 , wherein said device comprises two or more glass layers, and in that the degree of light reflection ρ v in accordance with Standard EN410 of the totality of the layers of the device with the exception of the switching layer is less than 35%.

18. A window comprising multipane insulating glass and at least one device according claim 1 .

19. A method for regulating the passage of light through a light-transmitting area into an interior space, said method comprising regulating said passage of light via passage through a device according to claim 1 .

20. The device according to claim 1 , wherein said device comprises two or more glass layers, and in that the degree of light reflection ρ v in accordance with Standard EN410 of the totality of the layers of the device with the exception of the switching layer is less than 30%.

21. The device according to claim 1 , further comprising a first electrode installed on one side of the switching layer and a second electrode installed on the other side of the switching layer, and wherein application of a voltage across the electrodes cause a change in the alignment of the molecules of the liquid-crystalline medium including the molecules of the at least one dichroic dye and a resultant change in the light transmission of the device.

22. The window according to claim 18 , wherein said device is applied to the outside of a pane of the multipane insulating glass.

23. The window according to claim 18 , wherein said device is positioned between two panes of the multipane insulating glass.

24. The device according to claim 1 , wherein said device comprises the following arrangement of layers:
1) a first glass layer,
2) a first electrically conductive layer,
3) a first alignment layer,
4) said switching layer,
5) a second alignment layer,
6) a second electrically conductive layer,
7) a second glass layer, and
8) a third glass layer,
wherein a free space is present between the second and third glass layers and where said free space is optionally filled with an insulating gas.

25. The device according to claim 1 , wherein said device is a switchable device that provides for a change in the light transmission of the device, wherein the switching occurs by transition of the liquid-crystalline medium from a nematic state to an isotropic state due to a change in the temperature of the switching layer.

26. The device according to claim 1 , wherein the proportion of all dichroic dyes together in the liquid-crystalline medium is in total 0.01 to 10% by weight.

27. The device according to claim 1 , wherein the liquid-crystalline medium has a dielectric anisotropy greater than 3, an optical anisotropy (An) of 0.01 to 0.3, and a specific electrical resistance of greater than 10 10 ohm*cm.

28. The device according to claim 1 , wherein said liquid-crystalline medium comprises at least one of the following dichroic dyes:

29. A window comprising multipane insulating glass and at least one device according claim 24 wherein which a first glass pane of the window is formed by a glass pane of said at least one device.

30. The device according to claim 1 , wherein said liquid-crystalline med

Assignees

• Merck Patent Gmbh

Inventors

• Junge Michael
• Beyer Andreas
• Patwal Ursula

Classifications

• C09K2019/3077

  Cy-Cy-COO-Ph · CPC title

• C09K2019/2035

  Ph-COO-Ph · CPC title

• C09K2019/3016

  Cy-Ph-Ph · CPC title

• G02F2001/133738

  Physics · mapped topic

• G02F1/13762

  containing luminescent or electroluminescent additives · CPC title