Sulphite sensor and method for measuring sulphite concentration in a substance

Patent metadata

Field	Value
Publication number	US-10113989-B2
Application number	US-201214347393-A
Country	US
Kind code	B2
Filing date	Oct 8, 2012
Priority date	Oct 7, 2011
Publication date	Oct 30, 2018
Grant date	Oct 30, 2018

Abstract

The present invention relates to a method for measuring a concentration of sulphite in a substance in a gas cleaning process, the method comprising the steps of sending a plurality of voltage pulses through the substance by a first electrode ( 11 ) and a second electrode ( 20 ), which first and second electrodes ( 11, 20 ) are in contact with the substance, receiving current responses generated by the plurality of voltage pulses, and analyzing the current responses using a multivariate data analysis for calculation of the concentration of sulphite in the substance. The present invention further relates to a sulphite sensor ( 1 ) for performing such a method.

First claim

What is claimed is:

1. A method for measuring a concentration of sulphite in an absorption liquid of a wet scrubber used in a gas cleaning process, the method comprising steps of:
sending a plurality of voltage pulses through the absorption liquid of the wet scrubber using a first electrode and a second electrode that are in contact with the absorption liquid of the wet scrubber, wherein sending a plurality of voltage pulses comprises sending the plurality of voltage pulses in a stepwise series having a stepwise increase or a stepwise decrease of voltage level between consecutive pulses;
receiving current responses generated by the plurality of voltage pulses sent in the stepwise series;
analyzing the current responses by analyzing at least two separate values of each current response generated by the plurality of voltage pulses sent in the stepwise series; and
calculating the concentration of sulphite in the absorption liquid of the wet scrubber based on the at least two separate values of each current response generated by the plurality of voltage pulses sent in the stepwise series.

2. The method according to claim 1 , wherein each voltage pulse sent through the absorption liquid of the wet scrubber is 0.02-0.2 V higher or lower than an immediately preceding voltage pulse.

3. The method according to claim 1 , wherein the step of analyzing the at least two separate values comprises analyzing a peak value and at least one more value of each of the current responses.

4. The method according to claim 1 , wherein the method further comprises cleaning a surface of the first electrode by removing a coating from the first electrode caused by contact between the first electrode and the absorption liquid of the wet scrubber.

5. The method according to claim 1 , wherein the method further comprises cleaning a surface of the first electrode by rotating a cleaning unit in contact with the first electrode.

6. The method according to claim 1 , further comprising cleaning the first electrode using a cleaning unit rotated in contact with a surface of the first electrode at a speed of 2-40 rpm.

7. The method according to claim 1 , further comprising providing a sensor for measuring another property of the absorption liquid of the wet scrubber.

8. The method according to claim 1 , further comprising providing a sensor for measuring a temperature of the absorption liquid of the wet scrubber.

Assignees

• General Electric Company Gmbh
• General Electric Technology Gmbh

Inventors

• Brogaard Fredrik Jens
• Larsson Mikael
• Winquist Fredrik

Classifications

• G01N27/4162 Primary

  investigating the composition of gases, by the influence exerted on ionic conductivity in a liquid (conductometry in general G01N27/06; amperometric gas sensors G01N27/404) · CPC title

• G01N33/0029

  Cleaning of the detector · CPC title

• G01N21/93

  Detection standards; Calibrating {baseline adjustment, drift correction} · CPC title