Optically transparent films for measuring optically thick fluids

Patent metadata

Field	Value
Publication number	US-10113958-B2
Application number	US-201214441481-A
Country	US
Kind code	B2
Filing date	Dec 28, 2012
Priority date	Dec 28, 2012
Publication date	Oct 30, 2018
Grant date	Oct 30, 2018

Abstract

A multilayered film and a method for performing spectroscopic measurements in a fluid are provided. The multilayered film includes a substrate; a porous layer adjacent to the substrate; and a reflective layer formed on the porous layer, wherein the porous layer selectively allows a component of a fluid to be optically measured when the multilayered film is immersed in the fluid. A sensor for spectroscopic measurements in crude oil samples including a multilayered film as above is also provided. A method of manufacturing a multilayered film for spectroscopic measurements in fluids as above is also provided.

First claim

What is claimed is:

1. A method for measuring properties of a fluid, the method comprising:
directing an input light through a multivariate optical element (MOE) of a multilayered film, then through a substrate and a porous layer of the multilayered film, the multilayered film further including a reflective layer disposed on the porous layer, and the porous layer having the fluid therein;
reflecting the input light using the reflective layer, thereby forming an output light which is directed back through the porous layer and the substrate, then through the MOE;
detecting the output light from the multilayered film; and
comparing the output light with the input light to measure a property of at least one component of the fluid.

2. The method of claim 1 , wherein a plurality of pores in the porous layer excludes particulates and contaminants from filling interior portions of the pores, the excluded particulates and contaminants being larger in size than a diameter of the pores.

3. The method of claim 2 , wherein the larger particulates and contaminants comprise asphaltenes.

4. A method for measuring properties of a fluid, the method comprising:
directing an input light through a multilayered film, the multilayered film comprising a substrate, a multivariate optical element (MOE), a porous layer, and a reflective layer disposed on the porous layer;
detecting an output light from the multilayered film;
comparing the output light with the input light to measure a property of at least one component of the fluid; and
resistively heating the reflective layer to allow cleaning of deposits from openings of the porous layer.

5. The method of claim 4 , wherein a plurality of pores in the porous layer excludes particulates and contaminants from filling interior portions of the pores, the excluded particulates and contaminants being larger in size than a diameter of the pores.

6. The method of claim 5 , wherein the larger particulates and contaminants comprise asphaltenes.

7. The method of claim 4 , wherein the fluid comprises crude oil.

8. The method of claim 4 , wherein the fluid is in a wellbore formed in a procedure selected from the group consisting of a wireline logging procedure and a logging while drilling (LWD) procedure.

9. The method of claim 4 , wherein directing the input light through the multilayered film comprises:
directing the input light through the MOE, then through the substrate and the porous layer having the fluid therein; and
reflecting the input light using the reflective layer, thereby forming an output light which is directed back through the porous layer and the substrate, then through the MOE.

10. The method of claim 4 , wherein the fluid comprises an electrolyte solution separable into ionic components, the method further comprising: applying a voltage to separate the ionic components; allowing at least one of the ionic components to fill the pores in the porous layer; and optically measuring the at least one ionic component filling the pores.

11. The method of claim 1 , wherein the fluid comprises crude oil.

12. The method of claim 1 , wherein the fluid comprises an electrolyte solution separable into ionic components, the method further comprising:
applying a voltage to separate the ionic components;
allowing at least one of the ionic components to fill the pores in the porous layer; and
optically measuring the at least one ionic component filling the pores.

13. The method of claim 1 , wherein the fluid is in a wellbore formed in a procedure selected from the group consisting of a wireline logging procedure and a logging while drilling (LWD) procedure.

14. The method of claim 1 , further comprising:
placing a side of the multilayered film in contact with the fluid such that the porous layer is filled with analytes of interest.

Assignees

• Halliburton Energy Services Inc

Inventors

• Perkins David L

Classifications

• G01N21/031

  Multipass arrangements · CPC title

• C25D5/52

  by brightening or burnishing · CPC title

• E21B49/08

  Obtaining fluid samples or testing fluids, in boreholes or wells · CPC title

• G01N21/3577 Primary

  for analysing liquids, e.g. polluted water · CPC title

• C25D5/12

  at least one layer being of nickel or chromium · CPC title