Gold plate coated stainless material and method of producing gold plate coated stainless material

Patent metadata

Field	Value
Publication number	US-10113238-B2
Application number	US-201314897093-A
Country	US
Kind code	B2
Filing date	Sep 20, 2013
Priority date	Jun 13, 2013
Publication date	Oct 30, 2018
Grant date	Oct 30, 2018

Abstract

There is provided a gold plate coated stainless material characterized by comprising: a stainless steel sheet formed with a passivation film having a surface of which a Cr/O value is within a range of 0.05 to 0.2 and a Cr/Fe value is within a range of 0.5 to 0.8 when measured by Auger electron spectroscopy analysis; and a gold plated layer formed on the passivation film of the stainless steel sheet. According to the present invention, there can be provided a gold plate coated stainless material which can be improved in the coverage and interfacial adhesion property of the gold plated layer formed on the stainless steel sheet even when reducing the thickness of the gold plated layer, thereby to be excellent in corrosion resistance and conductivity and advantageous in cost.

First claim

What is claimed is:

1. A gold plate coated stainless material comprising:
a stainless steel sheet coated with a gold plated layer which is deposited directly on a passivation film present on a surface of the stainless steel sheet, wherein
the passivation film has a surface composition having a Cr/O value comprised within a range from 0.05 to 0.2 and a Cr/Fe value comprised within a range from 0.5 to 0.8, the Cr/O value and the Cr/Fe value obtained by Auger electron spectroscopy analysis.

2. The gold plate coated stainless material according to claim 1 , wherein the gold plated layer has a coverage of 95% or more.

3. A method of producing a gold coated stainless material according to claim 1 , the method comprising:
immersing a stainless steel sheet in a sulfuric acid aqueous solution; and
forming a gold plated layer on the stainless steel sheet, wherein
the stainless steel sheet is immersed in the sulfuric acid aqueous solution to satisfy Expression (1) below:
0.6×10 6 ≤x 2 ·( y− 40) 2 ·√{square root over (z)}≤ 3.0×10 6   (1)

where x represents a sulfuric acid concentration [vol %] of the sulfuric acid aqueous solution (20≤x≤25), y represents a temperature [° C.] of the sulfuric acid aqueous solution, and z represents an immersion time [seconds] when the stainless steel sheet is immersed in the sulfuric acid aqueous solution.

4. A method of producing a gold plate coated stainless material, the method comprising:
immersing a stainless steel sheet in a sulfuric acid aqueous solution so as to form a passivation film on the stainless steel sheet, the passivation film having a surface of which a Cr/O value is within a range of 0.05 to 0.2 and a Cr/Fe value is within a range of 0.5 to 0.8 when measured by Auger electron spectroscopy analysis; and
forming a gold plated layer directly on the passivation film of the stainless steel sheet.

5. The gold plate coated stainless material according to claim 1 , wherein the ratio (Fe (metal)/Fe (total)) of an elementary substance of iron (Fe (metal) to the total amount of Fe atoms (Fe (total)) at the surface of the passivation film is 14% or more.

6. The gold plate coated stainless material according to claim 1 , wherein the ratio (Ni (metal)/Ni (total)) of an elementary substance of nickel (Ni (metal) to the total amount of Ni atoms (Ni (total)) at the surface of the passivation film is 18% or more.

7. The gold plate coated stainless material according to claim 1 , wherein an arithmetic average roughness Ra of the passivation film is 0.015 μm or more.

8. The gold plate coated stainless material according to claim 1 , wherein the thickness of the gold plated layer is within 2 to 20 nm.

Assignees

• Toyo Kohan Co Ltd

Inventors

• Mukai Nobuaki
• Yoshida Takahiro

Classifications

• C23C22/50

  Treatment of iron or alloys based thereon · CPC title

• C23G1/081

  solutions containing H2SO4 · CPC title

• C23C18/44 Primary

  using reducing agents · CPC title

• C23C28/322

  only coatings of metal elements only · CPC title

• C23C18/54

  Contact plating, i.e. electroless electrochemical plating · CPC title