Activity enhanced scale dispersant for treating inorganic sulfide scales

Patent metadata

Field	Value
Publication number	US-10113102-B2
Application number	US-201415527147-A
Country	US
Kind code	B2
Filing date	Dec 23, 2014
Priority date	Dec 23, 2014
Publication date	Oct 30, 2018
Grant date	Oct 30, 2018

Abstract

Processes and compositions to control inorganic sulfide scale formations in oilfield applications, including flow lines, wellbores, and subterranean formations. One example involves providing a treatment fluid comprising: a base fluid, a scale inhibitor, and a water clarifying agent; introducing the treatment fluid into a target region, wherein an inorganic cation and a sulfide anion are present in the target region; allowing the inorganic cation and the sulfide anion to form a sulfide precipitate; and using the treatment fluid to remove at least a portion of the sulfide precipitate from the target region.

First claim

What is claimed is:

1. A method comprising:
providing a treatment fluid comprising:
a base fluid,
a scale inhibitor, wherein the scale inhibitor comprises a phosphonate, and
a water clarifying agent, wherein the water clarifying agent comprises at least one compound selected from the group consisting of: a polyDADMAC, a DADMAC acrylamide copolymer, and any combination thereof;

introducing the treatment fluid into a target region, wherein an inorganic cation and a sulfide anion are present in the target region;
allowing the inorganic cation and the sulfide anion to form a sulfide precipitate; and
using the treatment fluid to remove at least a portion of the sulfide precipitate from the target region.

2. The method of claim 1 wherein the inorganic cation is a metal cation.

3. The method of claim 2 wherein the metal cation comprises at least one metal cation selected from the group consisting of: iron, zinc, lead, and any combination thereof.

4. The method of claim 1 wherein the target region is a portion of a wellbore.

5. The method of claim 4 wherein the treatment fluid is a consolidation fluid, a drilling fluid, a fracturing fluid, a completion fluid, a workover fluid, a packer fluid, a spacer fluid, or any combination thereof.

6. The method of claim 4 wherein the treatment fluid is introduced into the portion of the wellbore in a continuous injection.

7. The method of claim 4 wherein the treatment fluid is introduced into the portion of the wellbore using a pump.

8. A method comprising:
providing a treatment fluid comprising a base fluid, a scale inhibitor comprising a phosphonate, and a water clarifying agent comprising least one compound selected from the group consisting of: a polyDADMAC, a DADMAC acrylamide copolymer, and any combination thereof;
introducing the treatment fluid into a portion of a wellbore, wherein an inorganic cation and a sulfide anion are present in the wellbore;
allowing the inorganic cation and the sulfide anion to form a sulfide precipitate; and
using the treatment fluid to remove at least a portion of the sulfide precipitate from the wellbore.

9. The method of claim 8 wherein the inorganic cation is a metal cation.

10. The method of claim 9 wherein the metal cation comprises at least one metal cation selected from the group consisting of: iron, zinc, lead, and any combination thereof.

11. The method of claim 8 wherein the treatment fluid is a consolidation fluid, a drilling fluid, a fracturing fluid, a completion fluid, a workover fluid, a packer fluid, a spacer fluid, or any combination thereof.

12. The method of claim 8 wherein the treatment fluid is introduced into the portion of the wellbore in a continuous injection.

13. The method of claim 8 wherein the treatment fluid is introduced into the portion of the wellbore using a pump.

14. A composition comprising:
a base fluid;
a scale inhibitor, wherein the scale inhibitor comprises a phosphonate;
a water clarifying agent, wherein the water clarifying agent comprises at least one compound selected from the group consisting of: a polyDADMAC, a DADMAC acrylamide copolymer, and any combination thereof; and
a sulfide precipitate.

15. The composition of claim 14 wherein the sulfide precipitate comprises at least one compound selected from the group consisting of: iron sulfide, zinc sulfide, lead sulfide, and any combination thereof.

Assignees

• Multi Chem Group Llc

Inventors

• Peng Yang
• Yue Zhiwei
• Fan Chunfang
• Hazlewood Johnathan Scott

Classifications

• C09K2208/20

  Hydrogen sulfide elimination · CPC title

• C09K8/528

  inorganic depositions, e.g. sulfates or carbonates · CPC title

• E21B37/06

  using chemical means for preventing or limiting {, e.g. eliminating,} the deposition of paraffins or like substances · CPC title

• C09K8/03

  Specific additives for general use in well-drilling compositions · CPC title

• C09K8/532 Primary

  Sulfur · CPC title