Clear and impact resistant polymer composition and fabricated article

Patent metadata

Field	Value
Publication number	US-10113058-B2
Application number	US-201615390005-A
Country	US
Kind code	B2
Filing date	Dec 23, 2016
Priority date	Dec 30, 2015
Publication date	Oct 30, 2018
Grant date	Oct 30, 2018

Abstract

A polymer composition providing optical clarity and impact resistance includes from about 40 weight percent (wt. %) to about 99.9 wt. % (e.g., 50-95 wt. %) of a continuous matrix, and from about 0.01 wt. % to about 60 wt. % (e.g., 5-50 wt. %) of a dispersed phase. The weight percentages of the matrix phase and the dispersed phase are based on the total weight of the matrix phase and the dispersed phase. The matrix phase may comprise a polypropylene polymer comprising from 0 to 7 mole percent (mol. %) of units derived from ethylene, a C 4 -C 10 alpha olefin or combinations thereof. The dispersed phases may be a propylene/alpha olefin copolymer having from 10 mol. % to 70 mol. % of units derived from ethylene or a C 4 -C 10 alpha olefin or combinations thereof.

First claim

What is claimed is:

1. A polymer composition, comprising:
from about 50 weight percent (wt. %) to about 95 wt. % of a matrix phase comprising a polypropylene polymer comprising from 0 to 7 mole percent (mol. %) of units derived from ethylene, a C 4 -C 10 alpha olefin or combinations thereof;
from about 5 wt. % to about 50 wt. % of a dispersed phase being a propylene/alpha olefin copolymer having from 10 mol. % to 70 mol. % of units derived from ethylene or a C 4 -C 10 alpha olefin or combinations thereof,
wherein the weight percentages of the matrix phase and the dispersed phase are based on the total weight of the matrix phase and the dispersed phase, and
the polymer composition satisfies the following inequality:
y≤55x −8, wherein x is a ratio of Mw solubles/Mw insolubles and is less than or equal to 0.85, Mw solubles is weight average molecular weight of a soluble fraction of the polymer composition in xylene at 25° C. following ASTM D5492, Mw insoluble is weight average molecular weight of an insoluble fraction of the polymer composition in xylene at 25° C. following ASTM D5492, and y is the haze value being measured on a 0.508 millimeter (20 mil) thick injection molded plaque according to ASTM D1003; and
wherein the matrix phase has a melt flow rate of from about 0.1 dg/min. to about 10 dg/min.; and the dispersed phase has a melt flow rate of from about 1 dg/min. to about 200 dg/min., being measured using a load of 2.16 kg at 230 ° C. following ASTM D 1238.

2. The polymer composition of claim 1 , wherein the dispersed phase comprises from 35 mol. % to 60 mol. % of units derived from ethylene or a C 4 -C 10 alpha olefin or combinations thereof.

3. The polymer composition of claim 1 , wherein the dispersed phase has an intrinsic viscosity of from about 0.5 to about 3.

4. The polymer composition of claim 1 , wherein the polypropylene polymer of the matrix phase comprises from 0.01 mol. % to 5 mol. % of ethylene.

5. The polymer composition of claim 1 , further comprising a clarifying agent.

6. The polymer composition of claim 5 , wherein the clarifying agent is present at a final concentration less than 8000 ppm.

7. The polymer composition of claim 1 , wherein the haze value is less than 30%, the haze value being measured using at an injection molded plaque having a thickness of 0.508 millimeter (20 mil) following ASTM D1003.

8. The polymer composition of claim 1 , wherein the copolymer of the dispersed phase has a domain size smaller than 700 nanometers (nm).

9. The polymer composition of claim 1 , wherein the polymer composition has a melt flow rate of from about 0.5 dg/min. to about 10 dg/min., the melt flow rates being measured using a load of 2.16 kg at 230 ° C. following ASTM D 1238.

10. The polymer composition of claim 1 , wherein the polymer composition has a flexural modulus greater than 1000 MPa at 23 ° C. according to ASTM D 790.

11. The polymer composition of claim 1 , wherein the polymer composition has a notched Izod impact strength greater than 5 ft-lbs/in 2 measured at 23 ° C. according to ASTM D 256.

12. The polymer composition of claim 1 , wherein the polymer composition has a ratio of β/α less than 1.2 according to the formula:

β
/
α

=

(

MFR
1

/

MFR
2

)

0.213

-
1

(

Fc
/
100

)

+
1

wherein MFR 1 is the melt flow of the matrix phase only, MFR 2 is the overall melt flow of the polymer composition, and F c is the weight percentage of the dispersed phase in the polymer composition.

13. The polymer composition of claim 1 , having a Mw/Mn equal to or greater than 4.

14. The polymer composition of claim 1 , having a heat deflection temperature (HDT) greater than 75° C. at 0.46 MPa (66 psi) according to ASTM D648.

15. The polymer composition of claim 1 , having a viscosity ratio (Mw solubles/Mw insolubles) less than 0.8.

16. A fabricated article, comprising the polymer composition of claim 1 .

17. The fabricated article of claim 16 , manufactured by a blow molding or thermoforming process.

18. The fabricated article of claim 16 , wherein the copolymer of the dispersed phase in the matrix has a phase domain size smaller than 700 nm.

19. The fabricated article of claim 16 , wherein the article has a haze value less than 30%.

20. The fabricated article of claim 16 , wherein the article has a top load value greater than 20 lb-ft.

Assignees

• Braskem America Inc

Inventors

• Bockman Leslie
• Carnevale Elliot
• Larson Jon Scott
• Herrington Kevin

Classifications

• C08L2666/06

  Homopolymers or copolymers of unsaturated hydrocarbons; Derivatives thereof · CPC title

• C08L2203/30

  used for thermoforming · CPC title

• B29C51/002

  characterised by the choice of material · CPC title

• C08L23/20

  having four to nine carbon atoms · CPC title

• C08L23/12 Primary

  Polypropene · CPC title