Release liner comprising nanofibrillar cellulose

Patent metadata

Field	Value
Publication number	US-10113006-B2
Application number	US-201415314222-A
Country	US
Kind code	B2
Filing date	Jun 26, 2014
Priority date	Jun 26, 2014
Publication date	Oct 30, 2018
Grant date	Oct 30, 2018

Abstract

The invention relates to a method for obtaining a release liner and to release liner comprising a primer layer and a cellulose based support layer, the primer layer comprising an organic compound having one or more functional vinylic groups, the organic compound comprising an acetal connecting a first moiety and a second moiety, the first moiety comprising nanofibrillar cellulose having functional hydroxyl groups and the second moiety comprising an organic fragment, the organic fragment comprising at least one functional vinylic group.

First claim

The invention claimed is:

1. A method for obtaining a substrate layer for a release liner comprising nanofibrillar cellulose, the method comprising:
providing a cellulose based support layer,
providing an organic compound comprising a first moiety and a second moiety connected by an acetal by arranging an acetalisation reaction between nanofibrillar cellulose and an organic fragment, and
applying the organic compound on a surface of the cellulose based support layer to form a release liner comprising a primer layer and the cellulose based support layer,

wherein after the acetalisation reaction the first moiety comprises the nanofibrillar cellulose obtained from a primary cellulose having functional hydroxyl groups and the second moiety comprises the organic fragment, the organic fragment comprising at least one functional vinylic group.

2. The method according to claim 1 , wherein the first moiety and the second moiety are connected by a hemiacetal.

3. The method according to claim 1 , further comprising:
disintegrating the primary cellulose to the nanofibrillar cellulose by mechanical means.

4. The method according to claim 1 , further comprising:
oxidizing the primary cellulose or the nanofibrillar cellulose to provide nanofibrillar cellulose having functional aldehyde groups in an amount of at least 0.02 mmol/g of the amount of the primary cellulose.

5. The method according to claim 1 , wherein the nanofibrillar cellulose comprises an amount of functional aldehyde groups of at least 0.02 mmol/g of the amount of the primary cellulose.

6. The method according to claim 1 , wherein the organic fragment participating in the acetalisation reaction is
an unsaturated aldehyde having a general formula
CH 2 ═CH—(CH 2 ) n —CH═O, wherein n= 1 to 17,

or
an unsaturated alcohol having a general formula
CH 2 ═CH—(CH 2 ) n —CH—OH, wherein n= 1 to 17.

7. The method according to claim 1 , wherein the organic fragment participating in the acetalisation reaction is a water soluble carrier polymer having functional hydroxyl groups, the water soluble carrier polymer comprising at least one functional vinylic group.

8. The method according to claim 1 , wherein the cellulose based support layer is paper.

9. The method according to claim 1 , wherein the primer layer comprises the nanofibrillar cellulose equal to or less than 5% by weight of the primer layer.

10. The method according to claim 1 , wherein the nanofibrillar cellulose has a number-averaged diameter equal to or less than 400 nm.

11. A substrate layer for a release liner comprising a primer layer and a cellulose based support layer, the primer layer comprising an organic compound having one or more functional vinylic groups, the organic compound comprising an acetal connecting a first moiety and a second moiety, the first moiety comprising nanofibrillar cellulose having functional hydroxyl groups and the second moiety comprising an organic fragment, the organic fragment comprising at least one functional vinylic group.

12. The substrate layer for a release liner according to claim 11 , wherein the first moiety and the second moiety are connected by a hemiacetal.

13. The substrate layer for a release liner according to claim 11 , wherein the nanofibrillar cellulose comprises functional aldehyde groups.

14. The substrate layer for a release liner according to claim 11 , wherein the organic fragment comprises a linear or branched, saturated or unsaturated hydrocarbon chain having 2 to 20 carbon atoms, optionally interrupted by heteroatoms of N, O, or S, the organic molecule comprising at least one functional vinylic group.

15. The substrate layer for a release liner according to claim 11 , wherein the organic fragment is obtainable from the acetalisation reaction of
an unsaturated aldehyde having a general formula
CH 2 ═CH—(CH 2 ) n —CH═O, wherein n= 1 to 17,

or
an unsaturated alcohol having a general formula
CH 2 ═CH—(CH 2 ) n —CH—OH, wherein n= 1 to 17.

16. The substrate layer for a release liner according to claim 11 , wherein the organic fragment is obtainable from an acetalisation reaction of a water soluble carrier polymer having functional hydroxyl groups, the water soluble carrier polymer comprising at least one functional vinylic group.

17. The substrate layer for a release liner according to claim 11 , wherein the cellulose based support layer is paper.

18. The substrate layer for a release liner according to claim 11 , wherein the nanofibrillar cellulose has a number-averaged diameter equal to or less than 400 nm, preferably 200 nm, preferably 100 nm.

19. The substrate layer for a release liner according to claim 11 , comprising the nanofibrillar cellulose equal to or less than 5% by weight of the primer layer.

20. The substrate layer for a release liner according to claim 11 , further comprising a top layer, such as a release coating.

21. A labelstock comprising the substrate layer for a release liner according to claim 11 and an adhesive label, the adhesive label attached to the primer layer side of the substrate layer for a release liner.

Assignees

• Upm Kymmene Corp
• Upm Specialty Papers Oy

Inventors

• Rissanen Mikko
• Nuopponen Markus

Classifications

• C09J7/403

  characterised by the structure of the release feature · CPC title

• C08B15/02 Primary

  Oxycellulose; Hydrocellulose; {Cellulosehydrate, e.g. microcrystalline cellulose} · CPC title

• C09J2401/006

  in the substrate · CPC title

• C09J7/401

  characterised by the release coating composition · CPC title

• C09J2401/005

  in the release coating · CPC title