Process and system for producing acrylic acid

Patent metadata

Field	Value
Publication number	US-10112885-B2
Application number	US-201515118126-A
Country	US
Kind code	B2
Filing date	Feb 12, 2015
Priority date	Feb 20, 2014
Publication date	Oct 30, 2018
Grant date	Oct 30, 2018

Abstract

A process for recovering (meth)acrylic acid includes distilling a mixture comprising (meth)acrylic acid in a finishing column at less than atmospheric pressure to produce a finishing column overhead stream and a finishing column bottoms stream. An overhead aspirating direct contact condenser system at least partially condenses the finishing column overhead stream to form a finishing column overhead condensate and an overhead non-condensables vent stream. A finishing column vapor-phase side draw may also be recovered. An aspirating direct contact condenser system may be used to at least partially condense the vapor-phase side draw.

First claim

I claim:

1. A process for the recovery of (meth)acrylic acid using coupled distillation columns comprising a dehydration column that is coupled to a finishing column such that a tails stream from the dehydration column is fed directly or indirectly into a top of the finishing column while an overhead stream of the finishing column is fed directly or indirectly into a base of the dehydration column, the process comprising:
A. dehydrating a gaseous reaction mixture comprising (meth)acrylic acid in said dehydration column to produce a dehydration column overhead stream and a dehydration column bottoms stream, wherein the dehydrating step is carried out without using azeotropic solvent;
B. passing at least a portion of the dehydration column bottoms stream to the upper half of said finishing column;
C. subjecting the portion of the bottoms stream passed to the finishing column to distillation at less than atmospheric pressure within the finishing column to produce at least a finishing column overhead stream and a finishing column bottoms stream;
D. at least partially condensing the finishing column overhead stream using an overhead aspirating direct contact (ADC) condenser system to form a finishing column overhead condensate, and passing at least a portion of the finishing column overhead condensate to the dehydration column, wherein said ADC condenser system at least partially condenses the finishing column overhead stream and comprises at least one liquid jet eductor supplied with condensate from the finishing column overhead stream to generate a vacuum; at least one liquid-vapor separatory vessel; and at least one condensate cooler;
E. collecting (meth)acrylic acid from the finishing column; wherein said (meth)acrylic acid collected is technical grade containing at least 98.5% by weight (meth)acrylic acid, less than 0.5% water, and less than 0.4% acetic acid, and without producing a wastewater stream.

2. The process of claim 1 , wherein the finishing column is operated at a pressure of not more than 100 mmHg.

3. The process of claim 1 , wherein said liquid-vapor separatory vessel is a centrifugal separator.

4. The process of claim 1 , wherein said at least one condensate cooler is selected from the group consisting of a shell-and-tube heat exchanger, a spiral heat exchanger, a monolithic block exchanger, a jacketed pipe, and a plate-and-frame heat exchanger.

5. The process of claim 1 , further comprising cooling said finishing column overhead condensate in said condensate cooler to a temperature of 50° C. or lower.

6. The process of claim 1 further comprising introducing an inhibitor package at one or more points within said overhead aspirating direct contact condenser system.

7. The process of claim 6 , wherein the inhibitor package comprises one or more of 4-hydroxy TEMPO (4HT), soluble manganese ions, Hydroquinone (HQ), monomethyl ether hydroquinone (MeHQ), and phenothiazine (PTZ).

8. The process of claim 1 , further comprising recovering a side draw product stream from the finishing column.

9. The process of claim 8 , wherein the side draw product stream is a vapor-phase side draw product stream, the process further comprises at least partially condensing said vapor-phase side draw product stream from the finishing column using a side draw aspirating direct contact condenser system.

10. The process of claim 9 , wherein said side draw aspirating direct contact condenser system comprises:
A. at least one liquid jet eductor;
B. at least one liquid-vapor separatory vessel; and
C. at least one condensate cooler.

11. The process of claim 1 , further comprising adding oxygen-containing gas to the finishing column.

12. The process of claim 1 , wherein the overhead aspirating direct contact condenser system forms an overhead aspirating direct contact condenser system non-condensables vent stream, and at least a portion of the overhead aspirating direct contact condenser system non-condensables vent stream is transferred to the dehydration column.

13. The process of claim 1 , wherein the overhead aspirating direct contact condenser system forms an overhead aspirating direct contact condenser system non-condensables vent stream, and at least a portion of the overhead aspirating direct contact condenser system non-condensables vent stream is transferred to a thermal oxidizer.

14. The process of claim 1 , wherein the overhead aspirating direct contact condenser system forms an overhead aspirating direct contact condenser system non-condensables vent stream, and at least a portion of the overhead aspirating direct contact condenser system non-condensables vent stream is transferred to a vapor suction port of the at least one liquid jet eductor to regulate the pressure within the finishing column.

15. A process for producing technical grade (meth)acrylic acid containing at least 98.5% by weight (meth)acrylic acid, less than 0.5% water, and less than 0.4% acetic acid, the process comprising:
A. forming a gaseous reaction mixture comprising (meth)acrylic acid through the gas-phase oxidation of at least one (meth)acrylic acid precursor;
B. cooling the gaseous reaction mixture;
C. using coupled distillation columns comprising a dehydration column that is coupled to a finishing column such that a tails stream from the dehydration column is fed directly or indirectly into a top of the finishing column while an overhead stream of the finishing column is fed directly or indirectly into a base of the dehydration column, dehydrating the cooled gaseous reaction mixture in said dehydration column to produce a dehydration column overhead stream and a dehydration column bottoms stream, wherein the dehydrating is carried out without using an azeotropic solvent;
D. at least partially condensing the dehydration column overhead stream to form a condensate, and returning at least a portion of the condensate to the dehydration column as reflux;
E. dividing the dehydration column bottoms stream into at least first and second dehydration column bottom streams, and passing at least a portion of one of the first and second dehydration column bottoms stream to a dehydration column heater/re boiler and passing at least a portion of the other dehydration column bottoms stream to the upper half of said finishing column;
F. subjecting the portion of the bottoms stream passed to the finishing column to distillation at less than atmospheric pressure within the finishing column to produce at least a finishing column overhead stream and a finishing column bottoms stream comprising heavy components;
G. at least partially condensing the finishing column overhead stream using an overhead aspirating direct contact (ADC) condenser system to form a finishing column overhead condensate and an overhead aspirating direct contact condenser system non-condensables vent stream, and passing at least a portion of the finishing column overhead condensate to the dehydration column heater/reboiler, wherein said ADC condenser system at least partially condenses the finishing column overhead stream and comprises at least one liquid jet eductor supplied with condensate from the finishing column overhead stream to generate a vacuum, at least one liquid-vapor separatory vessel and at least one condensate cooler; and
H. passing at least a portion of the finishing column bottoms stream to a finishing column heater/reboiler, wherein the process produces (meth)acrylic acid without producing a wastewater stream.

16. The process of claim 15 , wherein forming a gaseous reaction mixture comprising (meth)acrylic acid through the gas-phase oxidation of at least one

Assignees

• Arkema Inc

Inventors

• Decourcy Michael S

Classifications

• C07C57/04

  Acrylic acid; Methacrylic acid · CPC title

• C07C51/44 Primary

  by distillation · CPC title

• B01D5/006

  with evaporation or distillation · CPC title

• C07C51/42

  Separation; Purification; Stabilisation; Use of additives · CPC title

• B01D5/0027

  by direct contact between vapours or gases and the cooling medium · CPC title