Metal-air battery having a device for controlling the potential of the negative electrode

Patent metadata

Field	Value
Publication number	US-10109902-B2
Application number	US-201314648307-A
Country	US
Kind code	B2
Filing date	Nov 25, 2013
Priority date	Nov 29, 2012
Publication date	Oct 23, 2018
Grant date	Oct 23, 2018

Abstract

A method for storing and releasing power using a metal-air battery, which includes: (a) a discharge phase during which a first positive air electrode is connected to the positive terminal of the battery and a second positive oxygen-release electrode is disconnected from the positive terminal of the battery; (b) a recharging phase during which the second positive oxygen-release electrode is connected to the positive terminal of the battery and the first positive air electrode is disconnected from the positive terminal of the battery, and during which the potential of the negative electrode is measured relative to the first positive air electrode. Also disclosed is a metal-air battery designed especially for implementing said method.

First claim

The invention claimed is:

1. A method for storing and releasing electrical energy using a metal-air battery comprising:
a negative terminal,
a positive terminal,
a negative electrode, connected to the negative terminal,
a positive air electrode, and
a positive oxygen evolution electrode,

the method comprising the following steps:
(a) a discharging phase during which the positive air electrode is connected to the positive terminal of the battery and the positive oxygen evolution electrode is disconnected from the positive terminal of the battery;
(b) a recharging phase during which the positive oxygen evolution electrode is connected to the positive terminal of the battery and the positive air electrode is disconnected from the positive terminal of the battery, and during which the potential of the negative electrode is measured relative to the positive air electrode used as a reference electrode;
wherein the absolute value of the potential of the negative electrode measured relative to the air electrode is controlled during the recharging phase of the metal-air battery, so that it is not above a set value determined in order to limit the formation of zinc deposits in the form of foam or dendrites on the negative electrode.

2. The method of claim 1 , wherein the value of the potential of the negative electrode during recharging is controlled automatically by an electronic charge controller.

3. The method of claim 1 , wherein, during the discharging phase, the absolute value of the potential of the negative electrode measured relative to the positive air electrode connected to the positive terminal of the battery is controlled so that it is not below a set value.

4. The method of claim 3 , wherein the value of the potential of the negative electrode during discharging is controlled automatically by an electronic discharge controller.

5. A metal-air battery comprising:
a negative terminal,
a positive terminal,
a negative electrode, connected to the negative terminal,
a positive air electrode,
a positive oxygen evolution electrode,
a switch allowing either the positive air electrode or the positive oxygen evolution electrode to be connected to the positive terminal,
a potential measurer for measuring the potential of the negative electrode, adapted for measuring the potential of the negative electrode during recharging of the battery, said measurement being performed relative to the positive air electrode used as a reference electrode, and
a charge controller adapted for keeping the absolute value of the potential measured between the negative electrode and the positive air electrode below a set value during charging of the battery, in order to limit the formation of metal deposits in the form of foam or dendrites on the negative electrode.

6. The battery of claim 5 , wherein it further comprises a discharge controller adapted for keeping the absolute value of the voltage measured between the negative electrode and the positive air electrode above a second set value, during discharging of the battery.

7. The battery of claim 5 , wherein the battery further comprises an electronic battery control system, and said charge controller and/or discharge controller form part of the electronic control system.

Assignees

• Electricite De France

Inventors

• Stevens Philippe
• Toussaint Gwenaelle

Classifications

• H01M10/48 Primary

  Accumulators combined with arrangements for measuring, testing or indicating the condition of cells, e.g. the level or density of the electrolyte (constructional details of current conducting connections for detecting conditions inside cells or batteries, e.g. details of voltage sensing terminals, H01M50/569) · CPC title

• H01M2010/4271

  Battery management systems including electronic circuits, e.g. control of current or voltage to keep battery in healthy state, cell balancing · CPC title

• H01M10/425

  Structural combination with electronic components, e.g. electronic circuits integrated to the outside of the casing (printed circuits H05K1/00) · CPC title

• Y02E60/10

  Energy storage using batteries · CPC title

• H01M12/08 Primary

  composed of a half-cell of a fuel-cell type and a half-cell of the secondary-cell type · CPC title