Gas decomposition device and power generation device

Patent metadata

Field	Value
Publication number	US-10109866-B2
Application number	US-201515309242-A
Country	US
Kind code	B2
Filing date	May 15, 2015
Priority date	May 26, 2014
Publication date	Oct 23, 2018
Grant date	Oct 23, 2018

Abstract

A gas decomposition device 100 includes one or two or more membrane electrode assemblies 5 , each including a solid electrolyte layer 2 , an anode layer 3 stacked on a first side of the solid electrolyte layer 2 , and a cathode layer 4 stacked on a second side of the solid electrolyte layer; and porous current collectors 8 a, 8 b , and 8 c including continuous pores 1 b , the membrane electrode assemblies being stacked with the porous current collector, the solid electrolyte layer being composed of a proton-conducting solid electrolyte, the porous current collectors including porous metal bodies 1 , each of the porous metal bodies 1 including an alloy layer 12 a having corrosion resistance on at least a surface of the porous metal body 1 facing the continuous pores, and the porous metal bodies forming gas channels 9 a, 9 b , and 9 c that supply gases to the anode layer and the cathode layer.

First claim

The invention claimed is:

1. A gas decomposition device comprising:
first and second membrane electrode assemblies, each including a solid electrolyte layer, an anode layer stacked on a first side of the solid electrolyte layer, and a cathode layer stacked on a second side of the solid electrolyte layer; and
a porous current collector including continuous pores,
the first and second membrane electrode assemblies being stacked with the porous current collector such that the porous current collector is interposed between the cathode layer of the first membrane electrode assembly and the anode layer of the second membrane electrode assembly,
the solid electrolyte layer being composed of a proton-conducting solid electrolyte,
the porous current collector including a porous metal body that includes an alloy layer having corrosion resistance on at least a surface of the porous metal body facing the continuous pores,
a tin content in a portion of the porous metal body adjacent to the cathode layer of the first membrane electrode assembly being different than a tin content in a portion of the porous metal body adjacent to the anode layer of the second membrane electrode assembly, and
the porous metal body forming a gas channel that supplies a gas to the anode layer of the second membrane electrode assembly and the cathode layer of the first membrane electrode assembly.

2. The gas decomposition device according to claim 1 , wherein the alloy layer is composed of a nickel (Ni)-tin (Sn) alloy and has a tin content of 10% to 20% by mass.

3. The gas decomposition device according to claim 1 , wherein the tin content in the portion of the porous metal body adjacent to the cathode layer of the first membrane electrode assembly is higher than the tin content in the portion of the porous metal body adjacent to the anode layer of the second membrane electrode assembly.

4. The gas decomposition device according to claim 1 , wherein the porous metal body has a porosity of 30% to 98% and a pore size of 0.1 mm or more and 1 mm or less.

5. The gas decomposition device according to claim 1 , wherein the portion of the porous metal body adjacent to the cathode layer of the first membrane electrode assembly has higher porosity than the portion of the porous metal body adjacent to the anode layer of the second membrane electrode assembly.

6. The gas decomposition device according to claim 1 , wherein the portion of the porous metal body adjacent to the cathode layer of the first membrane electrode assembly larger pore size than the portion of the porous metal body adjacent to the anode layer of the second membrane electrode assembly.

7. The gas decomposition device according to claim 1 , wherein a side of the porous metal body that receives a gas inflow has a smaller pore size than a side of the porous metal body that does not receive the gas inflow.

8. The gas decomposition device according to claim 1 , wherein the porous metal body includes a skeleton that includes a shell portion and a core portion, the core portion containing one or both of a hollow portion and a conductive material, and wherein the skeleton has a three-dimensional mesh-like structure having an integrated continuous form.

9. The gas decomposition device according to claim 1 , wherein the anode layer of each membrane electrode assembly has a thickness of 100 μm or more and 1000 or less.

10. The gas decomposition device according to claim 1 , wherein the cathode layer of each membrane electrode assembly has a thickness of 10 μm or more and 100 μm or less.

11. A power generation device comprising the gas decomposition device according to claim 1 .

Assignees

• Sumitomo Electric Industries

Inventors

• Hiraiwa Chihiro
• Majima Masatoshi
• Tawarayama Hiromasa
• Mizuhara Naho
• Higashino Takahiro
• Noda Yohei

Classifications

• B01D53/326

  in electrochemical cells · CPC title

• H01M8/02

  Details (electrodes H01M4/86 - H01M4/98) · CPC title

• H01M8/00

  Fuel cells; Manufacture thereof · CPC title

• B01D2257/7025

  Methane · CPC title

• H01M8/06

  Combination of fuel cells with means for production of reactants or for treatment of residues (regenerative fuel cells H01M8/18) · CPC title