Method of making vacuum insulated glass (VIG) window unit

Patent metadata

Field	Value
Publication number	US-10107028-B2
Application number	US-201615090821-A
Country	US
Kind code	B2
Filing date	Apr 5, 2016
Priority date	Feb 22, 2011
Publication date	Oct 23, 2018
Grant date	Oct 23, 2018

Abstract

Certain example embodiments relate to seals for glass articles. Certain example embodiments relate to a composition used for sealing an insulted glass unit. In certain example embodiments the composition includes vanadium oxide, barium oxide, zinc oxide, and at least one additional additive. For instance, another additive that is a different metal oxide or different metal chloride may be provided. In certain example embodiments, a composition may be combined with a binder solution that substantially or completely burns out by the time the composition is melted. In certain example embodiments, a vacuum insulated glass unit includes first and second glass substrates that are sealed together with a seal that includes the above-described composition.

First claim

What is claimed is:

1. A method of making a vacuum insulated glass (VIG) window unit, the method comprising:
providing a sealing material on, directly or indirectly, a first glass substrate and/or a second glass substrate, the material comprising at least a frit material and a binder solution;
wherein the first and second glass substrates are thermally tempered;
providing the first and second glass substrates in substantially parallel, spaced apart relation to one another, where the sealing material is provided on at least one of the glass substrates, and a gap being defined between the first and second substrates, and wherein at least a portion of the sealing material is located between the first and second glass substrates;
applying energy to the frit material so as to melt the frit material at least at a melting temperature, the melting temperature being less than about 400 degrees C.,
wherein after the energy is applied the first and second glass substrates are sealed to each other directly or indirectly in making the VIG window unit, and
wherein the frit material is formed from a base composition comprising:

Ingredient
Normalized Mole %

vanadium oxide
>=35%

barium oxide
15-35%

zinc oxide
<=25%

tellurium oxide
 1-10%

molybdenum oxide
 1-6%,

wherein the vanadium oxide, the barium oxide, and the zinc oxide are the largest three elements making up the base composition of the frit material.

2. The method of claim 1 , wherein the applying of the energy to the frit material includes: holding a temperature of the frit material at a first temperature for a first period of time; and increasing the temperature of the frit material to the melting temperature over a second period of time.

3. The method of claim 2 , wherein the first period of time is greater than the second period of time.

4. The method of claim 1 , wherein prior to applying the energy, a ratio between the frit material and the binder solution is about 5 to 1.

5. The method of claim 1 , further comprising evacuating the gap between the first and second glass substrates to a pressure less than atmospheric pressure after a seal has been formed via at least said frit material.

6. A method of making a vacuum insulated glass (VIG) window unit, the method comprising:
providing a sealing material on, directly or indirectly, a first glass substrate and/or a second glass substrate, the sealing material comprising at least a frit material;
providing the first and second glass substrates in substantially parallel, spaced apart relation to one another, where the sealing material is provided on at least one of the first and second glass substrates, and a gap being defined between the first and second substrates, and wherein at least a portion of the sealing material is located between the first and second glass substrates;
applying energy to the frit material so as to melt the frit material at least at a melting temperature, the melting temperature being less than about 400 degrees C.,
wherein after the energy is applied the first and second glass substrates are sealed to each other, directly or indirectly, in making the VIG window unit, and
wherein the frit material is formed from a base composition comprising:

Ingredient
Normalized Mole %

vanadium oxide
>=35%

barium oxide
15-35%

zinc oxide
<=25%

tellurium oxide
 1-10%

molybdenum oxide
  1-6%,

wherein the vanadium oxide, the barium oxide, and the zinc oxide are the largest three elements making up the base composition of the frit material.

7. The method of claim 6 , wherein the applying of the energy to the frit material includes: holding a temperature of the frit material at a first temperature for a first period of time; and increasing the temperature of the frit material to the melting temperature over a second period of time.

8. The method of claim 7 , wherein the first period of time is greater than the second period of time.

9. The method of claim 6 , further comprising evacuating the gap between the first and second glass substrates to a pressure less than atmospheric pressure after a seal has been formed via at least said frit material.

10. The method of claim 6 , wherein a plurality of spacers is provided between the first and second glass substrates.

11. The method of claim 6 , wherein the first and second glass substrates are thermally tempered.

Assignees

• Guardian Glass Llc

Inventors

• Dennis Timothy A

Classifications

• C03C8/24 Primary

  Fusion seal compositions being frit compositions having non-frit additions, i.e. for use as seals between dissimilar materials, e.g. glass and metal; Glass solders · CPC title

• C03C8/06

  containing halogen · CPC title

• C03C3/122

  containing oxides of As, Sb, Bi, Mo, W, V, Te as glass formers · CPC title

• C03C3/062

  with less than 40% silica by weight · CPC title

• E06B3/67334

  by soldering; Preparing the panes therefor · CPC title