Method for producing noble metal nanocomposites

Patent metadata

Field	Value
Publication number	US-10106895-B2
Application number	US-201715474760-A
Country	US
Kind code	B2
Filing date	Mar 30, 2017
Priority date	Mar 24, 2015
Publication date	Oct 23, 2018
Grant date	Oct 23, 2018

Abstract

The method for producing noble metal nanocomposites involves reducing noble metal ions (Ag, Au and Pt) on graphene oxide (GO) or carbon nanotubes (CNT) by using Artocarpus integer leaves extract as a reducing agent. As synthesized MNPs/GO and MNPs/CNT composites have been characterized using X-ray diffraction (XRD), transmission electron microscope (TEM) imaging, and energy dispersive X-ray spectroscopy (EDX). The TEM images of prepared materials showed that the nanocomposites were 1-30 nm in size with spherical nanoparticles embedded on the surface of GO and CNT. This synthetic route is easy and rapid for preparing a variety of nanocomposites. The method avoids use of toxic chemicals, and the prepared nanocomposites can be used for biosensor, fuel cell, and biomedical applications.

First claim

We claim:

1. A method for producing noble metal nanocomposites, comprising the steps of:
functionalizing carbon nanotubes;
preparing an aqueous solution of the functionalized carbon nanotubes;
adding an aqueous solution of a salt of a noble metal to the solution of the functionalized carbon nanotubes to form a complex of the functionalized carbon nanotubes and the noble metal ion in aqueous solution, wherein the noble metal is platinum; and
reducing the noble metal ion on the carbon nanotubes by adding an extract of Artocarpus integer leaves to the aqueous solution of the noble metal ion-functionalized carbon nanotubes complex, thereby forming a composite of nanoparticles of the reduced noble metal on the functionalized carbon nanotubes, the nanoparticles being embedded on a surface of the carbon nanotubes and having a particle size between 1 nm and 3 nm.

2. The method for producing noble metal nanocomposites according to claim 1 , wherein the carbon nanotubes are functionalized by oxidation in an acid, the oxidation including refluxing the carbon nanotubes with the acid.

3. The method for producing noble metal nanocomposites according to claim 1 , wherein the nanoparticles are substantially spherical.

4. The method for producing noble metal nanocomposites according to claim 1 , wherein said step of adding the aqueous solution of a salt of a noble metal to the solution of the functionalized carbon nanotubes comprises adding the aqueous solution of a salt of a noble metal drop-wise.

5. The method for producing noble metal nanocomposites according to claim 1 , further comprising the step of preparing the extract of Artocarpus integer leaves, including the steps of:
washing Artocarpus integer leaves several times with deionized water;
chopping the washed leaves;
stirring the chopped leaves in distilled water at 95° C. for about 5 minutes to obtain the leaf extract; and
filtering to remove the chopped leaves from the leaf extract.

Assignees

• Univ King Saud

Inventors

• Alshatwi Ali A
• Athinarayanan Jegan
• Periasamy Vaiyapuri Subbarayan

Classifications

• Y10S977/904

  for medical, immunological, body treatment, or diagnosis · CPC title

• Y10S977/92

  Detection of biochemical · CPC title

• Y10S977/748

  Modified with atoms or molecules bonded to the surface · CPC title

• Y10S977/892

  Liquid phase deposition · CPC title

• Y10S977/81

  Of specified metal or metal alloy composition · CPC title