Systems and methods for in-situ etching prior to physical vapor deposition in the same chamber
US-2024167144-A1 · May 23, 2024 · US
US10106866B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10106866-B2 |
| Application number | US-201415108260-A |
| Country | US |
| Kind code | B2 |
| Filing date | Dec 17, 2014 |
| Priority date | Dec 24, 2013 |
| Publication date | Oct 23, 2018 |
| Grant date | Oct 23, 2018 |
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An exemplary embodiment of the present invention provides a coated steel sheet on which a magnesium-aluminum alloy coating layer is formed, including: a steel sheet; and a coating layer configured to include a first magnesium-aluminum alloy layer formed on a top surface of the steel sheet and a second magnesium-aluminum alloy layer formed on a top surface of the first magnesium-aluminum alloy layer, wherein a magnesium content of the first magnesium-aluminum alloy layer is higher than that of the second magnesium-aluminum alloy layer.
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The invention claimed is: 1. A coated steel sheet on which a magnesium-aluminum alloy coating layer is formed, the coated steel sheet comprising: a steel sheet; and a coating layer configured to include a first magnesium-aluminum alloy layer formed on a top surface of the steel sheet and a second magnesium-aluminum alloy layer formed on a top surface of the first magnesium-aluminum alloy layer, wherein a magnesium content of the first magnesium-aluminum alloy layer as a wt % of the first magnesium-aluminum alloy layer is higher than that of the second magnesium-aluminum alloy layer as a wt % of the second magnesium-aluminum alloy layer, wherein the second magnesium-aluminum alloy layer contains columnar crystals, wherein the magnesium content of the first magnesium-aluminum alloy layer is in a range of 20 to 95 wt %, and the magnesium content of the second magnesium-aluminum alloy layer is in a range of 5 to 40 wt %, wherein a total magnesium content of the coating layer formed by the first magnesium-aluminum alloy layer and the second magnesium-aluminum alloy layer is equal to or greater than 12.5 wt %, and wherein each of the first magnesium-aluminum alloy layer and the second magnesium-aluminum alloy layer has a thickness in a range of 0.5 to 30 μm. 2. The coated steel sheet of claim 1 , wherein a total thickness of the coating layer formed on the steel sheet by the first magnesium-aluminum alloy layer and the second magnesium-aluminum alloy layer is in a range of 1 to 50 μm. 3. The coated steel sheet of claim 1 , wherein a total thickness of the coating layer formed on the steel sheet by the first magnesium-aluminum alloy layer and the second magnesium-aluminum alloy layer is equal to or smaller than 5 μm. 4. A coated steel sheet on which a magnesium-aluminum alloy coating layer is formed, the coated steel sheet comprising: a steel sheet; and a coating layer configured to include a first magnesium-aluminum alloy layer formed on a top surface of the steel sheet and a second magnesium-aluminum alloy layer formed on a top surface of the first magnesium-aluminum alloy layer, wherein a magnesium content of the first magnesium-aluminum alloy layer as a wt % of the first magnesium-aluminum alloy layer is higher than that of the second magnesium-aluminum alloy layer as a wt % of the second magnesium-aluminum alloy layer, and wherein the coating layer contains a mixture of α-phase Al and β-phase Al 3 Mg 2 . 5. The coated steel sheet of claim 4 , wherein a part or all of the coating layer is formed to have a crystal grain shape. 6. The coated steel sheet of claim 5 , wherein each of the α-phase Al and the β-phase Al 3 Mg 2 forms crystal grains, and an average size of the crystal grains is in a range of 0.1 to 2 μm. 7. The coated steel sheet of claim 6 , wherein an area ratio of β-phase/α-phase of the coating layer crystal grain is in a range of 10 to 70%. 8. The coated steel sheet of claim 7 , wherein a ratio of α- and β-phases is in a range of 0.01 to 1.5 as an XRD intensity ratio, which is Iβ(880)/Iα(111).
Metallic sublayers · CPC title
Containing more than 10% nonferrous elements [e.g., high alloy, stainless] · CPC title
including components having same physical characteristic in differing degree · CPC title
on hard metal substrates · CPC title
Thermal treatment · CPC title
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