Method for producing biomethane incorporating the production of heat for the methaniser using membrane separation

Patent metadata

Field	Value
Publication number	US-10106756-B2
Application number	US-201415037198-A
Country	US
Kind code	B2
Filing date	Nov 6, 2014
Priority date	Nov 18, 2013
Publication date	Oct 23, 2018
Grant date	Oct 23, 2018

Abstract

The present invention relates to a process for producing biomethane suitable for supplying a natural gas network that incorporates a process for providing heat for heating the biogas production step, the process comprising at least steps of producing biogas by anaerobic fermentation of organic matter, of pretreating and compressing the biogas and also of permeation in order to obtain, after a first separation by permeation, a stream of biomethane and a gaseous permeate having a reduced methane content; the process additionally provides the heat necessary for the anaerobic fermentation step via a boiler using the retentate from a second permeation step fed by the permeate from the first separation.

First claim

What is claimed is:

1. A process for producing biomethane suitable for supplying a natural gas network that incorporates a process for providing heat for heating the biogas production step, wherein the biomethane production process comprises at least:
a step (a) of producing biogas by methanization of organic matter;
a step (b) of pretreating the biogas produced during step (a);
a step (c) of compressing the pretreated biogas with a compressor;
a step (d) of using a first gas separation module to separate, by permeation, the pretreated and compressed biogas resulting from step (c) in order to produce, in comparison to the pretreated and compressed biogas, a first methane-enriched gaseous retentate having a methane content of greater than 89% and a first methane-depleted gaseous permeate having a methane content of between 10% and 25%;
a step (e) of providing the gaseous retentate from step (d) as biomethane;
a step (f) of heating water in a heating water circuit including a gas boiler having burners, heat being provided to step (a) via the heating water circuit;
a step (g) of separating by permeation the first methane-depleted gaseous permeate to produce, in comparison to the first methane-depleted gaseous permeate, a second methane-enriched gaseous retentate and a second methane-depleted permeate, the methane content of the second methane-enriched gaseous retentate of step (g) being greater than or equal to 25%;
a step (h) of supplying the burners of the boiler from step (f) with the second methane-enriched gaseous retentate from the separation step (g) as fuel for consumption by the burners; and
a step (i) of discharging the permeate produced by the permeation separation step (g).

2. The process of claim 1 , further comprising a step (j) of providing additional heat to the water circulating in said heating water circuit using heat recovered during steps (b) and (c).

3. The process of claim 1 , wherein a variable fraction of the methane-enriched retentate from the separation step (g) is sent back to an inlet of the compressor of step (c) when the supply of heat to step (a) is greater than heat requirements of step (a).

4. The process of claim 1 , wherein the gaseous retentate resulting from performance of step (d) has a methane content of greater than 96.5%.

5. The process of claim 1 , wherein the gaseous retentate resulting from performance of step (g) has a methane content of between 30% and 40%.

6. A plant for carrying out the process of claim 1 for producing biomethane intended for supplying a natural gas network and the integrated provision of heat for heating the biogas production step, said plant comprising at least:
a biomethane production unit comprising at least a source of organic matter, a digester for producing biogas by methanization of said organic matter, and a module for prepurifying the biogas produced;
a compressor suitable for compressing the prepurified biogas;
a first gas separation module for separating, by membrane permeation, the prepurified and compressed biogas, said first module being suitable for producing a gaseous retentate having a methane content of greater than 89% and a gaseous permeate having a methane content of between 10% and 25%;
a system for heating the organic matter contained in the digester comprising at a heating water circuit suitable for heating the digester and a gas boiler being suitable for heating the water of the heating water circuit; and
a second module for separating, by membrane permeation, the gaseous permeate resulting from the first permeation separation module, said second module being suitable for producing a methane-depleted permeate and a methane-enriched gaseous retentate having methane content greater than 25, wherein the second module provides the gaseous retentate retentate thereof as biogas, the second separation module supplies the retentate thereof to the burners of said gas boiler, and the second separation module discharges the permeate resulting therefrom.

7. The plant of claim 6 , wherein the means suitable for cooperating in order to heat the organic matter contained in the digester comprise additional means suitable for recovering heat from the biogas prepurification module and the prepurified biogas compressor and also additional means suitable for providing the heat recovered to the water of the heating circuit of the digester.

8. The plant of claim 6 , further comprising a line equipped with a flow control valve suitable for recycling a fraction of the retentate from the second membrane stage to the inlet of the compressor.

9. The plant of claim 6 , wherein said first module is suitable for producing a gaseous retentate having a methane content of greater than 96.5%.

10. The plant of claim 6 , wherein a second module is suitable for producing the methane-enriched gaseous retentate at a methane content of between 30% and 40%.

Assignees

• Air Liquide
• Air Liquide

Inventors

• Paget Nicolas
• Garnaud Delphine
• Prince Guénaël
• Lefebvre Mathieu

Classifications

• B01D53/22

  by diffusion (manufacturing semi-permeable membranes B01D67/00; form, structure or properties of semi-permeable membranes B01D69/00; material for semi-permeable membranes B01D71/00) · CPC title

• B01D2258/05

  Biogas · CPC title

• C10L2290/02

  Combustion or pyrolysis · CPC title

• C10L2290/10

  Recycling of a stream within the process or apparatus to reuse elsewhere therein · CPC title

• C10L2290/30

  Pressing, compressing or compacting · CPC title