Rapid estimation of feed potential for base oil formation

Patent metadata

Field	Value
Publication number	US-10106751-B2
Application number	US-201615368888-A
Country	US
Kind code	B2
Filing date	Dec 5, 2016
Priority date	Dec 10, 2015
Publication date	Oct 23, 2018
Grant date	Oct 23, 2018

Abstract

Methods are provided for rapidly characterizing a feedstock being considered for lubricant base oil production in order to determine the viscosity index potential of the feedstock. It has unexpectedly been discovered that the DDVI value for a feedstock at a specified pour point can be predicted based on a) the feed distillate residual wax content at a temperature as determined by Differential Scanning Calorimetry, such as the feed distillate residual wax content at a temperature corresponding to the specified pour point temperature; b) the feed distillate refractive index; c) the feed distillate kinematic viscosity at a temperature, such as kinematic viscosity at 100° C.; and d) the distillate volume-averaged boiling point. Based on this unexpected correlation, the VI potential of a feedstock can be determined based on measurement of properties that can be performed on a time scale corresponding to one or a few days using a few milliliters of feedstock.

First claim

The invention claimed is:

1. A method for determining feedstock quality for lubricant base oil production, comprising:
determining a wax content of a distillate feedstock fraction by differential scanning calorimetry;
obtaining a characteristic boiling point, a characteristic viscosity, and a refractive index for the distillate feedstock fraction;
calculating a distillate dewaxed viscosity index (DDVI) at a DDVI-temperature for the distillate feedstock fraction based on the determined wax content and at least two of the obtained characteristic boiling point, the obtained characteristic viscosity, and the obtained refractive index, the calculated DDVI being at least 0 at the DDVI-temperature; and
processing the feedstock to form a lubricant base oil having a viscosity index of at least 80 and a pour point of 0° C. or less.

2. The method of claim 1 , wherein the DDVI-temperature is −9° C.

3. The method of claim 1 , wherein the wax content of the distillate feedstock fraction is determined based on the relationship W=ΔH/A(T), where W is the wax content, ΔH is a heat of fusion, T is a temperature where a freezing transition occurs, and A(T) is a scaling factor.

4. The method of claim 1 , wherein obtaining at least one of the characteristic boiling point, the characteristic viscosity, and the refractive index comprises measuring the at least one of the characteristic boiling point, the characteristic viscosity, and the refractive index.

5. The method of claim 1 , wherein the characteristic viscosity comprises a kinematic viscosity at 40° C.

6. The method of claim 1 , wherein the characteristic viscosity comprises a kinematic viscosity at 100° C.

7. The method of claim 1 , wherein the characteristic boiling point comprises a volume average boiling point.

8. The method of claim 1 , wherein the refractive index comprises a refractive index at 75° C.

9. The method of claim 1 , wherein the distillate dewaxed viscosity index at the DDVI temperature is calculated based on the formula:
DDVI= A 10 −A 11 *XRI−A 12 *e a121 DWX 09 a122 *(ln( Ykv 100+0.6)) a123 +A 13 *ZVABP−A 14 *ln(ln( Ykv 100+0.6)).

10. The method of claim 1 , wherein the distillate feedstock fraction comprises a fraction having a T5 boiling point of at least 650° F., a T95 boiling point of 1100° F. or less, or a combination thereof.

11. The method of claim 1 , wherein processing the feedstock comprises solvent processing, hydroprocessing, or a combination thereof.

12. The method of claim 1 , wherein processing the feedstock further comprises determining a suitability of the lubricant base oil for satisfying at least one of a filterability test or a flocculation test based on determining a slope of a cooling trace measured by differential scanning calorimetry.

13. The method of claim 12 , wherein the suitability of the lubricant base oil is based on the determined slope of the cooling trace being at least 0.008 W/g° C.

14. The method of claim 12 , wherein the suitability of the lubricant base oil is based on the determined slope of the cooling trace being at least 0.01 W/g° C.

15. A method for determining feedstock quality for lubricant base oil production, comprising:
determining a wax content of a distillate feedstock fraction by differential scanning calorimetry;
measuring at least two of a characteristic boiling point, a characteristic viscosity, and a refractive index for the distillate feedstock fraction;
calculating a distillate dewaxed viscosity index (DDVI) at −9° C. for the distillate feedstock fraction based on the determined wax content and the measured at least two of the characteristic boiling point, the characteristic viscosity, and the refractive index, the calculated DDVI being at least 0 at −9° C.; and
processing the feedstock to form a lubricant base oil having a viscosity index of at least 80 and a pour point of 0° C. or less.

16. The method of claim 15 , wherein the wax content of the distillate feedstock fraction is determined based on the relationship W=ΔH/A(T), where W is the wax content, ΔH is a heat of fusion, T is a temperature where a freezing transition occurs, and A(T) is a scaling factor.

Assignees

• Exxonmobil Res & Eng Co

Inventors

• Gong Liezhong
• Powers Corry S
• Joseck Eric D
• Gooding Beatrice M

Classifications

• C10G2300/30

  Physical properties of feedstocks or products · CPC title

• G01N33/30

  for lubricating properties · CPC title

• C10G73/42

  Refining of petroleum waxes · CPC title

• C10G45/02

  to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing · CPC title

• C10G45/00

  Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds · CPC title