Insulator material composition and method

Patent metadata

Field	Value
Publication number	US-10106710-B2
Application number	US-201414541103-A
Country	US
Kind code	B2
Filing date	Nov 13, 2014
Priority date	Nov 13, 2013
Publication date	Oct 23, 2018
Grant date	Oct 23, 2018

Abstract

An electrical insulator material includes a polymer and a solvent, and has a viscosity in the range of from about 1.0 to about 20.0 cP such that the electrical insulator material can be applied to a surface using an ink jet print head.

First claim

We claim:

1. An electrical insulator material comprising a polymer and a solvent, wherein the electrical insulator material has a viscosity in the range of from about 1.0 to about 20.0 cP such that the electrical insulator material can be applied to a surface in a layer using an ink jet print head and heated to form a void-free continuous film; and
wherein the polymer is present in an amount from about 0.5% to about 6.0% by weight, wherein the solvent is present in an amount from about 30.0% to about 99.5% by weight, and wherein the polymer comprises a poly(amide imide), a linear copolyester, or a combination thereof.

2. The electrical insulator material of claim 1 , wherein the viscosity is in the range of from about 3.4 cP to about 5.5 cP.

3. The electrical insulator of claim 1 , wherein the electrical insulator material has a dynamic surface tension in a range from about 25 dynes/cm to about 45 dynes/cm.

4. The electrical insulator material of claim 1 , wherein the solvent comprises n-methyl-2-pyrrolidone.

5. The electrical insulator material of claim 1 , wherein the insulator material does not degrade in gamma butyrolactone.

6. The electrical insulator material of claim 1 , further comprising a crosslinking agent.

7. The electrical insulator material of claim 1 , further comprising a device for use in an ink jet print operation comprising:
a housing;
a series of ejection nozzles mounted within the housing, each ejection nozzle capable of ejecting a drop on demand; and
a source of the electrical insulator material communicating with the nozzles.

8. The electrical insulator material of claim 1 , wherein the insulator material is disposed in a layer having a thickness of about 25 microns to about 100 microns.

9. The electrical insulator material of claim 8 , wherein the insulator material is disposed in a layer having a thickness of about 35 microns to about 45 microns.

10. The electrical insulator material of claim 1 , wherein the surface is one of a substrate and an intermediate layer disposed on the substrate.

11. The electrical insulator material of claim 10 , wherein the intermediate layer is an adhesive material.

12. An electrical insulator material comprising a polymer and a solvent, wherein the electrical insulator material has a viscosity in the range of from about 1.0 to about 20.0 cP such that the electrical insulator material can be applied to a surface in a layer using an ink jet print head and heated to form a void-free continuous film;
wherein the polymer comprises a linear copolyester;
wherein the linear copolyester is present in an amount of from about from about 1% to about 20% by weight and wherein the solvent is present in an amount of from about 1% to about 99% by weight; and
wherein the solvent comprises toluene, xylene, and cyclohexanone, and combinations thereof.

13. A method of manufacturing a battery using an ink jet print head comprising the steps of:
jetting an electrical insulator material onto a surface, wherein the electrical insulator material comprises a polymer and a solvent and has a viscosity in the range of from about 1.0 to about 20.0 cP such that the electrical insulator material can be applied to a surface in a layer using an ink jet print head and heated to form a void-free continuous film, and wherein the polymer is present in an amount from about 0.5% to about 6.0% by weight, wherein the solvent is present in an amount from about 30.0% to about 99.5% by weight, and wherein the polymer comprises a poly(amide imide), a linear copolyester, or a combination thereof; and
vaporizing a portion of the solvent.

14. The method of claim 13 , wherein the viscosity is in the range of from about 3.4 cP to about 5.5 cP.

15. The method of claim 13 , wherein the electrical insulator material forms a layer having a thickness of about 25 microns to about 100 microns.

16. The method of claim 13 , wherein the electrical insulator material forms a layer having a thickness of about 35 microns to about 45 microns.

17. The method of claim 13 , wherein the electrical insulator material forms a layer having an electrical resistance greater than 125 megaohms.

18. The method of claim 17 , wherein the electrical insulator material forms a layer having an electrical resistance greater than 550 megaohms.

19. The method of claim 13 , wherein the electrical insulator material is jetted from an ink jet print head, and the method further comprises relative movement of the ink jet print head over the substrate to form a layer thereon.

20. The method of claim 13 , wherein the surface comprises one of a substrate and an intermediate layer atop the substrate.

21. The method of claim 20 , wherein the intermediate layer is an adhesive material.

22. The method of claim 13 , wherein the substrate is heated to promote vaporization of the solvent.

Assignees

• Donnelley & Sons Co

Inventors

• Cyman Jr Theodore F
• Hook Kevin J
• Geddes Pamela
• Murzynowski Alan R
• Blease James W
• Kanfoush Daniel E

Classifications

• B05B15/60

  Arrangements for mounting, supporting or holding spraying apparatus · CPC title

• H01M4/382

  Lithium (H01M4/405 takes precedence) · CPC title

• H01M6/40

  Printed batteries {, e.g. thin film batteries} · CPC title

• C09D11/52

  Electrically conductive inks · CPC title

• H01M6/188

  Processes of manufacture · CPC title