Degradable polymeric compositions and articles comprising same
US-2024425683-A1 · Dec 26, 2024 · US
US10106659B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10106659-B2 |
| Application number | US-201314652526-A |
| Country | US |
| Kind code | B2 |
| Filing date | Dec 24, 2013 |
| Priority date | Dec 27, 2012 |
| Publication date | Oct 23, 2018 |
| Grant date | Oct 23, 2018 |
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A molding film is high in both windability during film production and also excellent in appearance quality and moldability. The molding film includes cyclic olefin based resin, has roughened regions in side edge parts of the molding film, is non-oriented, and satisfies (1) to (3): (1) one of the surfaces has a surface roughness SRa of 2 nm or more and 30 nm or less in the central region, which is defined as the region outside the roughened regions, whereas the other surface has a surface roughness SRa of 100 nm or more and 800 nm or less, (2) the ratio h/t where h represents the height (in μm) of the roughened regions while t represents the thickness (in μm) of the central region is 5/100 or more and 30/100 or less, and (3) the width of the roughened regions is 5 mm or more and 20 mm or less.
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The invention claimed is: 1. A non-oriented molding film having a machine direction, a transverse direction, a thickness direction, and comprising a cyclic olefin based resin wherein: a surface of the molding film comprises a central region and side edge parts located on each side of the central region in the transverse direction; the side edge parts comprise roughened regions extending in the machine direction along the molding film; and the film satisfies (1) to (3): (1) a surface of the molding film has a surface roughness SRa of 2 nm or more and 30 nm or less in the central region of the transverse direction and along the machine direction and defined as a region outside roughened regions, whereas an opposing surface of the molding film has a surface roughness SRa of 100 nm or more and 800 nm or less, (2) ratio h/t where h represents height (in pm) of the roughened regions while t represents thickness (in pm) of the central region is 5/100 or more and 30/100 or less, and (3) width of the roughened regions is 5 mm or more and 20 mm or less, wherein the thickness of the central region is 50 pm or more and 200 pm or less. 2. The molding film as described in claim 1 in the form of a multilayer film containing layer A and layer B, wherein layer A is composed primarily of a cyclic olefin copolymer resin (COC) and layer B is composed primarily of a cyclic olefin polymer resin (COP). 3. The molding film as described in claim 2 , wherein the multilayer film comprises layer B, layer A, and layer B directly stacked in this order. 4. The molding film as described in claim 2 , wherein layer A in the multilayer film has a glass transition temperature of 70° C. or more and 140° C. or less. 5. The molding film as described in claim 2 , wherein layer B in the multilayer film has a glass transition temperature of 70° C. or more and 140° C. or less and that is equal to or higher than the glass transition temperature of layer A. 6. The molding film as described in claim 1 in the form of a monolayer film having a glass transition temperature of 70° C. or more and 140° C. or less. 7. A film roll comprising a core and the molding film as described in claim 1 wound up thereon. 8. A transfer foil comprising a clear layer, a decorating layer, and an adhesive layer stacked in this order on at least one side of molding film as described in claim 1 . 9. The molding film as described in claim 3 , wherein layer A in the multilayer film has a glass transition temperature of 70° C. or more and 140° C. or less. 10. The molding film as described in claim 3 , wherein layer B in the multilayer film has a glass transition temperature of 70° C. or more and 140° C. or less and that is equal to or higher than the glass transition temperature of layer A. 11. The molding film as described in claim 4 , wherein layer B in the multilayer film has a glass transition temperature of 70° C. or more and 140° C. or less and that is equal to or higher than the glass transition temperature of layer A. 12. The molding film as described in claim 1 in the form of a monolayer film having a glass transition temperature of 70° C. or more and 140° C. or less. 13. A film roll comprising a core and the molding film as described in claim 2 wound up thereon. 14. A film roll comprising a core and the molding film as described in claim 3 wound up thereon. 15. A film roll comprising a core and the molding film as described in claim 4 wound up thereon. 16. A film roll comprising a core and the molding film as described in claim 5 wound up thereon.
Polymer derived only from ethylenically unsaturated monomer · CPC title
not modified by chemical after treatment · CPC title
Manufacture of films or sheets · CPC title
Vehicles · CPC title
Buildings or parts thereof · CPC title
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