Method for producing a composite body of a material with a high silicic acid content

Patent metadata

Field	Value
Publication number	US-10106453-B2
Application number	US-201615358287-A
Country	US
Kind code	B2
Filing date	Nov 22, 2016
Priority date	Nov 25, 2015
Publication date	Oct 23, 2018
Grant date	Oct 23, 2018

Abstract

A low cost method for producing a mechanically and thermally stable composite body containing a first layer of a material with a high silicic acid content and an additional component connected to a second layer of a material with a high silicic acid content and an additional component in a second concentration differing from the first concentration is provided. The method involves (a) preparing a first slurry layer having a free surface using a first shirt mass containing SiO2 particles and an additional component dispersed in a first dispersing agent, (b) providing a second slurry mass containing SiO2 particles and an additional component in a second concentration dispersed in a second dispersing agent, (c) forming a composite-body intermediate product by applying the second slurry mass to the free surface of the first slurry layer, and (d) heating the composite-body intermediate product while forming the composite body.

First claim

We claim:

1. A method for producing a composite body comprising a first layer of a material having a high silicic acid content and a first additional component in a first concentration connected to a second layer of a material having a high silicic acid content and a second additional component in a second concentration that differs from the first concentration, wherein the first and the second concentrations are greater than or equal to zero, the method comprising the following steps:
(a) preparing a first slurry layer having a free surface from a first slurry mass containing first SiO 2 particles and the first additional component in the first concentration dispersed in a first dispersing agent,
(b) providing a second slurry mass containing second SiO 2 particles and the second additional component in a second concentration that differs from the first concentration dispersed in a second dispersing agent,
(c) forming a composite-body intermediate product by applying the second slurry mass to the free surface of the first slurry layer, and
(d) heating the composite-body intermediate product while forming the composite body.

2. The method according to claim 1 , wherein each of the first and the second SiO 2 -containing slurry masses has a solids content of at least 65% by wt.

3. The method according to claim 1 , wherein the solids contents of the first and the second SiO 2 -containing slurry masses differ by not more than 5% by wt.

4. The method according to claim 1 , wherein the preparation of the first slurry layer according to step (a) and the formation of the composite-body intermediate product according to step (c) are carried out by introducing the first and the second SiO 2 slurry masses into an absorbent mold one after the other.

5. The method according to claim 1 , wherein the preparation of the first slurry layer according to step (a) comprises a settling phase of at least 30 minutes, followed by removing a supernatant of the first slurry mass from the surface of the first slurry layer.

6. The method according to claim 1 , wherein the second SiO 2 -containing slurry mass is applied by a pouring stream guided at an angle in a range of 3° to 15° relative to the free surface of the first slurry layer.

7. The method according to claim 6 , wherein the pouring stream has an elongated shape in a horizontal cross-section.

8. The method according to claim 1 , wherein the first and the second SiO 2 -containing slurry masses contain amorphous SiO 2 particles in a splintery and/or spherical form with particle sizes in a range of 1 μm to 50 μm.

9. The method according to claim 1 , wherein at least one of the first and the second additional components contains silicon particles and/or carbon particles.

10. The method according to claim 9 , wherein the silicon particles are contained with a solids content in a range of 0.1% by wt. to 5% by wt.

11. The method according to claim 9 wherein the carbon particles are contained with a solids content in a range of 0.01 by wt. to 3% by wt.

12. The method according to claim 9 , wherein the heating in step (d) is carried out at a temperature of not more than 1400° C. while forming the composite body.

13. The method according to claim 9 , wherein at least one of the first and second SiO 2 -containing slurry masses forms a base body layer of the composite body.

Assignees

• Heraeus Quarzglas

Inventors

• Schenk Christian
• Wessely Frank
• Scheich Gerrit

Classifications

• B05D3/007

  After-treatment · CPC title

• C03C2214/30

  Methods of making the composites · CPC title

• C03C2203/22

  using colloidal silica sols · CPC title

• B05D7/50

  Multilayers · CPC title

• C03C2201/26

  containing carbon · CPC title