Composition for treating suspensions of solid particles in water and method using said composition

Patent metadata

Field	Value
Publication number	US-10106443-B2
Application number	US-201313870746-A
Country	US
Kind code	B2
Filing date	Apr 25, 2013
Priority date	Apr 25, 2013
Publication date	Oct 23, 2018
Grant date	Oct 23, 2018

Abstract

A composition for treating an aqueous suspension of mineral particles includes at least one water soluble polymer and at least one calcium salt, magnesium salt or both a Calcium salt and a Magnesium salt. The composition is in powder form.

First claim

What is claimed is:

1. A composition for the treatment of an aqueous suspension of mineral particles, said composition comprising a mixture of:
at least one water soluble polymer; and
at least one Calcium salt, Magnesium salt or both a Calcium salt and a Magnesium salt;
wherein the composition is in powder form;
wherein, prior to creating the mixture by mixing the at least one water soluble polymer with the at least one Calcium salt, Magnesium salt or both a Calcium salt and a Magnesium salt, the at least one water soluble polymer is a synthetic polymer obtained by polymerization of
at least one non-ionic monomer selected from the group consisting of acrylamide; methacrylamide; N-mono derivatives of acrylamide; N-mono derivatives of methacrylamide; N,N derivatives of acrylamide; N,N derivatives of methacrylamide; acrylic esters; and methacrylic esters, and
at least one anionic monomers selected from the group consisting of monomers having a carboxylic function and salts thereof; monomers having a sulfonic acid function and salts thereof; and monomers having a phosphonic acid function and sails thereof; and
wherein a weight ratio between the water soluble polymer and the at least one Calcium salt. Magnesium salt or both a Calcium salt and a magnesium salt is between 99/1 to 20/80;
wherein the composition is water soluble; and
wherein contacting the composition with the aqueous suspension results in a treatment of the aqueous suspension via flocculation of the mineral particles in the aqueous suspension.

2. The composition according to claim 1 , wherein the salts are selected from the group consisting of calcium chloride, calcium acetate, calcium sulfate, calcium nitrate, calcium hydroxide, calcium carbonate, magnesium chloride, magnesium acetate, magnesium sulfate, magnesium nitrate, magnesium hydroxide, magnesium carbonate, and mixtures thereof.

3. The composition according to claim 1 , wherein the salts are selected from the group consisting of calcium chloride, calcium acetate, magnesium chloride, magnesium acetate, and mixtures thereof.

4. The composition according to claim 1 , wherein the non-ionic monomer is acrylamide and the anionic monomers are acrylic acid or acrylamide tertio butyl sulfonic acid (ATBS), and salts thereof.

5. The composition according to claim 1 , wherein the at least one water soluble polymer is a synthetic polymer obtained by the polymerization of at least one of the following: at least one non-ionic monomer and at least one anionic monomer and at least one cationic monomer, at least one monomer having a hydrophobic character in a range comprised between 0.001 and 1 mol %, r N-Vinyl Pyrrolidone (NVP), and AcryloyMorpholine (ACMO).

6. The composition according to claim 1 , wherein the at least one water-soluble polymer has an anionicity preferably ranging from between 10 to 55 mol % and a molecular weight between 5 and 40 million daltons.

7. A method for treating an aqueous suspension of mineral particles by flocculation, comprising the steps of:
preparing a composition comprising a mixture of at least one water soluble polymer, and at least one Calcium salt, Magnesium salt, or both a Calcium salt and a Magnesium salt, and
contacting the composition with the aqueous suspension, wherein, prior to creating the mixture by mixing the at least one water soluble polymer with the at least one Calcium salt, Magnesium salt, or both a Calcium salt and a Magnesium salt, the at least one water soluble polymer is obtained by polymerization of a non-ionic monomer of acrylamide and an a anionic monomer of either acrylic acid or acrylamide tertio butylsulfonic acid (ATBS), and salts thereof;
wherein a ratio between the water soluble polymer and the at least one Calcium salt, Magnesium salt, or both a Calcium salt and a Magnesium salt is between 99/1 to 20/80:
wherein the composition is in powder form;
wherein the composition is water soluble; and
wherein contacting the composition with the aqueous suspension results in a treatment of the aqueous suspension via flocculation of the mineral particles in the aqueous suspension.

8. The method according to claim 7 , wherein the salts are selected from the group consisting of calcium chloride, calcium acetate, calcium sulfate, calcium nitrate, calcium hydroxide, calcium carbonate, magnesium chloride, magnesium acetate, magnesium sulfate, magnesium nitrate, magnesium hydroxide, magnesium carbonate, and mixtures thereof.

9. The method of claim 7 , wherein the composition is added into a pipe transporting the suspension to a thickener.

10. The method of claim 7 , wherein the composition is added into a thickener containing the suspension to treat.

11. The method of claim 7 , wherein the composition is added to the suspension during transport of the suspension to a deposition area.

12. The method of claim 7 , wherein the composition is a solution prepared by a method comprising the steps of:
mixing powders of the at least one water soluble polymer and the salts, and
dissolving partially or totally the powder mixture in water.

13. The method of claim 7 , wherein the composition is a solution prepared by a method comprising the steps of:
dissolving the at least one water soluble polymer in water in order to obtain a mother solution comprising between 0.1 wt% to 3 wt% of the polymer,
dissolving the salts in a separate aqueous solution,
diluting the mother solution with the aqueous solution comprising the salts.

14. The method according to claim 7 , wherein the aqueous suspension of mineral particles comprises mature fine tailings (MFT) and the composition is introduced directly into a pipeline transporting the MFT from a pound to a deposition area.

15. The method according to claim 7 , wherein a total dosage of polymer added to the suspension is between 50 and 5,000 g per ton of dry solids of suspension.

16. The method according to claim 7 , wherein the ratio between the water soluble polymer and the salts is between 80/20 to 40/60.

17. The composition according to claim 1 , wherein the ratio between the water soluble polymer and the salts is between 80/20 to 40/60.

Assignees

• Favero Cedrick
• Tizzotti Morgan
• Dang Vu Trong
• Spcm Sa

Inventors

• Favero Cedrick
• Tizzotti Morgan
• Dang-Vu Trong

Classifications

• C02F1/5245 Primary

  using basic salts, e.g. of aluminium and iron · CPC title

• C08L33/26 Primary

  Homopolymers or copolymers of acrylamide or methacrylamide · CPC title

• C08K3/105

  Compounds containing metals of Groups 1 to 3 or of Groups 11 to 13 of the Periodic Table · CPC title

• C08F220/06

  Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof · CPC title

• C08F220/56

  Acrylamide; Methacrylamide · CPC title