Use of plasticizer-free polyvinylacetal for laminating sheets of polycarbonate

Patent metadata

Field	Value
Publication number	US-10105934-B2
Application number	US-201715647619-A
Country	US
Kind code	B2
Filing date	Jul 12, 2017
Priority date	Aug 19, 2016
Publication date	Oct 23, 2018
Grant date	Oct 23, 2018

Abstract

At least one polycarbonate sheet is laminated to at least one further rigid layer by at least one adhesion layer, characterized in that the adhesive layer consists of polyvinyl acetal having a content of vinylacetate groups of more than 10 wt. % but less than 25 wt. % and a content of plasticizer of less than 10 wt. %.

First claim

What is claimed is:

1. A process for laminating at least one polycarbonate sheet with at least one rigid layer, comprising:
laminating with at least one adhesive layer of polyvinylacetal having a content of vinylacetate groups between 10 and 25 wt. % and a content of plasticizer of less than 5 wt. %.

2. The process of claim 1 , wherein the polyvinylacetal has a viscosity of 5 mPas to 3000 mPas, measured according to DIN 53015:2001-0.

3. The process of claim 1 , wherein the polyvinylacetal has a degree of acetalization of 60-80 wt. %.

4. The process of claim 3 , wherein the polyvinylacetal has a content of vinyl alcohol groups of 10-35 wt. %.

5. The process of claim 1 , wherein the plasticizer is present, and is selected from the group consisting of aliphatic diesters of tri- or tetraethylene glycols, dialkyl adipates, triorganophosphates, triorganophosphites, phthalates, diisononylcyclohexyl dicarboxylic acid (DINCH), and mixtures thereof.

6. The process of claim 5 , wherein the polyvinylacetal has a content of vinyl alcohol groups of 10-35 wt. %.

7. The process of claim 1 , wherein the polyvinylacetal has a content of vinyl alcohol groups of 10-35 wt. %.

8. The process of claim 1 , wherein the adhesive layer contains no plasticizer.

9. The process of claim 1 , wherein lamination is performed at temperatures of less than 125° C.

10. The process of claim 1 , wherein polyvinylbutyral is employed as a polyvinylacetal.

11. The process of claim 1 , wherein the adhesive layer is applied in the form of a sheet having a thickness of 10-300 μm.

12. A process for laminating at least one polycarbonate sheet with at least one rigid layer, comprising:
laminating with at least one adhesive layer of polyvinylacetal having a content of vinylacetate groups between 14 and 25 wt. % based on the weight of the polyvinylacetal, and a content of plasticizer of less than 10 wt. %.

13. The process of claim 12 , wherein the plasticizer content is less than 5 wt. % based on the weight of the adhesive layer.

14. The process of claim 12 , wherein the polyvinylacetal consists of polyvinyl butyral.

15. The process of claim 12 , wherein lamination is performed at temperatures of less than 125° C.

16. The process of claim 12 , wherein the plasticizer is present, and is selected from the group consisting of aliphatic diesters of tri- or tetraethylene glycols, dialkyl adipates, triorganophosphates, triorganophosphites, phthalates, diisononylcyclohexyl dicarboxylic acid (DINCH), and mixtures thereof.

17. The process of claim 12 , wherein the adhesive layer contains no plasticizer.

18. A process for laminating at least one polycarbonate sheet with at least one rigid layer, comprising:
laminating with at least one adhesive layer of polyvinylbutyral having a content of vinylacetate groups between 10 and 25 wt. % and a content of plasticizer of less than 5 wt. %.

19. The process of claim 18 , wherein the polyvinyl acetate content of the polyvinylbutyral is from 14 to 25 wt. %.

20. The process of claim 18 , wherein the plasticizer is present, and is selected from the group consisting of aliphatic diesters of tri- or tetraethylene glycols, dialkyl adipates, triorganophosphates, triorganophosphites, phthalates, diisononylcyclohexyl dicarboxylic acid (DINCH), and mixtures thereof.

Assignees

• Kuraray Europe Gmbh

Inventors

• Frank Michael
• Sabel Thomas
• Mummy Florian
• Steinbach Niklas

Classifications

• B32B2309/02

  Temperature · CPC title

• B32B2307/542

  Shear strength · CPC title

• B32B2250/24

  All layers being polymeric · CPC title

• B32B17/10816

  by pressing · CPC title

• B32B27/22

  using plasticisers · CPC title