Foamed sheet

Patent metadata

Field	Value
Publication number	US-10105929-B2
Application number	US-201414914359-A
Country	US
Kind code	B2
Filing date	Aug 21, 2014
Priority date	Aug 26, 2013
Publication date	Oct 23, 2018
Grant date	Oct 23, 2018

Abstract

A foamed sheet according to the present invention has a thickness of 30 to 500 μm and includes a foam. The foam has a density of 0.2 to 0.7 g/cm 3 , an average cell diameter of 10 to 150 μm, and a peak top of loss tangent (tan δ) occurring in a temperature range of from −30° C. to 30° C., where the loss tangent is defined as the ratio of a loss modulus to a storage modulus determined at an angular frequency of 1 rad/s in dynamic viscoelastic measurement of the foam. The foam preferably has a maximum of the loss tangent (tan δ) in the temperature range of from −30° C. to 30° C. of 0.2 or more.

First claim

The invention claimed is:

1. A foamed sheet having a thickness of 30 to 500 μm and comprising
a foam having a density of 0.2 to 0.7 g/cm 3 and an average cell diameter of 10 to 150 μm, the foam having a peak top of loss tangent (tan δ) occurring in a temperature range of from −30° C. to 30° C., where the loss tangent (tan δ) is specified as a ratio of a loss modulus to a storage modulus each determined at an angular frequency of 1 rad/s in dynamic viscoelastic measurement of the foam, and
the foam has an initial elastic modulus of 1.93 N/mm 2 or less in a tensile test at a tensile speed of 300 mm/min and at an ambient temperature of 23° C.

2. The foamed sheet according to claim 1 ,
wherein the foam has a maximum of loss tangent (tan δ) in the temperature range of from −30° C. to 30° C. of 0.2 or more.

3. The foamed sheet according to claim 1 ,
wherein a value R is 0.15 or more at an impactor weight of 28 g and a rise angle of 40° and is 0.10 or more at an impactor weight of 96 g and a rise angle of 47°, where the value R is determined by dividing an impact absorption rate (%) by the thickness (μm) of the foamed sheet, and where the impact absorption rate is determined in an impact test using a pendulum impact tester and specified by an expression:
Impact absorption rate (%)=[( F 0 −F 1 )/ F 0 ]×100

wherein:
F 0 represents an impact force upon collision of an impactor with a backing plate alone; and
F 1 represents an impact force upon collision of the impactor with the backing plate in a structure including the backing plate and the foamed sheet.

4. The foamed sheet according to claim 1 ,
wherein at least one side of the foam has a shear bond strength of 0.5 N/100 mm 2 or more to a SUS 304BA plate, where the shear bond strength is determined at 23° C. and at a tensile speed of 50 mm/min.

5. The foamed sheet according to claim 1 ,
wherein the foam is derived from at least one resinous material selected from the group consisting of acrylic polymers, rubbers, urethane polymers, and ethylene-vinyl acetate copolymers.

6. The foamed sheet according to claim 1 ,
wherein the foam is formed via a step A of mechanically foaming an emulsion resin composition to give a foamed emulsion resin composition containing bubbles.

7. The foamed sheet according to claim 6 ,
wherein the foam is formed further via a step B of applying the mechanically foamed emulsion resin composition onto a substrate and drying the applied composition.

8. The foamed sheet according to claim 7 ,
wherein the drying in the step B comprises:
a preliminary drying step B1 of drying the applied foamed emulsion resin composition on the substrate at a temperature of from 50° C. to lower than 125° C.; and
a drying step B2 of further drying the preliminarily dried foamed emulsion resin composition at a temperature of from 125° C. to 200° C.

9. The foamed sheet according to claim 1 , further comprising
a pressure-sensitive adhesive layer on or above at least one side of the foam.

10. The foamed sheet according to claim 1 ,
wherein the foamed sheet is used as a shock absorbing sheet for electrical/electronic devices.

11. An electrical/electronic device comprising
the foamed sheet according to claim 1 .

12. The electrical/electronic device according to claim 11 , further comprising:
a display member; and
a cabinet,
wherein the electrical/electronic device has such a structure that the foamed sheet is held between the cabinet and the display member.

13. The foamed sheet according to claim 5 , the acrylic polymers are derived from monomer components essentially including a monomer that gives a homopolymer having a glass transition temperature Tg of 10° C. or higher, and a monomer that gives a homopolymer having a glass transition temperature Tg of lower than 10° C.

14. The foamed sheet according to claim 1 , wherein the foam comprises a surfactant.

15. The foamed sheet according to claim 14 , wherein foam further comprises a resinous material and the solid content of the surfactant is 0.5 to 10 parts by weight per 100 parts by weight of the solid content of the resinous material.

16. The foamed sheet according to claim 1 , wherein the foam comprises an azole-ring-containing compound as a rust inhibitor.

17. The foamed sheet according to claim 16 , wherein the foam further comprises a resinous material and the solid content of the rust inhibitor is 0.2 to 5 parts by weight per 100 parts by weight of the solid content of the resinous material.

Assignees

• Nitto Denko Corp

Inventors

• Doi Kohei
• Nagasaki Kunio
• Otsuka Tetsuya
• Okada Mika
• Kato Kazumichi
• Tokuyama Hideyuki
• Kitahara Tsunaki
• Takahashi Tadao
• Matsushita Kiichiro

Classifications

• C08J2323/08

  Copolymers of ethene (C08J2323/16 takes precedence) · CPC title

• C08J9/30

  by mixing gases into liquid compositions or plastisols, e.g. frothing with air · CPC title

• C09J2203/318

  for the production of liquid crystal displays · CPC title

• C08J2375/04

  Polyurethanes · CPC title

• B32B2266/0242

  Acrylic resin · CPC title