Process and absorbent for dehumidifying moist gas mixtures

Patent metadata

Field	Value
Publication number	US-10105644-B2
Application number	US-201715619584-A
Country	US
Kind code	B2
Filing date	Jun 12, 2017
Priority date	Jun 14, 2016
Publication date	Oct 23, 2018
Grant date	Oct 23, 2018

Abstract

The invention relates to a process for dehumidifying a moist gas mixture in which the moist gas mixtures are brought into contact with an absorbent comprising dialkylimidazolium salts and trialkyl phosphate. In addition, the invention also relates to an absorption heat pump comprising the absorbent according to the invention and to the absorbent according to the invention itself.

First claim

What is claimed is:

1. A process for dehumidifying a moist gas mixture G 1 , wherein the moist gas mixture G 1 is contacted with a liquid absorption medium A 1 , which comprises a mixture of at least one trialkyl phosphate of structure (I):

and at least one salt S selected from the group consisting of Q + A − , Q + (R 1 O) 2 PO 2 − , (Q + ) 2 R 2 OPO 3 2 − , and Q + M + R 3 OPO 3 2 − , to obtain a gas mixture G 2 which has a lower water content compared to the moist gas mixture G 1 and a liquid absorption medium A 2 which has an elevated water content compared to the liquid absorption medium A 1 ; wherein:
a) Q + is a dialkylimidazolium cation;
b) A − is an anion selected from the group consisting of R*COO − , R′SO 3 − , HSO 4 − , and R″SO 4 − ;
c) R*, R′, R″, R A , R B , R C are each independently an alkyl group;
d) R 1 , R 2 , R 3 are each independently an alkyl group; and
e) M + is an alkali metal ion.

2. The process of claim 1 , wherein:
a) Q + is a dialkylimidazolium cation, in which the alkyl groups each independently have 1 to 10 carbon atoms;
b) R*, R′, R″, R A , R B , R C , R 1 , R 2 , R 3 are each independently an alkyl group having 1 to 10 carbon atoms; and
c) M + =Li + , K + or Na + .

3. The process of claim 1 , wherein:
a) salt S is selected from the group of: Q + A − , and Q + (R 1 O) 2 PO 2 − ;
b) Q + is a dialkylimidazolium cation, in which the alkyl groups each independently have 1 to 6 carbon atoms;
c) A − is an anion selected from the group consisting of R*COO − , R'SO 3 − , and R″SO 4 − ; and
d) R*, R 1 , R′, R″, R A , R B , and R C are each independently an alkyl group having 1 to 6 carbon atoms.

4. The process of claim 1 , wherein R A , R B , and R C are each independently either methyl or ethyl.

5. The process of claim 1 , wherein the liquid absorption medium A 1 is an aqueous solution.

6. The process of claim 5 , wherein, in the liquid absorption medium A 1 :
a) the total weight of all trialkyl phosphates of structure (I) and all salts S is in the range of 65% by weight to 95% by weight, based on the total weight of the aqueous solution; or
b) the ratio of the total weight of all trialkyl phosphates of structure (I) to the total weight of all salts S is in the range from 1:9999 to 1:9.

7. An apparatus V 2 for dehumidifying a moist gas mixture, comprising the components:
(i) a liquid absorption medium A 1* , which comprises a mixture of at least one trialkyl phosphate of structure (I):

and at least one salt S selected from the group consisting of Q + A − , Q + (R 1 O) 2 PO 2 − , (Q + ) 2 R 2 OPO 3 2− , and Q + M + R 3 OPO 3 2− ;

(ii) at least one water absorption unit W abs2 set up for contacting the moist gas mixture with the liquid absorption medium A 1* ;
(iii) at least one water desorption unit W des2 which comprises a heat exchanger W x2 and is set up for at least partially removing water from a liquid absorption medium A 1* ;
(iv) and a circuit U 2 which connects the water absorption unit W abs2 with the water desorption unit W des2 and by means of which the liquid absorption medium A 1* may be circulated;
wherein:
Q + is a dialkylimidazolium cation;
A − is an anion selected from the group consisting of R*COO − , R′SO 3 − , HSO 4 − , and R″SO 4 − ;
R*, R′, R″, R A , R B , and R C are each independently an alkyl group;
R 1 , R 2 , and R 3 are each independently an alkyl group; and
M + is an alkali metal ion.

8. The apparatus V 2 of claim 7 , wherein in A 1* :
a) Q + is a dialkylimidazolium cation, in which the alkyl groups each independently have 1 to 10 carbon atoms;
b) R*, R′, R″, R A , R B , R C , R 1 , R 2 , R 3 are each independently an alkyl group having 1 to 10 carbon atoms; and
c) M + =Li + , K + or Na + .

9. The apparatus V 2 of claim 7 , wherein in A 1* :
a) salt S is selected from the group consisting of: Q + A − and Q + (R 1 O) 2 PO 2 − ;
b) Q + is a dialkylimidazolium cation, in which the alkyl groups each independently have 1 to 6 carbon atoms;
c) A − is an anion selected from the group consisting of: R*COO − , R′SO 3 − , and R″SO 4 − ; and
d) R*, R 1 , R′, R″, R A , R B , and R C are each independently an alkyl group having 1 to 6 carbon atoms.

10. The apparatus V 2 of claim 7 , wherein R A , R B , R C are mutually independently either methyl or ethyl.

11. The apparatus V 2 of claim 7 , wherein the liquid absorption medium A 1* is an aqueous solution.

12. The apparatus V 2 of claim 11 , wherein in A 1* :
a) the total weight of all trialkyl phosphates of structure (I) and all salts S is in the range of 65% by weight to 95% by weight, based on the total weight of the aqueous solution; or
b) the ratio of the total weight of all trialkyl phosphates of structure (I) to the total weight of all salts S is in the range from 1:9999 to 1:9.

13. The apparatus V 2 of claim 7 , wherein V 2 is part of an absorption heat pump, that further comprises a condenser; an evaporator; and a coolant, wherein the coolant is water.

14. An absorption medium A 1* , comprising a mixture of at least one trialkyl phosphate of structure (I):

and at least one salt S selected from the group consisting of: Q + A − , Q + (R 1 O) 2 PO 2 − , (Q + ) 2 R 2 OPO 3 2− , and Q + M + R 3 OPO 3 2− ; wherein:
a) Q + is a dialkylimidazolium cation;
b) A − is an anion selected from the group consisting of R*COO − , R′SO 3 − , HSO 4 − , and R″SO 4 − ;
c) R*, R′, R″, R A , R B , R C , R 1 , R 2 , and R 3 are each independently an alkyl group; and
d) M + is an alkali metal ion.

15. The absorption medium A 1* of claim 14 , wherein:
a) Q + is a dialkylimidazolium cation, in which the alkyl groups each independently have 1 to 10 carbon atoms;
b) R*, R′, R″, R A , R B , R C , R 1 , R 2 , and R 3 are each independently an alkyl group having 1 to 10 carbon atoms; and
c) M + =Li + , K + or Na + .

16. The absorption medium A 1* of claim 14 , wherein:
a) salt S is selected from the group consisting of: Q + A − and Q + (R 1 O) 2 PO 2 − ;
b) Q + is a dialkylimidazolium cation in which the alkyl groups each independently have 1 to 6 carbon atoms;
c) A − is an anion selected from the group consisting of: R*COO − , R′SO 3 − , and R″SO 4 − ; and
d) R*, R 1 , R′, R″, R A , R B , and R C are each independently an alkyl group having 1 to 6 carbon atoms.

17. The absorption medium A 1* of claim 14 , wherein R A , R B , R C are mutually independently either methyl or ethyl.

18. The absorption medium A 1* of claim 14 , wherein is A 1* is an aqueous solution.

19. The absorption medium A 1* of claim 14 , in which the total weight of all trialkyl phosphates of structure (I) and all salts S is in the range of 65% by weight to 95% by weight, based on the total weight of the aqueous solution.

20. The absorption medium A 1* of claim 14 , in which the ratio of the total weight of all trialkyl phosphates of structure (I) to the total weight of all salts S is in the range from 1:9999 to 1:9.

Assignees

• Evonik Degussa Gmbh

Inventors

• Zehnacker Olivier
• Willy Benjamin

Classifications

• C07F9/091

  with hydroxyalkyl compounds with further substituents on alkyl · CPC title

• B01D53/263 Primary

  by absorption · CPC title

• C01D5/00

  Sulfates or sulfites of sodium, potassium or alkali metals in general {(sulfites in general C01B17/62)} · CPC title

• C07D233/56

  with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, attached to ring carbon atoms · CPC title

• B01D2252/20473

  containing an imidazole-ring · CPC title