Measurement of hydrocarbon contamination in water

Patent metadata

Field	Value
Publication number	US-10101271-B2
Application number	US-201615387032-A
Country	US
Kind code	B2
Filing date	Dec 21, 2016
Priority date	Dec 21, 2016
Publication date	Oct 16, 2018
Grant date	Oct 16, 2018

Abstract

A method for performing infrared analysis for measuring hydrocarbon contamination in water includes providing light from a light source; directing light from the light source through an experimental water sample; detecting the light transmitted from the experimental water sample; and determining a level of hydrocarbon contamination in the experimental water sample based on the light loss in the range between about 5700 cm−1 and 6300 cm−1. An apparatus for performing infrared analysis for measuring hydrocarbon contamination in water includes a controller operative to determine light loss through the sample cell and to determine a level of hydrocarbon contamination in the experimental water sample based on the light loss in the range between about 5700 cm−1 and 6300 cm−1.

First claim

What is claimed is:

1. A method for performing infrared analysis for measuring hydrocarbon contamination in water, comprising:
providing light from a light source, the light including a near infrared (NIR) radiation output in a range between about 5700 cm −1 and 6300 cm −1 ;
directing light from the light source through an experimental water sample, wherein the experimental water sample has a path length of between 2 mm and 8 mm;
detecting the light transmitted from the experimental water sample;
determining the light loss through the experimental water sample in the range between about 5700 cm −1 and 6300 cm −1 ;
determining a level of hydrocarbon contamination in the experimental water sample based on the light loss only in the range between about 5700 cm −1 and 6300 cm −1 ; and
generating an output indicating the level of hydrocarbon contamination in the experimental water sample.

2. The method of claim 1 , further comprising:
comparing the light loss with a known light loss in the range between about 5700 cm −1 and 6300 cm −1 associated with a known level of hydrocarbon contamination in water; and
determining a level of hydrocarbon contamination based on the light loss and the known light loss.

3. The method of claim 1 , further comprising modulating the light at switching frequencies uniquely associated with different wavelengths prior to the light reaching the experimental sample or after being transmitted from the experimental sample, wherein the modulation includes modulating through at least some frequencies in the range between about 5700 cm −1 and 6300 cm −1 .

4. The method of claim 1 , further comprising selecting the light source to have only one or two wavelengths or wavelength bands prior to the light reaching the experimental sample or after being transmitted from the experimental sample, wherein the wavelengths or wavelength bands occur in the range between about 5700 cm −1 and 6300 cm −1 .

5. The method of claim 1 , wherein the light source is a tunable laser or a plurality of lasers having different variable wavelengths, wherein the tunable laser permits tuning through at least some frequencies in the range between about 5700 cm −1 and 6300 cm −1 , or wherein the plurality of lasers output light at least some frequencies in the range between about 5700 cm −1 and 6300 cm −1 .

6. The method of claim 1 , wherein the light source is one or more fixed wavelength lasers modulating the light at switching, frequencies uniquely associated with different wavelengths that occur in the range between about 5700 cm −1 and 6300 cm −1 .

7. The method of claim 1 , wherein the infrared analysis is performed with a dispersive diode array spectrometer.

8. The method of claim 1 , wherein the infrared analysis is performed with a dispersive scanning spectrometer.

9. The method of claim 1 , wherein the infrared analysis is performed using a Fourier transform infrared spectrum analyzer.

10. The method of claim 1 , further comprising:
directing light from the light source through a reference water sample;
detecting the light exiting the reference water sample;
determining the light loss through the reference water sample in a range between about 5700 cm −1 and 6300 cm −1 ;
subtracting the light loss through the reference water sample from the light loss through the experimental water sample to generate a light loss difference, wherein the experimental water sample has a path length of between 2 mm and 8 mm; and
determining the level of hydrocarbon contamination in the experimental water sample based on the light loss difference only in the range between about 5700 cm −1 and 6300 cm −1 .

11. The method of claim 10 , further comprising:
comparing the light loss difference with a known light loss in the range between about 5700 cm −1 and 6300 cm −1 associated with a known level of hydrocarbon contamination in water; and
determining the level of hydrocarbon contamination based on the comparison.

12. The method of claim 1 , wherein the experimental water sample has a path length of between 0.5 and 10 millimeters.

13. The method of claim 1 , wherein the experimental water sample has a path length of approximately 5 millimeters.

14. The method of claim 1 , further comprising filtering the light with a long wave filter operative to block transmittance at wavenumbers above about 7000 cm −1 prior to detecting the light.

15. The method of claim 1 , further comprising:
measuring water samples with known hydrocarbon contamination levels to obtain known light loss characteristics in the range between about 5700 cm −1 and 6300 cm −1 associated with the known hydrocarbon contamination levels; and
determining the level of hydrocarbon contamination in the experimental water sample based on the light loss and the known light loss characteristics.

16. An apparatus for performing infrared analysis for measuring hydrocarbon contamination in water, comprising:
a light source providing an output including a near infrared (NIR) spectral output in a range between about 5700 cm −1 and 6300 cm −1 ;
a sample cell constructed to admit water and positioned to receive light from the light source, wherein the sample cell has a sample path length equal to or greater than about 0.5 millimeters;
a detector positioned to receive light transmitted through the sample cell, wherein the detector is operative to detect radiation at least in the range between about 5700 cm −1 and 6300 cm −1 ; and
a controller communicatively coupled to the detector, wherein the controller is operative to determine light loss through the sample cell in the range between about 5700 cm −1 and 6300 cm −1 , to determine a level of hydrocarbon contamination in the experimental water sample based the light loss only in the range between about 5700 cm −1 and 6300 cm −1 , and to generate an output indicating the level of hydrocarbon contamination in the experimental water sample.

17. The apparatus of claim 16 , wherein the apparatus is constructed to modulate the light at switching frequencies uniquely associated with different wavelengths prior to the light reaching the experimental sample or after being transmitted from the experimental sample, wherein the modulation includes modulating through at least some frequencies in the range between about 5700 cm−1 and 6300 cm−1.

18. The apparatus of claim 16 , wherein the light source is constructed to yield only one or two wavelengths or wavelength bands prior to the light reaching the experimental sample or after being transmitted from the experimental sample; and wherein the wavelengths or wavelength bands occur in the range between about 5700 cm −1 and 6300 cm −1 .

19. The apparatus of claim 16 , wherein the light source is a tunable laser or a plurality of lasers having different variable wavelengths, wherein the tunable laser permits tuning through at least some frequencies in the range between about 5700 cm −1 and 6300 cm −1 , or wherein the plurality of lasers output light at least some frequencies in the range between about 5700 cm −1 and 6300 cm −1 .

20. The apparatus of claim 16 , wherein the light source is one or more fixed wavelength lasers modulating the light at switching frequencies uniquely associated with different wavelengths that occur in the range between about 5700 cm −1 and 6300 cm −1 .

21. The apparatus of claim 16 , wherein the infrared analysis is performed using a dispersive diode array spectrometer.

22. The apparatus of claim 16 , w

Assignees

• Abb Schweiz Ag

Inventors

• Buijs Henry L

Classifications

• G01N21/59 Primary

  Transmissivity (G01N21/25 takes precedence) · CPC title

• G01N33/1833 Primary

  Oil in water · CPC title

• G01N21/39

  using tunable lasers · CPC title

• G01J3/12

  Generating the spectrum; Monochromators · CPC title

• G01N21/3577

  for analysing liquids, e.g. polluted water · CPC title