Process for removing light components from an ethylene stream

Patent metadata

Field	Value
Publication number	US-10101083-B2
Application number	US-201314651441-A
Country	US
Kind code	B2
Filing date	Dec 13, 2013
Priority date	Dec 13, 2012
Publication date	Oct 16, 2018
Grant date	Oct 16, 2018

Abstract

A process for removing light components from an ethylene stream may include providing a dried ethylene stream containing ethylene, ethane, CO, CO 2 , H 2 , CH 4 , and C 3+ hydrocarbons. The process may include sending the dried ethylene stream to a stripper to produce an overhead stream containing ethylene, CO, H 2 and CH 4 , and a bottom stream containing ethylene, ethane, CO 2 , and C 3+ hydrocarbons. The gaseous phase on top of the stripper may be condensed in a heat exchanger cooled by a refrigerant stream to get a first gaseous phase and a first liquid phase. The first gaseous phase may be condensed in a heat exchanger cooled by liquid ethane or liquid ethylene to get a second gaseous phase containing ethylene CO, H 2 and CH 4 and a second liquid phase. The first and second liquid phases may be the reflux of the stripper.

First claim

The invention claimed is:

1. A process for removing light components from an ethylene stream comprising:
a) providing a dried ethylene stream (A) comprising ethylene, ethane, CO, CO 2 , H 2 , CH 4 , C 3+ hydrocarbons and optionally oxygenates;
b) sending said dried ethylene stream (A) to a stripper to produce an overhead stream and a bottom stream, wherein the overhead stream comprises ethylene, CO, H 2 and CH 4 , and wherein the bottom stream comprises ethylene, ethane, CO 2 , C 3+ hydrocarbons and optionally oxygenates;
wherein a gaseous phase from the overhead stream of the stripper is condensed in a heat exchanger cooled by a refrigerant stream to get a first gaseous phase and a first liquid phase;
wherein the first gaseous phase is condensed in another heat exchanger cooled by liquid ethane or liquid ethylene to get a second gaseous phase comprising ethylene CO, H 2 and CH 4 and a second liquid phase; wherein the first and second liquid phases are a reflux of the stripper; and
either
i)
c) sending said bottom stream of step b) to a deethanizer to produce:
a bottom stream comprising ethane, C 3+ hydrocarbons and optionally oxygenates; and
an overhead stream consisting of ethylene and CO 2 ; and

d) sending said overhead of step c) to a fixed bed CO 2 adsorption zone to recover an ethylene stream free of CO 2 ;
or
(ii)
c1) sending said bottom stream of step b) to a fixed bed CO 2 adsorption zone to recover a stream free of CO 2 , then sending said stream to a deethanizer to produce:
a bottom stream comprising ethane, C 3+ hydrocarbons and optionally oxygenates; and
an overhead stream consisting of ethylene free of CO 2 .

2. The process according to claim 1 , wherein the refrigerant stream comprises a mixture of liquid and optionally C 3 to C 4 gaseous hydrocarbons.

3. The process according to claim 2 , wherein the refrigerant stream comprises liquid and optionally gaseous propane and/or liquid and optionally gaseous propylene with a pressure ranging from 30 kPag to 200 kPag.

4. The process according to claim 1 , wherein the liquid ethane or liquid ethylene pressure ranges from 30 kPag to 500 kPag.

5. The process according to claim 1 , wherein the bottom stream of the stripper is purified to remove oxygenates and CO 2 , and get pure ethylene.

6. The process according to claim 5 , wherein a part of the ethylene is expanded to get liquid ethylene, and wherein the liquid ethylene is sent as a cooling fluid to condense the first gaseous phase on top of the stripper.

7. The process according to claim 5 , wherein the part of the ethylene is expanded to a pressure from 30 kPag to 500 kPag.

8. The process according to claim 7 , wherein, during the condensation of the first gaseous phase, ethylene returns to gas phase and is recycled.

9. The process according to claim 8 , wherein the ethylene of the dried ethylene stream (A) is made by ethanol dehydration, and wherein the condensed ethylene at low pressure is recycled at any point between an outlet of a reactor of the ethanol dehydration and the stripper.

10. The process according to claim 1 , wherein a part of liquid ethylene in a reflux drum of the deethanizer is expanded to get a cold mixture of gas and liquid, and sent as a cooling fluid to condense the first gaseous phase on top of the stripper.

11. The process according to claim 10 , wherein the part of liquid ethylene in the reflux drum of the deethanizer is expanded to a pressure ranging from 30 kPag to 500 kPag.

12. The process according to claim 10 , wherein, during the condensation of the first gaseous phase on top of the stripper, ethylene returns to gas phase and is recycled.

13. The process according to claim 12 , wherein ethylene of the dried ethylene stream (A) is made by ethanol dehydration and said condensed ethylene at low pressure is recycled at any point between a reactor of the ethanol dehydration and the stripper.

14. The process according to claim 1 , wherein the dried ethylene stream (A) originates from the dehydration of ethanol.

Assignees

• Total Res & Technology Feluy
• Ifp Energies Now

Inventors

• Vermeiren Walter
• Boutrot Catherine
• Arratia Manuela

Classifications

• C07C11/04

  Ethene · CPC title

• F25J3/0209

  Natural gas or substitute natural gas · CPC title

• C07C1/24

  by elimination of water · CPC title

• B01D3/343 Primary

  the substance being a gas · CPC title

• C07C7/12

  by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers · CPC title