Coated article with IR reflecting layer and method of making same

Patent metadata

Field	Value
Publication number	US-10100202-B2
Application number	US-201615256872-A
Country	US
Kind code	B2
Filing date	Sep 6, 2016
Priority date	Sep 6, 2016
Publication date	Oct 16, 2018
Grant date	Oct 16, 2018

Abstract

A coated article is provided with a low-emissivity (low-E) coating on a glass substrate. The low-E coating includes an infrared (IR) reflecting layer between at least a pair of dielectric layers. The IR reflecting layer may be of silver or the like. The coating is designed so as to provide a highly transparent coated article that is thermally stable upon optional heat treatment and which can be made to have a low emissivity in a consistent manner. The coating is designed to have improved IR reflecting layer quality, and thus reduced tolerances with respect to manufacturability of desired emissivity values. The coated article may be used in monolithic window applications, IG window applications, or the like.

First claim

The invention claimed is:

1. A coated article including a coating supported by a glass substrate, the coating comprising moving away from the glass substrate:
a dielectric layer comprising zirconium silicon oxynitride;
a layer comprising titanium oxide;
a layer comprising zinc stannate;
a layer comprising zinc oxide located over and directly contacting the layer comprising zinc stannate;
an infrared (IR) reflecting layer comprising silver located on the substrate over and directly contacting the layer comprising zinc oxide; and
a layer comprising metal oxide located over at least the IR reflecting layer comprising silver;
wherein the coating contains only one silver based IR reflecting layer;
wherein the coating has a normal emissivity (E n ) of no greater than 7%, and measured monolithically the coated article has a visible transmission of at least 75%.

2. The coated article of claim 1 , wherein the layer comprising zirconium silicon oxynitride contains at least three times as much nitrogen as oxygen.

3. The coated article of claim 1 , wherein the layer comprising zirconium silicon oxynitride contains at least four times as much nitrogen as oxygen.

4. The coated article of claim 1 , wherein a ratio of Zr/Si (atomic) is from 0.30 to 0.47 in the layer comprising zirconium silicon oxynitride.

5. The coated article of claim 1 , wherein a ratio of Zr/Si (atomic) is from 0.35 to 0.44 in the layer comprising zirconium silicon oxynitride.

6. The coated article of claim 1 , wherein the layer comprising titanium oxide is located over and directly contacting the layer comprising zirconium silicon oxynitride.

7. The coated article of claim 1 , further comprising a layer comprising silicon nitride located between the glass substrate and the layer comprising zirconium silicon oxynitride.

8. The coated article of claim 1 , wherein the layer comprising zirconium silicon oxynitride is from about 20-250 Å thick.

9. The coated article of claim 1 , wherein the layer comprising zirconium silicon oxynitride is from about 50-100 Å thick.

10. The coated article of claim 1 , wherein the layer comprising titanium oxide is from about 15-150 Å thick.

11. The coated article of claim 1 , wherein the layer comprising titanium oxide is from about 20-60 Å thick.

12. The coated article of claim 1 , wherein the layer comprising zinc stannate is located over and directly contacting the layer comprising titanium oxide.

13. The coated article of claim 1 , further comprising, below said layer comprising zinc stannate and above said layer comprising titanium oxide, another layer comprising zinc stannate and another layer comprising zinc oxide.

14. The coated article of claim 13 , wherein said another layer comprising zinc stannate directly contacts said layer comprising titanium oxide.

15. The coated article of claim 1 , wherein the coating has a normal emissivity (E n ) of no greater than 6%.

16. The coated article of claim 1 , wherein measured monolithically the coated article has a visible transmission of at least 86%.

17. The coated article of claim 1 , wherein the layer comprising metal oxide comprises an oxide of Ni and/or Cr and is located directly over and contacting the IR reflecting layer comprising silver.

18. The coated article of claim 1 , further comprising another layer comprising zinc stannate and another layer comprising zinc oxide located over the IR reflecting layer comprising silver.

19. The coated article of claim 18 , further comprising a layer comprising silicon nitride located over the another layer comprising zinc oxide.

20. The coated article of claim 19 , further comprising a layer comprising tin oxide located between the another layer comprising zinc oxide and the layer comprising silicon nitride.

21. The coated article of claim 1 , wherein the coated article is heat treated and has a film side reflective ΔE* value of no greater than 4.0 due to the heat treatment.

22. The coated article of claim 1 , wherein the coated article is heat treated and has a film side reflective ΔE* value of no greater than 2.0 due to the heat treatment.

23. The coated article of claim 1 , wherein the coated article is heat treated and has a glass side reflective ΔE* value of no greater than 2.5 due to the heat treatment.

24. The coated article of claim 1 , wherein the coated article is heat treated and has a glass side reflective ΔE* value of no greater than 2.0 due to the heat treatment.

25. The coated article of claim 1 , wherein the coated article is heat treated and has a glass side reflective ΔE* value of no greater than 1.5 due to the heat treatment.

26. An IG window unit comprising the coated article of claim 1 , wherein the IG window unit has a U-value of no greater than 1.4, the IG window unit further comprising another glass substrate, and wherein the coating is on surface three of the IG window unit.

27. An IG window unit comprising the coated article of claim 1 , wherein the IG window unit has a U-value of no greater than 1.1, the IG window unit further comprising another glass substrate, and wherein the coating is on surface three of the IG window unit.

28. An IG window unit comprising:
first and second glass substrates with a gap therebetween;
a coating supported by the second glass substrate and facing the gap, the second glass substrate to be located closer to a building interior than is the first glass substrate, the coating comprising moving away from the second glass substrate:
a dielectric layer comprising zirconium silicon oxynitride;
a layer comprising titanium oxide;
a layer comprising zinc stannate;
a layer comprising zinc oxide located over and directly contacting the layer comprising zinc stannate;
an infrared (IR) reflecting layer comprising silver located on the substrate over and directly contacting the layer comprising zinc oxide; and
a layer comprising metal oxide located over at least the IR reflecting layer comprising silver;
wherein the coating contains only one silver based IR reflecting layer;
wherein the coating has a normal emissivity (E n ) of no greater than 7%;
wherein the IG window unit has a visible transmission of at least 70% and a U-value of no greater than 1.4.

Assignees

• Guardian Europe Sarl
• Guardian Ind Uk Ltd
• Guardian Europe Sarl

Inventors

• Disteldorf Bernd
• Dietrich Anton
• Baker Robert
• Silvester Stuart
• Sanz Eduardo

Classifications

• C03C17/36 Primary

  at least one coating being a metal · CPC title

• C03C17/3644

  the metal being silver · CPC title

• E06B3/6715

  specially adapted for increased thermal insulation or for controlled passage of light (E06B3/66323 takes precedence; coating of glass pains C03C17/00; devices or arrangements for controlling the intensity, colour, phase, polarisation or direction of light G02F1/00) · CPC title

• C03C2217/256

  Ag · CPC title

• C03C17/366

  Low-emissivity or solar control coatings · CPC title