Process for producing pellets of soft copolymers

Patent metadata

Field	Value
Publication number	US-10100158-B2
Application number	US-201515506333-A
Country	US
Kind code	B2
Filing date	Nov 19, 2015
Priority date	Nov 21, 2014
Publication date	Oct 16, 2018
Grant date	Oct 16, 2018

Abstract

The present invention deals with a process for producing pellets from olefin copolymers. The process comprises: (i) melting the olefin copolymer in an extruder; (ii) extruding the molten olefin copolymer through a die plate into a pellet water bath in a pelletizer thereby producing strands of the olefin copolymer; (iii) cutting the strands of the olefin copolymer in the pelletizer into pellets; and (iv) drying the pellets. The pellet water in the pelletizer contains from 0.1 to 5% by weight of a colloidal silica based on the weight of the water.

First claim

The invention claimed is:

1. A process for producing pellets from olefin copolymers comprising the steps of: (i) melting the olefin copolymer in an extruder; (ii) extruding the molten olefin copolymer through a die plate having a multitude of holes into a pellet water bath in a pelletiser thereby producing strands of the olefin copolymer and solidifying the strands; (iii) cutting the strands of the olefin copolymer in the pelletiser into pellets; and (iv) drying the pellets, characterised in that the pellet water in the pelletiser contains from 0.5 to 6.0% by weight of a colloidal silica based on the weight of the water, wherein the colloidal silica has a particle size of from 30 to 200 nm and the pH of the pellet water is adjusted within the range of from 6 to 10.

2. The process according to claim 1 comprising the additional steps of: (v) introducing a stream comprising the water and the colloidal silica into the pelletiser; (vi) maintaining a level of the water and the colloidal silica in the pelletiser so that the entire die plate is maintained below the level of the water and the colloidal silica, thereby producing a slurry of the olefin copolymer pellets in the pelletiser; (vii) withdrawing a stream of the slurry of the olefin copolymer pellets from the pelletiser; (viii) passing the stream of the slurry of the olefin copolymer pellets into a dryer; and (ix) recovering from the dryer the pellets comprising the olefin copolymer and silica.

3. The process according to claim 2 comprising the additional steps of: (x) withdrawing a pellet water recycle stream from the drying step; (xi) optionally, adding into the pellet water recycle stream make-up water and make-up colloidal silica; and (xii) passing the pellet water recycle stream into the pelletiser.

4. The process according to claim 1 wherein the pellet water in the pelletiser contains from 0.5 to 3.0% by weight of the colloidal silica based on the weight of the water.

5. The process according to claim 4 wherein the pellet water in the pelletiser contains from 0.6 to 1.5% by weight of the colloidal silica based on the weight of the water.

6. The process according to claim 1 wherein the colloidal silica has a particle size of from 30 to 100 nm.

7. The process according to claim 1 wherein the pH of the pellet water is adjusted within the range of from 8 to 10.

8. The process according to claim 1 comprising an additional step of storing the pellets at a temperature which is not greater than the Vicat softening temperature of the polymer.

9. A process for producing pellets from olefin copolymers comprising the steps of: (i) melting the olefin copolymer in an extruder; (ii) extruding the molten olefin copolymer through a die plate having a multitude of holes into a pellet water bath in a pelletiser thereby producing strands of the olefin copolymer and solidifying the strands; (iii) cutting the strands of the olefin copolymer in the pelletiser into pellets; and (iv) drying the pellets, characterised in that the pellet water in the pelletiser contains from 0.5 to 6.0% by weight of a colloidal silica based on the weight of the water, wherein the colloidal silica has a particle size of from 30 to 200 nm and the pH of the pellet water is adjusted within the range of from 6 to 10, wherein the olefin copolymer is a copolymer of ethylene with one or more comonomers selected from alpha-olefins having from 4 to 10 carbon atoms, and wherein the copolymer has a density of from 856 to 915 kg/m 3 .

10. A process for producing pellets from olefin copolymers comprising the steps of: (i) melting the olefin copolymer in an extruder; (ii) extruding the molten olefin copolymer through a die plate having a multitude of holes into a pellet water bath in a pelletiser thereby producing strands of the olefin copolymer and solidifying the strands; (iii) cutting the strands of the olefin copolymer in the pelletiser into pellets; and (iv) drying the pellets, characterised in that the pellet water in the pelletiser contains from 0.5 to 6.0% by weight of a colloidal silica based on the weight of the water, wherein the colloidal silica has a particle size of from 30 to 200 nm and the pH of the pellet water is adjusted within the range of from 6 to 10, wherein the olefin copolymer is a copolymer of ethylene with one or more comonomers selected from alpha-olefins having from 4 to 10 carbon atoms, wherein the copolymer has a density of from 856 to 915 kg/m 3 , and wherein the copolymer of ethylene has a melt flow rate MFR 2 of from 0.2 to 50 g/10 min.

11. The process according to claim 9 , wherein the copolymer has a density of from 860 to 910 kg/m 3 .

12. The process according to claim 10 , wherein the copolymer of ethylene has a melt flow rate MFR 2 of from 0.3 to 30 g/10 min.

Assignees

• Borealis Ag

Inventors

• Tran Anh Tuan
• Vijay Sameer

Classifications

• B29K2105/0094

  having particular viscosity · CPC title

• B29K2509/08

  Glass · CPC title

• C08J2323/00

  Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers · CPC title

• B29K2023/08

  Copolymers of ethylene (B29K2023/16 takes precedence) · CPC title

• B29B9/065

  under-water, e.g. underwater pelletizers · CPC title