Synthesis of photovoltaic conjugated polymers
US-2015210800-A1 · Jul 30, 2015 · US
US10099963B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10099963-B2 |
| Application number | US-201615245676-A |
| Country | US |
| Kind code | B2 |
| Filing date | Aug 24, 2016 |
| Priority date | Oct 1, 2015 |
| Publication date | Oct 16, 2018 |
| Grant date | Oct 16, 2018 |
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A reaction comprising an organic Zn precursor in the amounts of (1−y), an organic Sn precursor in the amounts of y and a base in the amount of (1−y). The product produced from the reaction is (SnO x ) y ZnO (1−y) .
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The invention claimed is: 1. A reaction comprising: mixing an organic Zn precursor in the amounts of (1−y) with, an organic Sn precursor in the amounts of y, and a base in the amount of(1−y) to 1, wherein 0>y>1 followed by annealing at a temperature from about 170° C. to about 220° C. to produce (SnO x ) y ZnO (1−y) , wherein 0>y>1, and wherein (SnO x ) y ZnO (1−y) contains from about 10 to 25% atomic % of acetate as characterized with x-ray photoelectron spectroscopy. 2. The reaction of claim 1 , wherein the organic Zn precursor comprises Zn(CH 3 CO 2 ) 2 *2H 2 O. 3. The reaction of claim 1 , wherein the organic Sn precursor comprises Sn(CH 3 CO 2 ) 2 . 4. The reaction of claim 1 , wherein the base is an alcohol. 5. The reaction of claim 1 , wherein the base is alkanolamine. 6. The reaction of claim 1 , wherein the reaction also comprises a solvent. 7. The reaction of claim 1 , wherein the solvent is 2-methoxyethanol. 8. The reaction of claim 1 , wherein the reaction occurs at a temperature above room temperature. 9. The reaction of claim 1 , wherein the reaction occurs at a temperature greater than 150° C. 10. The reaction of claim 1 , wherein the reaction occurs at a temperature less than 250° C. 11. The reaction of claim 1 , wherein the reaction occurs at a temperature less than 225° C. 12. The reaction of claim 1 , wherein (SnO x ) y ZnO (1−y) is used as an electron transport layer for an organic photovoltaic device. 13. A reaction comprising: mixing an organic Zn precursor comprising Zn(CH 3 CO) 2 in the amounts of (1−y) with an organic Sn precursor comprising Sn(CH 3 CO 2 ) 2 in the amounts of y, and a base comprising alkanolamine in the amount of (1−y) wherein 0>y>1, wherein the reaction occurs at a temperature less than 225° C. followed by annealing at a temperature from about 170° C. to about 220° C. to produce (SnO x ) y ZnO (1−y) , wherein 0>y>1, and wherein (SnO x ) y ZnO (1−y) contains from about 10 to 25% atomic % of acetate as characterized with x-ray photoelectron spectroscopy.
Zinc oxides, zincates, cadmium oxides, cadmiates, mercury oxides, mercurates or oxide forming salts thereof · CPC title
Electricity · mapped topic
Electricity · mapped topic
Tin oxides, stannates or oxide forming salts thereof, e.g. indium tin oxide [ITO] · CPC title
Electricity · mapped topic
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