Electrode, nonaqueous electrolyte battery, and battery pack

Patent metadata

Field	Value
Publication number	US-10096833-B2
Application number	US-201615064915-A
Country	US
Kind code	B2
Filing date	Mar 9, 2016
Priority date	Sep 20, 2013
Publication date	Oct 9, 2018
Grant date	Oct 9, 2018

Abstract

According to one embodiment, an electrode is provided. This electrode includes a current collector and an electrode layer formed on the current collector. The electrode layer contains an active material represented by LiMn1-x-yFexAyPO4 (where 0<x≤0.3, 0≤y≤0.1, and A is at least one selected from the group consisting of Mg, Ca, Al, Ti, Zn, and Zr). A pore diameter appearing at highest frequency in pore diameter distribution of the electrode layer obtained by mercury porosimetry falls within a range of 10 nm to 50 nm. A pore specific surface area of the electrode layer is from 12 m2/g to 30 m2/g.

First claim

What is claimed is:

1. An electrode comprising:
a current collector; and
an electrode layer formed on the current collector and containing an active material represented by LiMn 1-x-y Fe x A y PO 4 (wherein 0<x≤0.3, 0≤y≤0.1, and A is at least one selected from the group consisting of Mg, Ca, Al, Ti, Zn, and Zr),
wherein a pore diameter appearing at highest frequency in pore diameter distribution of the electrode layer obtained by mercury porosimetry falls within a range of 10 nm to 50 nm, and a pore specific surface area of the electrode layer is from 12 m 2 /g to 30 m 2 /g, and
wherein a pore volume of the electrode layer is from 0.17 mL to 0.29 mL per 1 g of the electrode layer.

2. The electrode according to claim 1 , wherein a density of the electrode layer is from 2 g/cm3 to 2.3 g/cm3.

3. The electrode according to claim 1 , wherein a carbon material is adhered to at least a portion of a surface of the active material.

4. The electrode according to claim 3 , wherein the carbon material is a carbonaceous material having an interplanar spacing d 002 at a (002) plane as measured by powder X-ray diffraction of 0.344 nm or more.

5. The electrode according to claim 1 , wherein the current collector comprises an aluminum foil, or an aluminum alloy foil containing at least one element selected from Mg, Ti, Zn, Mn, Fe, Cu, and Si.

6. The electrode according to claim 1 , wherein the electrode layer further contains at least one selected from the group consisting of lithium-manganese composite oxide, lithium-nickel composite oxide, lithium-cobalt composite oxide, lithium-nickel-cobalt composite oxide, lithium-manganese-cobalt composite oxide, lithium-nickel-cobalt-manganese composite oxide, lithium-nickel-cobalt-aluminum composite oxide, and lithium-manganese-nickel composite oxide having a spinel structure.

7. A nonaqueous electrolyte battery comprising:
a negative electrode containing a negative electrode active material;
a positive electrode; and
a nonaqueous electrolyte,
wherein the positive electrode is the electrode according to claim 1 .

8. The nonaqueous electrolyte battery according to claim 7 , wherein a Li insertion/extraction potential of the negative electrode active material is 0.8 V (vs. Li/Li+) or more.

9. The nonaqueous electrolyte battery according to claim 7 , wherein the negative electrode active material contains at least one of lithium titanate having a spinel structure and monoclinic β-type titanium composite oxide.

10. A battery pack comprising the nonaqueous electrolyte battery according to claim 7 .

Assignees

• Toshiba Kk

Inventors

• Hoshina Keigo
• Isozaki Yoshiyuki
• Inagaki Hiroki
• Takami Norio

Classifications

• H01M4/136

  Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy · CPC title

• H01M2004/027

  Negative electrodes · CPC title

• H01M4/5825 Primary

  Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines · CPC title

• C01B25/45

  containing plural metal, or metal and ammonium · CPC title

• H01M2004/028

  Positive electrodes · CPC title