Aqueous two-component coating compositions and high erosion resistance coatings produced therefrom

Patent metadata

Field	Value
Publication number	US-10093825-B2
Application number	US-201515306287-A
Country	US
Kind code	B2
Filing date	Mar 6, 2015
Priority date	Apr 24, 2014
Publication date	Oct 9, 2018
Grant date	Oct 9, 2018

Abstract

The present invention relates to an aqueous two-component coating composition comprising (1) an aqueous paint base component comprising (A) at least one aqueous dispersion of at least one polymeric resin and (B) at least one polycarbonate diol and also (2) a hardener component comprising (C) at least one polyisocyanate-modified polyester having an isocyanate content of 4% to 15%. The present invention also relates to a method for coating on substrates by applying the coating composition and also to the use thereof.

First claim

The invention claimed is:

1. An aqueous two-component coating composition comprising
(1) an aqueous paint base component comprising
(A) at least one aqueous dispersion of at least one polymeric resin
and
(B) at least one polycarbonate diol

and
(2) a hardener component comprising
(C) at least one polyisocyanate-modified polyester having an isocyanate content of 4% to 15%.

2. The aqueous two-component coating composition as claimed in claim 1 , wherein the paint base component (1) comprises at least one aqueous dispersion (A) which comprises at least one hydroxy-functional polymeric resin.

3. The aqueous two-component coating composition as claimed in claim 2 , wherein the hydroxy-functional polymeric resin is also carboxy-functional.

4. The aqueous two-component coating composition as claimed in claim 2 , wherein the hydroxy-functional polymeric resin is a polyacrylate resin.

5. The aqueous two-component coating composition as claimed in claim 1 , wherein the polyisocyanate-modified polyester (C) is a hexamethylene diisocyanate-modified polyester.

6. The aqueous two-component coating composition as claimed in claim 1 , wherein the modified polyester (C) is obtained by reaction of hexamethylene diisocyanate with a hydroxy-functional aliphatic polyester.

7. The aqueous two-component coating composition as claimed in claim 6 , wherein the hydroxy-functional aliphatic polyester is a polycaprolactone polymer.

8. The aqueous two-component coating composition as claimed in claim 1 ,
wherein the hardener component (2) further comprises a component which is different from the polyester (C) and comprises polyisocyanate groups, and
the fraction of the polyester (C) in the hardener component, based on the total amount of components present in the coating composition and comprising polyisocyanate groups, is from 40 to 70 wt %.

9. The aqueous two-component coating composition as claimed in claim 1 , wherein the paint base component (1) comprises at least two aqueous dispersions (A), at least one dispersion (A) being a secondary dispersion and at least one dispersion (A) being a primary dispersion.

10. The aqueous two-component coating composition as claimed in claim 9 , wherein the at least one secondary dispersion (A) and the at least one primary dispersion (A) comprise a hydroxy-functional polyacrylate resin as polymeric resin.

11. The aqueous two-component coating composition as claimed in claim 1 , wherein the paint base component (1) is obtained by, in order:
emulsifying a polycarbonate diol (B) in an aqueous dispersion (A), thereby obtaining a mixture, and
adding further components of the paint base component to the mixture obtained in the emulsifying.

12. A method for producing a coating on a substrate, the method comprising
applying a coating composition as claimed in claim 1 to a substrate, thereby obtaining an applied composition, and
subsequently curing the applied composition.

13. A coating obtained by the method as claimed in claim 12 .

14. A multicoat coating which comprises as topcoat the coating as claimed in claim 13 .

15. A method of improving the erosion resistance of a substrate, the method comprising:
producing a coating on a substrate in need thereof by the method of claim 12 , thereby obtaining a coated substrate.

16. The method of claim 15 , wherein the coated substrate has a rain erosion resistance greater than 180 minutes.

17. The method of claim 16 , wherein the coated substrate has a gloss value of between 0 and 15.

18. The aqueous two-component coating composition of claim 1 , having a volatile organic content of less than 250 g/l.

19. The aqueous two-component coating composition of claim 1 , wherein the composition does not comprise a silica-based matting agent, a silicate-based matting agent, or matting agent.

20. The aqueous two-component coating composition of claim 1 , wherein the composition does not comprise a matting agent.

Assignees

• Akzo Nobel Coatings Int Bv

Inventors

• Muench Juergen

Classifications

• C08G18/4277

  Caprolactone and/or substituted caprolactone · CPC title

• C08G18/10

  Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step · CPC title

• C08G18/12

  using two or more compounds having active hydrogen in the first polymerisation step · CPC title

• C08G18/4063

  Mixtures of compounds of group C08G18/62 with other macromolecular compounds · CPC title

• C09D167/04 Primary

  Polyesters derived from hydroxycarboxylic acids, e.g. lactones (C09D167/06 takes precedence) · CPC title