Fiber-reinforced resin sheet, integrated molded product and process for producing same

Patent metadata

Field	Value
Publication number	US-10093777-B2
Application number	US-201314442764-A
Country	US
Kind code	B2
Filing date	Dec 6, 2013
Priority date	Dec 26, 2012
Publication date	Oct 9, 2018
Grant date	Oct 9, 2018

Abstract

A fiber-reinforced resin sheet and an integrally molded article are provided. The fiber-reinforced resin sheet comprises a nonwoven fabric made of reinforcing fibers having a thermoplastic resin (A) impregnated on one side of the nonwoven fabric. The fiber-reinforced resin sheet satisfies any one of the following conditions (I) and (II):
(I) the nonwoven fabric has an area wherein the reinforcing fibers constituting the nonwoven fabric are exposed on the other side in the thickness direction of the nonwoven fabric, and (II) the nonwoven fabric has a thermoplastic resin (B) impregnated on the other side in thickness direction of the nonwoven fabric, and the nonwoven fabric has a reinforcing fiber volume ratio Vfm of up to 20% by volume, and wherein the thermoplastic resin (A) and the thermoplastic resin (B) form an interface layer in the sheet, and the interface layer has a concave-convex shape with a maximum height Ry of at least 50 μm and an average roughness Rz of at least 30 μm.

First claim

The invention claimed is:

1. A fiber-reinforced resin sheet comprising a nonwoven fabric made of reinforcing fibers having a thermoplastic resin (A) impregnated on a first side in the nonwoven fabric thickness direction,
wherein the reinforcing fiber in the sheet has an anti-plane angle θz of at least 5°; and
wherein the fiber-reinforced resin sheet satisfies either one of the following conditions (I) and (II):
(I) the nonwoven fabric has an area wherein the reinforcing fibers constituting the nonwoven fabric are exposed on a second side opposite to the first side in the thickness direction of the nonwoven fabric, wherein the area where the reinforcing fibers are exposed has a reinforcing fiber volume ratio Vfm of up to 20% by volume; or
(II) the nonwoven fabric has a thermoplastic resin (B) impregnated on the second side of the nonwoven fabric, and the nonwoven fabric has a reinforcing fiber volume ratio Vfm of up to 20% by volume, wherein the thermoplastic resin (A) and the thermoplastic resin (B) form an interface layer in the sheet, and the interface layer has a concave-convex shape with a maximum height Ry of at least 50 μm and an average roughness Rz of at least 30 μm.

2. The fiber-reinforced resin sheet according to claim 1 , wherein the resin sheet satisfies the condition (I).

3. The fiber-reinforced resin sheet according to claim 1 , wherein the resin sheet satisfies the condition (II).

4. The fiber-reinforced resin sheet according to claim 1 , wherein the thermoplastic resin (A) usable temperature range and the thermoplastic resin (B) usable temperature range overlap with each other over an overlapping temperature range of at least 5° C.

5. The fiber-reinforced resin sheet according to claim 1 , wherein discontinuous reinforcing fibers are dispersed in a substantially monofilament state in the nonwoven fabric.

6. The fiber-reinforced resin sheet according to claim 1 , wherein the reinforcing fiber constituting the nonwoven fabric is carbon fiber.

7. An integrally molded article comprising a first member constituted from the fiber-reinforced resin sheet according to claim 2 and a second member which is a different molded article comprising a thermoplastic resin (B) joined to the first member by impregnation of the thermoplastic resin (B) into the area where the reinforcing fibers are exposed in the fiber-reinforced resin sheet.

8. An integrally molded article comprising a first member which is the fiber-reinforced resin sheet according to claim 3 ; and a second member joined to the first member which is a different molded article.

9. An integrally molded article comprising: a first member which is a molded article containing the fiber-reinforced resin sheet according to claim 3 ; and a second member joined to the first member which is a different molded article.

10. The integrally molded article according to claim 7 wherein the thermoplastic resin (A) and the thermoplastic resin (B) forms an interface layer having a concave-convex shape with a maximum height Ry of at least 50 μm and an average roughness Rz of at least 30 μm.

11. A method for producing the integrally molded article according to claim 7 wherein the second member is a molded article prepared by injection molding, and the second member is joined to the first member by insert injection molding or outsert injection molding.

12. A method for producing the integrally molded article according to claim 7 wherein the second member is a molded article prepared by press molding, and the second member is joined to the first member by press molding.

13. The integrally molded article according to claim 7 wherein the article is used for automobile interior or exterior material, housing of electric or electronic equipment, structural member of a bicycle or sport equipment, aircraft interior finishing material, or transportation package.

14. The integrally molded article according to claim 8 wherein the thermoplastic resin (A) and the thermoplastic resin (B) forms an interface layer having a concave-convex shape with a maximum height Ry of at least 50 μm and an average roughness Rz of at least 30 μm.

15. A method for producing the integrally molded article according to claim 8 wherein the second member is a molded article prepared by injection molding, and the second member is joined to the first member by insert injection molding or outsert injection molding.

16. A method for producing the integrally molded article according to claim 8 wherein the second member is a molded article prepared by press molding, and the second member is joined to the first member by press molding.

17. The integrally molded article according to claim 8 wherein the article is used for automobile interior or exterior material, housing of electric or electronic equipment, structural member of a bicycle or sport equipment, aircraft interior finishing material, or transportation package.

Assignees

• Toray Industries

Inventors

• Takebe Yoshiki
• Kihara Hiroki
• Hirano Noriyuki

Classifications

• C08J2371/12

  Polyphenylene oxides · CPC title

• B29K2101/12

  Thermoplastic materials · CPC title

• C08J2323/12

  Polypropene · CPC title

• B32B27/12

  next to a fibrous or filamentary layer · CPC title

• B29C43/305

  Making multilayered articles · CPC title