Lithium titanium sulfide, lithium niobium sulfide, and lithium titanium niobium sulfide

Patent metadata

Field	Value
Publication number	US-10090524-B2
Application number	US-201414777932-A
Country	US
Kind code	B2
Filing date	Mar 17, 2014
Priority date	Mar 18, 2013
Publication date	Oct 2, 2018
Grant date	Oct 2, 2018

Abstract

The present invention provides a novel lithium titanium sulfide, lithium niobium sulfide, or lithium titanium niobium sulfide that contains a sulfide containing lithium, titanium and/or niobium, and sulfur as constituent elements, and that has excellent charge-discharge performance (especially excellent charge-discharge capacity and charge-discharge potential) useful as a cathode active material or the like for lithium batteries, such as metal lithium secondary batteries or lithium-ion secondary batteries. Particularly preferred are, for example, (1) lithium titanium sulfide containing lithium, titanium, and sulfur as constituent elements and having a cubic rock salt crystal structure, (2) lithium niobium sulfide containing lithium, niobium, and sulfur as constituent elements and having a diffraction peak at a specific position in an X-ray diffractogram, and (3) lithium titanium niobium sulfide containing lithium, titanium, niobium, and sulfur as constituent elements and having a diffraction peak at a specific position in an X-ray diffractogram.

First claim

We claim:

1. A sulfide comprising lithium, titanium and/or niobium, and sulfur as constituent elements, wherein the sulfide is characterized by any one of the following (1) to (3):
(1) a lithium titanium sulfide comprising lithium, titanium, and sulfur as constituent elements, wherein the lithium titanium sulfide has a cubic rock salt crystal structure and comprises lithium and titanium ions that randomly occupy cationic sites;
(2) a lithium niobium sulfide comprising lithium, niobium, and sulfur as constituent elements and having diffraction peaks at positions of at least 35.0°, 50.3°, and 62.7° in the diffraction angle range of 2θ=10° to 80° with a tolerance of ±2° in an X-ray diffractogram obtained using Cu Kα radiation; and
(3) a lithium titanium niobium sulfide comprising lithium, titanium, niobium, and sulfur as constituent elements and having diffraction peaks at positions of at least 30.5°, 35.3°, 50.6°, and 63.2° in the diffraction angle range of 2θ=10° to 80° with a tolerance of ±2° in an X-ray diffractogram obtained using Cu Kα radiation.

2. The sulfide according to claim 1 , wherein the lithium titanium sulfide of (1) is represented by Li n1 TiS m1 , wherein 0.4≤n1≤6 and 2≤m1≤5.

3. The sulfide according to claim 1 , wherein the lithium titanium sulfide of (1) has diffraction peaks at positions of at least 30.6°, 35.5°, 51.0°, 60.6°, and 63.7° in the diffraction angle range of 2θ=10° to 80° with a tolerance of ±2° in an X-ray diffractogram obtained using Cu Kα radiation.

4. A method for producing the sulfide according to claim 1 , which is the lithium titanium sulfide of (1), comprising a step of subjecting lithium sulfide, titanium sulfide, and optionally sulfur, to mechanical milling as starting materials.

5. The sulfide according to claim 1 , wherein the composition ratio of sulfur S to niobium Nb, S/Nb, of the lithium niobium sulfide of (2) is in the range of 2 to 6 in terms of the molar ratio.

6. The sulfide according to claim 1 , wherein the composition ratio of lithium Li to niobium Nb, Li/Nb, of the lithium niobium sulfide of (2) is in the range of 1 to 5 in terms of the molar ratio.

7. The sulfide according to claim 1 , wherein the lithium niobium sulfide of (2) has a cubic crystal structure.

8. The sulfide according to claim 1 , wherein the lithium niobium sulfide of (2) has a diffraction peak at a position of 73.9° in the diffraction angle range of 2θ=10° to 80° with a tolerance of ±2° in an X-ray diffractogram obtained using Cu Kα radiation.

9. A method for producing the sulfide according to claim 1 , is the lithium niobium sulfide of (2) comprising a step of subjecting lithium sulfide, niobium sulfide, and optionally sulfur, to mechanical milling as starting materials.

10. The sulfide according to claim 1 , wherein the composition ratio of sulfur S to the sum of titanium Ti and niobium Nb, S/(Ti+Nb), of the lithium titanium niobium sulfide of (3) is in the range of 2 to 6 in terms of the molar ratio.

11. The sulfide according to claim 1 , wherein the composition ratio of lithium Li to the sum of titanium Ti and niobium Nb, Li/(Ti+Nb), of the lithium titanium niobium sulfide of (3) is in the range of 0.4 to 6 in terms of the molar ratio.

12. The sulfide according to claim 1 , wherein the lithium titanium niobium sulfide of (3) has a cubic crystal structure.

13. A method for producing the sulfide according to claim 1 , which is the lithium titanium niobium sulfide of (3) comprising subjecting lithium sulfide, titanium sulfide, niobium sulfide, and optionally sulfur, to mechanical milling as starting materials.

14. A charge and discharge product of the sulfide according to claim 1 .

15. An electrode for lithium batteries comprising, as an electrode active material, the sulfide according to claim 1 .

16. The electrode for lithium batteries according to claim 15 , which is a cathode for lithium batteries.

17. A lithium battery comprising the electrode for lithium batteries according to claim 15 .

18. The lithium battery according to claim 17 , further comprising a non-aqueous electrolyte comprising a carbonate-containing solvent.

19. The lithium battery according to claim 18 , wherein the carbonate content of the solvent in the non-aqueous electrolyte is 1 to 100 volume %.

Assignees

• Aist

Inventors

• Sakuda Atsushi
• Takeuchi Tomonari
• Sakaebe Hikari
• Tatsumi Kuniaki

Classifications

• Y02T10/7011

  Cross-Sectional Technologies · mapped topic

• H01M10/052

  Li-accumulators · CPC title

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• H01M2004/028

  Positive electrodes · CPC title

• H01M10/0569

  characterised by the solvents · CPC title