Systems and methods for authenticating working fluids

Patent metadata

Field	Value
Publication number	US-10088430-B2
Application number	US-201715412099-A
Country	US
Kind code	B2
Filing date	Jan 23, 2017
Priority date	Feb 15, 2016
Publication date	Oct 2, 2018
Grant date	Oct 2, 2018

Abstract

Systems and methods are provided for authenticating working fluids. The systems and methods include exposing at least a portion of a working fluid containing a UV-reactive chemical marker to light having wavelengths in the range of about 10-400 nm, thereby causing the chemical marker to generate a signal. The signal can be detected via a sensor system and compared to a reference signal that is associated with an authentic working fluid. An output may be generated to indicate whether the working fluid is the authentic working fluid.

First claim

The invention claimed is:

1. A method for in-situ authentication of a working fluid containing a UV-reactive chemical marker, the method comprising:
introducing the working fluid into a mechanical system wherein the working fluid is selected from a group consisting of a lubricant, an oil, a coolant, an hydraulic fluid, a fuel and an oil field chemical;
exposing at least a portion of the working fluid to a light having wavelengths in a range of about 10-400 nm, thereby causing the chemical marker to generate a signal;
detecting the chemical marker signal via a sensor system disposed on or within the mechanical system; and
comparing the signal generated by the chemical marker to a reference signal that is associated with an authentic working fluid;
further comprising generating an output indicating whether the working fluid is the authentic working fluid wherein the chemical marker is a quinone and the signal generated by the chemical marker is fluorescence.

2. A method for in-situ authentication of a working fluid containing a UV-reactive chemical marker, the method comprising:
introducing the working fluid into a mechanical system wherein the working fluid is selected from a group consisting of a lubricant, an oil, a coolant, an hydraulic fluid, a fuel and an oil field chemical;
exposing at least a portion of the working fluid to a light having wavelengths in a range of about 10-400 nm, thereby causing the chemical marker to generate a signal;
detecting the chemical marker signal via a sensor system disposed on or within the mechanical system; and
comparing the signal generated by the chemical marker to a reference signal that is associated with an authentic working fluid
wherein the signal generated by the chemical marker is a RGB color value.

3. The method of claim 2 , wherein the chemical marker is selected from a group consisting of a dye, a colorant, a polyaromatic hydrocarbon, asphaltene, quinone, detergent, ionic liquid, metallic nanoparticle, semi-conductor nanoparticle, fluorescent compound, enzyme, DNA, RNA, polypeptide, redox-active organometallic complex and array of molecules with unique molecular weight distributions.

4. A system for determining whether a working fluid containing a UV-reactive chemical marker is an authentic working fluid, the system comprising:
a control instrument having a reference signal that corresponds to the authentic working fluid;
a sensor operable for receiving a signal that is generated from the chemical marker in the working fluid upon exposure to UV light, wherein the sensor is communicatively connected to the control instrument wherein the working fluid is selected from a group consisting of a lubricant, an oil, a hydraulic fluid, a fuel and an oil field chemical,
wherein the control instrument is operable for receiving the signal from the sensor and comparing the reference signal to the working fluid signal and generating an output to indicate whether the working fluid is the authentic working fluid wherein the chemical marker is selected from a group consisting of a dye, a colorant, a polyaromatic hydrocarbon, asphaltene, quinone, detergent, ionic liquid, metallic nanoparticle, semi-conductor nanoparticle, fluorescent compound, enzyme, DNA, RNA, polypeptide, redox-active organometallic complex and array of molecules with unique molecular weight distributions and wherein the signal generated by the chemical marker in the working fluid is a RGB color value.

5. A system for determining whether a working fluid containing a UV-reactive chemical marker is an authentic working fluid, the system comprising:
a control instrument having a reference signal that corresponds to the authentic working fluid;
a sensor operable for receiving a signal that is generated from the chemical marker in the working fluid upon exposure to UV light, wherein the sensor is communicatively connected to the control instrument wherein the working fluid is selected from a group consisting of a lubricant, an oil, a hydraulic fluid, a fuel and an oil field chemical,
wherein the control instrument is operable for receiving the signal from the sensor and comparing the reference signal to the working fluid signal and generating an output to indicate whether the working fluid is the authentic working fluid wherein the chemical marker is a quinone and the signal generated by the chemical marker is fluorescence.

Assignees

• Exxonmobil Res & Eng Co

Inventors

• VANDER NEUT Christopher
• Blumenfeld Michael L
• Senzer Eric B
• Bainbridge Samuel C

Classifications

• G01N2201/061

  Sources · CPC title

• Y10T436/13

  Tracers or tags · CPC title

• G01N21/643

  non-biological material · CPC title

• G01N33/22

  Fuels; Explosives · CPC title

• G01N33/28

  Oils {, i.e. hydrocarbon liquids} (edible oils or edible fats G01N33/03) · CPC title