Carbon fiber manufacturing method

Patent metadata

Field	Value
Publication number	US-10087558-B2
Application number	US-201414780287-A
Country	US
Kind code	B2
Filing date	Mar 26, 2014
Priority date	Mar 27, 2013
Publication date	Oct 2, 2018
Grant date	Oct 2, 2018

Abstract

A carbon fiber manufacturing method with which high quality carbon fibers can be obtained. The carbon fiber manufacturing method includes introducing carbon fiber precursor fiber bundles that have been spread in sheet form into a flameproofing furnace, flameproofing the carbon fiber precursor fiber bundles introduced into the flameproofing furnace in a temperature range of 200° C. to 300° C., introducing the flameproofed fiber bundles obtained from the flameproofing treatment into a carbonization furnace, and carbonizing the flameproofed fiber bundles introduced into the carbonization furnace in a temperature range of 300° C. to 2500° C. The flameproofing furnace includes a heat-treatment chamber and a sealing chamber adjacent thereto and discharges air from the sealing chamber to outside of the flameproofing furnace. The space velocity (SV) (1/h) of hot air blown from the heat-treatment chamber into the sealing chamber satisfies relationship: 80≤SV≤400.

First claim

The invention claimed is:

1. A method for manufacturing a carbon fiber, the method comprising:
introducing carbon fiber precursor fiber bundles that have been spread in sheet form into a flameproofing furnace;
flameproofing the carbon fiber precursor fiber bundles introduced into the flameproofing furnace at a temperature of from 200° C. to 300° C.;
introducing the flameproofed fiber bundles obtained from the flameproofing treatment into a carbonization furnace; and
carbonizing the flameproofed fiber bundles introduced into the carbonization furnace at a temperature of from 300° C. to 2500° C.;
wherein the flameproofing furnace comprises a heat-treatment chamber and a sealing chamber adjacent thereto and discharges air from the sealing chamber to outside of the flameproofing furnace; and
wherein space velocity (SV) (1/h) of the hot air blown from the heat-treatment chamber into the sealing chamber satisfies the following relationship: 80≤SV≤400.

2. The method for manufacturing a carbon fiber according to claim 1 , wherein, when an introduction amount of the carbon fiber precursor fiber bundles into the flameproofing furnace is designated as Y (kg/h) and a total air discharge amount from the heat-treatment chamber to the outside of the heat-treatment chamber is designated as X (Nm 3 /h), a ratio of Y/X satisfies the following relationship: 0.001≤Y/X≤0.012.

3. The method for manufacturing a carbon fiber according to claim 1 , wherein:
the flameproofing is performed by transporting the carbon fiber precursor fiber bundles, in the fiber direction of the carbon fiber precursor fiber bundles, through the inside of the heat-treatment chamber, in which the transport is made such that the carbon fiber precursor fiber bundles are transported in parallel relationship at plural points inside the heat-treatment chamber; and
the sealing chamber comprises outer slits open on an outer side of the flameproofing furnace and inner slits open on the heat-treatment chamber, wherein the number of the outer slits and the number of the inner slits are the same as the number of times the carbon fiber precursor fiber bundles are transported.

4. The method for manufacturing a carbon fiber according to claim 3 , wherein:
the flameproofing is performed such that the transport is made in the horizontal direction in the heat-treatment chamber while plural points indicate plural points at vertically different positions in the heat-treatment chamber; and
each of the plural outer slits is formed at vertically different positions and an opening area of the outer slit present at a lowermost side in the vertical direction is smaller than an opening area of the outer slit present at an uppermost side.

5. The method for manufacturing a carbon fiber according to claim 2 , wherein:
the flameproofing is performed by transporting the carbon fiber precursor fiber bundles, in the fiber direction of the carbon fiber precursor fiber bundles, through the inside of the heat-treatment chamber, in which the transport is made such that the carbon fiber precursor fiber bundles are transported in parallel relationship at plural points inside the heat-treatment chamber; and
the sealing chamber comprises outer slits open on an outer side of the flameproofing furnace and inner slits open on the heat-treatment chamber, wherein the number of the outer slits and the number of the inner slits are the same as the number of times the carbon fiber precursor fiber bundles are transported.

6. The method for manufacturing a carbon fiber according to claim 5 , wherein:
the flameproofing is performed such that the transport is made in the horizontal direction in the heat-treatment chamber while plural points indicate plural points at vertically different positions in the heat-treatment chamber; and
each of the plural outer slits is formed at vertically different positions and an opening area of the outer slit present at a lowermost side in the vertical direction is smaller than an opening area of the outer slit present at an uppermost side.

Assignees

• Mitsubishi Chem Corp

Inventors

• Hatayama Akito
• Sugiura Naoki
• Hata Masahiro

Classifications

• D06C7/04 Primary

  Carbonising or oxidising (processes comprising combined chemical and mechanical treatment D06M) · CPC title

• D01F9/328 Primary

  for manufacturing filaments from polyaddition, polycondensation, or polymerisation products · CPC title

• F27B9/28

  for treating continuous lengths of work · CPC title

• F27D99/0073

  Seals · CPC title

• F27B9/145

  the charge moving along a serpentine path · CPC title