Reduced density article

Patent metadata

Field	Value
Publication number	US-10087556-B2
Application number	US-201415036562-A
Country	US
Kind code	B2
Filing date	Nov 7, 2014
Priority date	Nov 21, 2013
Publication date	Oct 2, 2018
Grant date	Oct 2, 2018

Abstract

A reduced density article of manufacture, and process for making same, made from a thermoplastic polycarbonate composition. The reduced density article of manufacture has (1) a certain density and (2) a certain micro structure containing from 1% to 20% by volume of voids wherein at least 80% of the voids are high aspect voids and less than 20% of the voids are spherical voids with a diameter of 10 to 100 microns. The polycarbonate thermoplastic composition comprises at least 50 mole % of a certain bisphenol A. The reduced density article of manufacture is made by a monofilament additive manufacturing technique.

First claim

The invention claimed is:

1. A reduced density article of manufacture comprising a thermoplastic polycarbonate composition, the reduced density article of manufacture having (1) a density as measured by ASTM D792-00 of 80% to 99% by weight of a similar solid standard injection molded article having no voids and (2) a micro structure measured by optical microscopy containing from 1% to 20% by volume of voids wherein at least 80% of the voids are high aspect voids and less than 20% of the voids are spherical voids with a diameter of 10 to 100 microns; wherein the polycarbonate thermoplastic composition comprises at least 50 mole % bisphenol A having a weight-average molecular weight (Mw) of 10,000 to 50,000, a glass transition temperature (Tg) from 130 to 180 degrees C., a phenolic OH end group content of less than 50 ppm, a halide group content below 100 ppm, and a diaryl carbonate content below 1% by weight; and wherein the reduced density article of manufacture is made by a monofilament additive manufacturing technique.

2. The reduced density article of manufacture of claim 1 wherein the reduced density article of manufacture further comprises at least 50 ppm of a triaryl phosphate having a weight average molecular weight (Mw) of at least 300.

3. The reduced density article of manufacture of claim 1 wherein the reduced density article of manufacture further comprises at least 100 ppm of a mixture of triaryl phosphate and triaryl phosphite each having a weight average molecular weight (Mw) of at least 300, wherein the wherein the triaryl phosphate is present in a greater amount than the triaryl phosphite.

4. The reduced density article of manufacture of claim 1 wherein thermoplastic polycarbonate composition has a carbamate group content of less than 10 ppm.

5. The reduced density article of manufacture of claim 1 wherein the article has high surface roughness with vertical deviation of at least 0.01 mm, or wherein the article has a grooved surface as measured by ISO 4287 (1997) with a groove depth from 20 to 100 micro meters (μm) and groove spacing of from 0.05 to 2.0 mm.

6. The reduced density article of manufacture of claim 1 wherein the reduced density article of manufacture further comprises a thermoplastic material chosen from acrylonitrile butadiene styrene (ABS), acrylic rubber, methacrylate styrene butadiene (MB S), polyacrylates (acrylic), polybutylene terephthalate (PBT), polyethylene terephthalate (PET), polycyclohexylene dimethylene terephthalate (PCT), polyhydroxyalkanoates (PHAs), polyester carbonates, polyetherimide (PEI), polytrimethylene terephthalate (PTT), styrene-acrylonitrile (SAN), silicone polycarbonate copolymers, or any combination thereof and, optionally, wherein the article comprises less than 5 weight % of a member selected from the group consisting of (i) polyvinyl chloride (PVC), polyvinylidene chloride, polyacetal, cellulosics; cellulose acetate, cellulose butyrate, cellulose propionate, polychloroprene, melamine formaldehyde, urea formaldehyde, polyacrylamide, and combinations thereof.

7. The reduced density article of manufacture of claim 1 wherein at least 90% of the voids are high aspect voids and less than 10% of the voids are spherical voids with a diameter of 10 to 100 microns.

8. The reduced density article of manufacture of claim 1 wherein least 20% of the voids are angular voids having a cusp angle that is an acute angle of 60 degrees or less.

9. The reduced density article of manufacture of claim 1 wherein the article has a tensile strength at yield of greater than 5,000 psi, and a flex modulus at 100° C. greater than 1,000 psi.

10. The article of claim 1 wherein the reduced density article of manufacture further comprises a colorant chosen from solvent violet 36, pigment blue 60, pigment blue 15:1, pigment blue 15.4, carbon black, titanium dioxide or any combination thereof.

11. The article of claim 1 wherein the high aspect voids have an aspect ratio from 2:1 to 100:1 with a major length of less than 5 mm.

12. A reduced density article of manufacture comprising a mixture of thermoplastic polycarbonate composition and at least 50 ppm of a triaryl phosphate having a weight average molecular weight (Mw) of at least 300, the reduced density article of manufacture having (1) a density as measured by ASTM D792-00 of 80% to 95% by weight of a similar standard injection molded article having no voids; (2) having a micro structure as measured by optical microscopy containing from 1% to 20% by volume of voids wherein at least 80% of the voids are high aspect voids have an aspect ratio from 2:1 to 100:1 with a major length of less than 5 mm and less than 20% of the voids are spherical voids with a diameter of 10 to 100 microns; wherein the polycarbonate thermoplastic composition comprises at least 50 mole % bisphenol A having a weight-average molecular weight (Mw) of 10,000 to 50,000, a glass transition temperature (Tg) from 130 to 180 degrees C., a phenolic OH end group content of less than 50 ppm, a halide group content below 100 ppm, and a diaryl carbonate content below 1% by weight, a tensile strength at yield of greater than 5,000 psi, and a flex modulus at 100° C. greater than 1,000 psi; and wherein the reduced density article of manufacture is made by an monofilament additive manufacturing technique using a monofilament having a diameter from 0.01 to 5.0 mm.

13. The reduced density article of manufacture of claim 12 wherein the material in the article contains at least 100 ppm of a mixture of triaryl phosphate and triaryl phosphite each having a weight average molecular weight (Mw) of at least 300, wherein the wherein the triaryl phosphate is present in a greater amount than the triaryl phosphite.

14. A process for making a reduced density article of manufacture comprising (1) depositing a multitude of thermoplastic monofilament strands having a diameter from 0.1 to 20.0 mm using a fused deposition modeling apparatus in a crossing pattern and (2) fusing the multitude of strands together to make a reduced density article of manufacture having voids therein; wherein the a reduced density article of manufacture comprises a thermoplastic polycarbonate composition, the reduced density article of manufacture having (a) a density as measured by ASTM D792-01 of 80% to 99% by weight of a similar standard injection molded article having no voids and (b) a micro structure as measured by optical microscopy containing from 1% to 20% by volume of voids wherein at least 80% of the voids are high aspect voids and less than 20% of the voids are spherical voids with a diameter of 10 to 100 microns; wherein the polycarbonate thermoplastic composition comprises at least 50 mole % bisphenol A having a weight-average molecular weight (Mw) of 10,000 to 50,000, a glass transition temperature (Tg) from 130 to 180 degrees C., a phenolic OH end group content of less than 50 ppm, a halide group content below 100 ppm, and a diaryl carbonate content below 1% by weight.

15. The process for making a reduced density article of manufacture of claim 14 wherein steps (1) and (2) are carried out in an inert atmosphere containing less than 1 volume % oxygen and wherein the inert atmosphere is chosen from nitrogen, carbon dioxide, argon, krypton, xenon and mixtures thereof.

16. The process for making a reduced density article of manufacture of claim 14 wherein each monofilament comprises a thermoplastic polycarbonate composition strand with a diameter of 0.1 to 5 mm that is deposited by an extrusion head of a fused deposition modeling apparatus in an oven at a temperature from 280 to 380 degrees C. for average re

Assignees

• Sabic Global Technologies Bv

Inventors

• Gallucci Robert R
• Pai-Paranjape Vandita
• Hocker Thomas
• Cox Keith E

Classifications

• C08L69/00

  Compositions of polycarbonates; Compositions of derivatives of polycarbonates · CPC title

• D10B2401/041

  thermoplastic; thermosetting · CPC title

• B29K2069/00

  Use of PC, i.e. polycarbonates {or derivatives thereof}, as moulding material · CPC title

• B33Y10/00

  Processes of additive manufacturing · CPC title

• D01F1/10

  Other agents for modifying properties · CPC title