Method and system for reducing residual soap in crude tall oil

Patent metadata

Field	Value
Publication number	US-10087394-B2
Application number	US-201615202715-A
Country	US
Kind code	B2
Filing date	Jul 6, 2016
Priority date	Jul 8, 2015
Publication date	Oct 2, 2018
Grant date	Oct 2, 2018

Abstract

The present invention relates to a method and system for reducing residual soap in crude tall oil, wherein crude tall oil is supplied via piping to at least one vessel, soap number of the crude tall oil is determined using on-line measuring technique and sulphuric acid is added to the crude tall oil at a site of blending, where the dosing of the sulphuric acid is adjusted on-line to provide soap number of not more than 2.

First claim

The invention claimed is:

1. A method for reducing residual soap in crude tall oil, wherein the method comprises the steps, where
a material consisting of crude tall oil containing up to 10,000 ppm of metals is supplied to at least one vessel,
soap number of the crude tall oil is measured on-line,
an amount of sulphuric acid having concentration between 20-50 wt %, needed for adjusting the soap number to a value of not more than 2 is determined, and
the determined amount of sulphuric acid is added to the crude tall oil at a site of blending whereby treated crude tall oil having soap number not more than 2 is obtained.

2. The method according to claim 1 , wherein the method further comprises the steps where
the measured soap number is transmitted as an input to a controlling unit, which controlling unit determines as an output the amount of sulphuric acid needed for adjusting the soap number to a value of not more than 2,
the output of the amount of sulphuric acid is transmitted to a sulphuric acid dosing device, and
the amount of sulphuric acid is added to the crude tall oil according to the output, at a site of blending of crude tall oil and sulphuric acid.

3. The method according to claim 1 , wherein the crude tall oil is supplied via a line to at least one vessel.

4. The method according to claim 3 , wherein the soap number is measured from the crude tall oil running in the line.

5. The method according to claim 3 , wherein the crude tall oil is supplied using an unloading pump.

6. The method according to claim 5 , wherein the line comprises a pipeline mixer downstream the unloading pump.

7. The method according to claim 6 , wherein sulphuric acid is added to the crude tall oil to suction side of the unloading pump or to a line downstream the unloading pump but prior to the pipeline mixer.

8. The method according to claim 3 , wherein the soap number of the crude tall oil running in the line is measured using an on-line measuring device.

9. The method according to claim 3 , wherein the length of the line between the site of blending and the vessel is at least 20 m.

10. The method according to claim 3 , wherein after the adding of sulphuric acid at the site of blending, a mixture is obtained, which is transferred via the line between the site of blending and the vessel to the vessel, and the mixture is allowed to settle whereby an aqueous phase and treated crude tall oil are formed.

11. The method according to claim 10 , wherein the treated crude tall and the aqueous phase are separated and the treated crude tall oil having soap number of not more than 2 is recovered.

12. The method according to claim 1 , wherein the adding of sulphuric acid is adjusted to provide soap number of the treated crude tall oil of not more than 1.

13. The method according to claim 1 , wherein the adding of sulphuric acid is adjusted to provide soap number of the treated crude tall oil of not more than 0.5.

14. The method according to claim 1 , wherein the adding of sulphuric acid is adjusted to provide soap number of the treated crude tall oil of not more than 0.2.

15. The method according to claim 1 , wherein the on-line measuring of the soap number is carried out by a FT-NIR method.

16. The method according to claim 1 , wherein the temperature of the crude tall oil, which is supplied, is maintained at 30-100° C.

17. The method according to claim 1 , wherein the temperature of the crude tall oil, which is supplied, is maintained at 30-85° C.

18. The method according to claim 1 , wherein the temperature of the crude tall oil, which is supplied, is maintained at 50-80° C.

19. The method according to claim 1 , wherein temperature in the vessel is maintained at 30-85° C.

20. The method according to claim 1 , wherein the temperature in the vessel is maintained at 40-70° C.

21. The method according to claim 1 , wherein the temperature in the vessel is maintained at 50-60° C.

22. The method according to claim 1 , wherein crude tall oil supplied from a pulping plant, tanker truck or tanker ship.

Assignees

• Upm Kymmene Corp

Inventors

• Kotoneva Jari

Classifications

• C11B13/005 Primary

  of residues of the fabrication of wood-cellulose (in particular tall-oil) · CPC title

• Y02W30/74

  Recovery of fats, fatty oils, fatty acids or other fatty substances, e.g. lanolin or waxes · CPC title

• C11B3/04 Primary

  with acids · CPC title

• D21C11/0007

  Recovery of by-products, i.e. compounds other than those necessary for pulping, for multiple uses or not otherwise provided for (volatile compounds obtained by decomposition of spent liquors in order to regenerate them D21C11/125; compounds obtained by fractionating the liquors in order to regenerate them D21C11/0042) · CPC title