Aviation fuel additive scavenger

Patent metadata

Field	Value
Publication number	US-10087383-B2
Application number	US-201615083890-A
Country	US
Kind code	B2
Filing date	Mar 29, 2016
Priority date	Mar 29, 2016
Publication date	Oct 2, 2018
Grant date	Oct 2, 2018

Abstract

Aviation fuel formulations receive many benefits when a manganese-containing additive is incorporated in that composition. However, to the extent that the use of a manganese-containing compound may result in the formation of engine deposits during combustion, it is beneficial to further provide a scavenger compound to the fuel composition. This scavenger compound may include a phosphorus-containing compound, an organobromide compounds, and/or a tricarbonyl compound.

First claim

What is claimed is:

1. An aviation fuel additive composition comprising a cyclopentadienyl manganese tricarbonyl compound and a manganese scavenger compound, wherein the manganese scavenger compound is selected from triphenyl phosphine oxide, a triphenyl phosphine, and a tricarbonyl compound.

2. An aviation fuel additive composition as described in claim 1 , wherein the manganese scavenger compound is triphenyl phosphine oxide, triphenyl phosphine, or mixtures thereof and which is present in an amount to be a stoichiometric ratio of Mn to P of from about 1:0.1 to 1:10.

3. An aviation fuel additive composition as described in claim 1 , wherein the cyclopentadienyl manganese tricarbonyl comprises methylcyclopentadienyl manganese tricarbonyl.

4. An aviation fuel additive composition as described in claim 3 , wherein an amount of the methylcyclopentadienyl manganese tricarbonyl in the aviation fuel additive composition is sufficient to provide equals about 1 to 500 mg Mn/l to an aviation fuel composition.

5. An aviation fuel additive composition as described in claim 1 , wherein the manganese scavenger compound is the tricarbonyl compound and selected from the group consisting of glycerol triacetate; triethyl 1, 1, 2-ethanetricarboxylate; triethyl citrate, and tributyl citrate.

6. An aviation fuel additive composition as described in claim 5 , wherein an amount of the tricarbonyl compound relative to an amount of manganese in the fuel additive is from about 1:0.05 to 1:10 mass ratio of manganese to tricarbonyl.

7. An aviation fuel additive composition as described in claim 5 , wherein the cyclopentadienyl manganese tricarbonyl comprises methylcyclopentadienyl manganese tricarbonyl.

8. An aviation fuel additive composition as described in claim 7 , wherein an amount of the methylcyclopentadienyl manganese tricarbonyl is sufficient to provide about 1 to 500 mg Mn/l to an aviation fuel composition.

9. An aviation fuel additive composition comprising:
(a) an amount of one or more cyclopentadienyl manganese tricarbonyl compounds sufficient to provide about 0.5 to 500 mg Mn/l to an aviation fuel composition,
(b) a scavenger selected from triphenyl phosphine oxide, triphenyl phosphine, and tricarbonyl compounds,
and wherein the composition is substantially lead free.

10. An aviation fuel additive composition as described in claim 9 , wherein the scavenger is triphenyl phosphine oxide, triphenyl phosphine, or mixtures thereof and which is present in an amount to be a stoichiometric ratio of Mn to P of from about 1:0.1 to 1:10.

11. An aviation fuel additive composition as described in claim 9 , wherein the cyclopentadienyl manganese tricarbonyl comprises methylcyclopentadienyl manganese tricarbonyl.

12. An aviation fuel additive composition as described in claim 9 , wherein the scavenger is the tricarbonyl compound and selected from the group consisting of glycerol triacetate; triethyl 1, 1, 2-ethanetricarboxylate; triethyl citrate, and tributyl citrate.

13. An aviation fuel additive composition as described in claim 9 , wherein the scavenger compound is a plurality of phosphorus-containing compounds.

14. An aviation fuel additive composition as described in claim 9 , wherein the scavenger compound comprises phosphorus-containing compound and a tricarbonyl compound.

15. A method of reducing manganese-containing deposits resulting from the combustion of an aviation fuel including a cyclopentadienyl manganese tricarbonyl in an aviation fuel engine, the method comprising the steps of:
providing a scavenger selected from triphenyl phosphine oxide, triphenyl phosphine, and tricarbonyl compounds;
mixing the scavenger with a substantially lead-free aviation fuel composition, wherein the aviation fuel composition further comprises a cyclopentadienyl manganese tricarbonyl; and
combusting the fuel composition and scavenger mixture in an aviation, spark ignition engine;
wherein the combustion results in less manganese-containing engine deposits than the combustion of a fuel composition without a scavenger in a comparable engine.

16. A method of reducing manganese-containing deposits as claimed in claim 15 , wherein the manganese-containing deposits that are formed during combustion are different from the manganese-containing deposits that are formed during the combustion of a fuel composition without a scavenger.

17. A method of reducing manganese-containing deposits as claimed in claim 15 , wherein the manganese-containing deposits are formed on engine components selected from the group consisting of spark plugs, intake valves, exhaust valves, and combustion chambers.

18. An aviation fuel additive composition as described in claim 1 , wherein the manganese scavenger compound is triphenyl phosphine oxide, triphenyl phosphine, or mixtures thereof.

19. An aviation fuel additive composition as described in claim 9 , wherein the scavenger is triphenyl phosphine oxide, triphenyl phosphine, or mixtures thereof.

20. A method of reducing manganese-containing deposits resulting from the combustion of an aviation fuel including a cyclopentadienyl manganese tricarbonyl in an aviation fuel engine as described in claim 15 , wherein the scavenger is triphenyl phosphine oxide, triphenyl phosphine, or mixtures thereof.

21. The aviation fuel additive composition as described in claim 1 , wherein the manganese scavenger compound is the tricarbonyl compound and selected from glycerol triacetate, triethyl 1, 1,2-ethanetricarboxylate, and mixtures thereof.

22. The aviation fuel additive composition as described in claim 9 , wherein the scavenger is the tricarbonyl compound and selected from glycerol triacetate, triethyl 1, 1,2-ethanetricarboxylate, and mixtures thereof.

23. The aviation fuel additive composition as described in claim 22 , wherein an amount of the tricarbonyl compound relative to an amount of manganese in the aviation fuel additive is from about 1:0.05 to 1:10 mass ratio of manganese to tricarbonyl.

Assignees

• Afton Chemical Corp

Inventors

• McAfee Zachary John
• Calderone Iii Joseph Anthony

Classifications

• C10L10/10

  for improving the octane number · CPC title

• C10L1/223

  having at least one amino group bound to an aromatic carbon atom {(C10L1/221, C10L1/2227 take precedence)} · CPC title

• C10L2230/22

  for improving fuel economy or fuel efficiency · CPC title

• C10L1/2641

  oxygen bonds only · CPC title

• C10L1/14 Primary

  Organic compounds · CPC title