Process for producing LPG and BTX

Patent metadata

Field	Value
Publication number	US-10087378-B2
Application number	US-201515538391-A
Country	US
Kind code	B2
Filing date	Dec 15, 2015
Priority date	Dec 22, 2014
Publication date	Oct 2, 2018
Grant date	Oct 2, 2018

Abstract

The invention relates to a process for producing LPG and BTX, comprising a) subjecting a mixed hydrocarbon stream to first hydrocracking in the presence of a first hydrocracking catalyst to produce a first hydrocracking product stream; b) separating the first hydrocracking product stream to provide at least a light hydrocarbon stream comprising at least C2 and C3 hydrocarbons, a middle hydrocarbon stream consisting of C4 and/or C5 hydrocarbons and a heavy hydrocarbon stream comprising at least C6+ hydrocarbons and c) subjecting the heavy hydrocarbon stream to second hydrocracking in the presence of a second hydrocracking catalyst to produce a second hydrocracking product stream comprising BTX, wherein the second hydrocracking is more severe than the first hydrocracking, d) wherein at least part of the middle hydrocarbon stream is subjected to C4 hydrocracking optimized for converting C4 hydrocarbons into C3 hydrocarbons in the presence of a C4 hydrocracking catalyst to produce a C4 hydrocracking product stream.

First claim

The invention claimed is:

1. A process for producing LPG and BTX, comprising
a) subjecting a mixed hydrocarbon stream to first hydrocracking in the presence of a first hydrocracking catalyst to produce a first hydrocracking product stream;
b) separating the first hydrocracking product stream to provide at least
a light hydrocarbon stream comprising at least C2 and C3 hydrocarbons,
a middle hydrocarbon stream consisting of C4 and/or C5 hydrocarbons and
a heavy hydrocarbon stream comprising at least C6+ hydrocarbons and
c) subjecting the heavy hydrocarbon stream to second hydrocracking in the presence of a second hydrocracking catalyst to produce a second hydrocracking product stream comprising BTX, wherein the second hydrocracking is more severe than the first hydrocracking,
wherein at least part of the middle hydrocarbon stream is subjected to C4 hydrocracking optimized for converting C4 hydrocarbons into C3 hydrocarbons in the presence of a C4 hydrocracking catalyst to produce a C4 hydrocracking product stream.

2. The process according to claim 1 , wherein the C4 hydrocracking catalyst comprises a mordenite or an erionite.

3. The process according to claim 1 , wherein the C4 hydrocracking catalyst consists of a mordenite and an optional binder or comprises sulfided-nickel/H-Erionite1 and the C4 hydrocracking is performed under conditions comprising a temperature between 325 and 450° C., a partial hydrogen pressure between 2 and 4 MPa, a molar ratio hydrogen to hydrocarbon feed of 2:1 to 8:1, wherein the number of moles of the hydrocarbon feed is based on the average molecular weight of the hydrocarbon feed and a VVH of 0.5 to 5 h −1 .

4. The process according to claim 1 , wherein the second hydrocracking product stream is substantially free from non-aromatic C6+ hydrocarbons.

5. The process according to claim 1 , wherein the second hydrocracking is performed using a hydrocracking catalyst comprising 0.01-1 wt-% hydrogenation metal in relation to the total catalyst weight and a zeolite having a pore size of 5-8 Å and a silica (SiO2) to alumina (Al2O3) molar ratio of 5-200 under conditions comprising a temperature of 300-580° C., a pressure of 0.3-5 MPa gauge and a Weight Hourly Space Velocity (WHSV) of 0.1-15 h −1 .

6. The process according to claim 1 , wherein the C4 hydrocracking product stream is recycled back to the separation of step b).

7. The process according to claim 1 , wherein step b) involves separating between the C4 hydrocarbons of the middle hydrocarbon stream and the C5 hydrocarbons of the middle hydrocarbon stream and wherein the C4 hydrocarbons of the middle hydrocarbon stream is subjected to the C4 hydrocracking and the C5 hydrocarbons of the middle hydrocarbon stream is recycled back to the first hydrocracking in step a).

8. The process according to claim 1 , wherein the mixed hydrocarbon feedstream comprises a naphtha or a naphtha-like product.

9. The process according to claim 1 , wherein H2 or H2 and C1 hydrocarbon is separated from the first hydrocracking product stream before the separation between the light, middle and heavy hydrocarbon streams.

10. The process according to claim 1 , wherein the separation between the light hydrocarbon stream and the middle hydrocarbon stream is performed to separate between C3 hydrocarbon and iC4 hydrocarbon, between iC4 hydrocarbon and nC4 hydrocarbon or between nC4 hydrocarbon and C5 hydrocarbon.

11. The process according to claim 1 , wherein the separation between the middle hydrocarbon stream and the heavy hydrocarbon stream is performed to separate between nC4 hydrocarbon and C5 hydrocarbon or between C5 hydrocarbon and C6 hydrocarbon.

12. The process according to claim 1 , wherein at least part of non-recycled C4 hydrocarbon from the middle hydrocarbon stream is subjected to a further step selected from the group consisting of isomerization, butane dehydrogenation (non-oxidative and oxidative), reaction with methanol and reaction with ethanol and combinations thereof.

13. The process according to claim 1 , wherein C4− hydrocarbon in the second hydrocracking product stream is separated from the second hydrocracking product stream to be recycled back to the separation of step b) or combined with the light hydrocarbon stream.

14. The process according to claim 1 , wherein the amount of methane in the first hydrocracking product stream is at most 5 wt %.

15. The process according to claim 1 , wherein the amount of the C4 and C5 hydrocarbons in the at least part of the middle hydrocarbon stream is at least 70 wt % and the amount of the C2-C3 hydrocarbons in the C4 hydrocracking product stream is at least 60 wt %.

16. The process according to claim 5 , wherein the temperature is 425-580° C.

17. The process according to claim 8 , wherein the mixed hydrocarbon feedstream has a boiling point range of 20-200° C.

Assignees

• Sabic Global Technologies Bv

Inventors

• Oprins Arno Johannes Maria
• Ward Andrew Mark
• Davies Andrew P
• Wong Kae Shin
• Aramburo Luis
• Van Iersel Maikel

Classifications

• B01D11/00

  Solvent extraction · CPC title

• C10G65/10 Primary

  including only cracking steps · CPC title

• C10G2400/28

  Propane and butane · CPC title

• C10G65/18 Primary

  including only cracking steps · CPC title

• C10G2400/26

  Fuel gas · CPC title