Functionalized rubber composition

Patent metadata

Field	Value
Publication number	US-10087314-B2
Application number	US-201615199250-A
Country	US
Kind code	B2
Filing date	Jun 30, 2016
Priority date	Dec 26, 2014
Publication date	Oct 2, 2018
Grant date	Oct 2, 2018

Abstract

Rubber compositions having a modified rubber component selected from a modified polybutadiene rubber, a modified styrene-butadiene rubber, or combinations thereof, the modification being with a functional group having a hydrogen bond acceptor atom. Such functional group may be selected from a pyridine, a pyrrolidone, an ether, a ketone or an epoxide, the rubber composition having a Tg of between −80° C. and −110° C.
The rubber composition may include an efficient plasticizing resin, which when included in a mixture consisting of the modified rubber component and 67 phr of the efficient plasticizing resin, causes a Tg of the mixture to be at least 14° C. higher than the Tg of the modified rubber component. The rubber composition may described as having the hydrogen bond acceptor atom located at least two covalent bond lengths or alternatively three covalent bond lengths from a backbone of the modified rubber component.

First claim

What is claimed is:

1. A rubber composition that is based upon a cross-linkable elastomer composition, the cross-linkable elastomer composition comprising, per 100 parts by weight of rubber (phr):
a rubber component that is a modified rubber component selected from the group consisting of a modified polybutadiene rubber, a modified styrene-butadiene rubber and combinations thereof, wherein the modified rubber component has been modified with a functional group having a hydrogen bond acceptor atom, the functional group selected from the group consisting of a pyridine, a pyrrolidone, an ether, a ketone, a sulfone and an epoxide and wherein the modified rubber component has a Tg of between −80° C. and −110° C., wherein the hydrogen bond acceptor atom is located at least two covalent bond lengths from a backbone of the modified rubber component;
between 30 phr and 130 phr of an efficient plasticizing resin, wherein the efficient plasticizing resin is, when included in a mixture consisting of the modified rubber component and 67 phr of the efficient plasticizing resin, causes a Tg of the mixture to be at least 14° C. higher than the Tg of the modified rubber component and wherein the efficient plasticizing resin has a hydrogen bond donor group;
a reinforcement filler; and
a curing system.

2. The rubber composition of claim 1 , wherein the functional group selected from the group consisting of a pyridine, a pyrrolidone, a cyclic ether and a cyclic ketone.

3. The rubber composition of claim 1 , wherein the functional group is selected from the group consisting of a non-cyclic ketone and a sulfone.

4. The rubber composition of claim 1 , wherein the hydrogen bond acceptor atom is located at least three covalent bond lengths from the backbone of the modified rubber component.

5. The rubber composition of claim 1 , wherein the functional group is an epoxide.

6. The rubber composition of claim 1 , wherein the functional group content of the modified rubber component is between 3 mol % and 18 mol %.

7. The rubber composition of claim 1 , wherein the modified rubber component is the modified styrene-butadiene rubber.

8. The rubber composition of claim 1 , wherein the rubber composition further comprises between 0 phr and 30 phr of a second rubber component that is a highly unsaturated diene elastomer.

9. The rubber composition of claim 8 , wherein the second rubber component is selected from the group consisting of a polybutadiene rubber (BR), a styrene-butadiene rubber (SBR) and combinations thereof.

10. The rubber composition of claim 1 , wherein the amount of the modified rubber component is between 10 phr and 95 phr.

11. The rubber composition of claim 9 , wherein the second rubber component is BR.

12. The rubber composition of claim 1 , wherein a Tg of the rubber composition is between −35° C. and 0° C.

13. The rubber composition of claim 1 , wherein the efficient plasticizing resin is a terpene phenolic resin.

14. The rubber composition of claim 1 , wherein the efficient plasticizing resin is a coumarone-indene resin.

15. A tire tread, comprising at least in part the rubber composition of claim 1 .

16. A rubber composition that is based upon a cross-linkable elastomer composition, the cross-linkable elastomer composition comprising, per 100 parts by weight of rubber (phr):
a rubber component that is a modified rubber component selected from the group consisting of a modified polybutadiene rubber, a modified styrene-butadiene rubber and combinations thereof, wherein the modified rubber component has been modified with a functional group having a hydrogen bond acceptor atom, the functional group selected from the group consisting of a non-cyclic ketone, a sulfone and combinations thereof and wherein the modified rubber component has a Tg of between −80° C. and −110° C.;
between 30 phr and 130 phr of an efficient plasticizing resin, wherein the efficient plasticizing resin is, when included in a mixture consisting of the modified rubber component and 67 phr of the efficient plasticizing resin, causes a Tg of the mixture to be at least 14° C. higher than the Tg of the modified rubber component and wherein the efficient plasticizing resin has a hydrogen bond donor group;
a reinforcement filler; and
a curing system.

17. The rubber composition of claim 16 , wherein the hydrogen bond acceptor atom is located at least two covalent bond lengths from a backbone of the modified rubber component.

18. The rubber composition of claim 16 , wherein the functional group content of the modified rubber component is between 3 mol % and 18 mol %.

19. The rubber composition of claim 16 , wherein the rubber composition further comprises between 0 phr and 30 phr of a second rubber component that is a highly unsaturated diene elastomer.

20. The rubber composition of claim 19 , wherein the second rubber component is selected from the group consisting of a polybutadiene rubber (BR), a styrene-butadiene rubber (SBR) and combinations thereof.

21. A tire tread, comprising at least in part the rubber composition of claim 16 .

Assignees

• Michelin & Cie

Inventors

• Khripin Constantine
• Munch Etienne
• Salit Anne-Frédérique Salit
• Mcdowell Jessica
• Saintigny Xavier

Classifications

• C08L15/00 Primary

  Compositions of rubber derivatives (C08L11/00, C08L13/00 take precedence) · CPC title

• C08L2205/035

  containing four or more polymers in a blend · CPC title

• C08L93/00

  Compositions of natural resins; Compositions of derivatives thereof (of polysaccharides C08L1/00 - C08L5/00; of natural rubber C08L7/00) · CPC title

• C08J3/18

  Plasticising macromolecular compounds (plasticisers C08K) · CPC title

• C08J2309/06

  Copolymers with styrene · CPC title