Method of producing a cable comprising a multimodal ethylene copolymer

Patent metadata

Field	Value
Publication number	US-10087296-B2
Application number	US-201514931398-A
Country	US
Kind code	B2
Filing date	Nov 3, 2015
Priority date	Oct 31, 2008
Publication date	Oct 2, 2018
Grant date	Oct 2, 2018

Abstract

The present invention relates to a cable comprising a conductor surrounded by one or more layers, wherein at least one layer comprises a polymer composition comprising a copolymer of ethylene with one or more comonomers, to a process for producing the cable and to a polymer composition suitable as a cable layer material.

First claim

The invention claimed is:

1. A process for producing a cable comprising:
applying two or more layers on a conductor thereby forming the cable, wherein the two or more layers include an insulation layer and an outermost jacketing layer,
wherein the outermost jacketing layer comprises a multimodal copolymer of ethylene with one or more comonomers and wherein the multimodal copolymer of ethylene with one or more comonomers is obtained by
polymerising ethylene and one or more comonomers in the presence of a single site catalyst (SSC) and an activator for said catalyst, wherein the multimodal copolymer of ethylene has a density of less than 945 kg/m 3 , an Mw/Mn of 2.5 to 10, and an Mz/Mw of at least 2.45.

2. The process according to claim 1 , wherein the multimodal copolymer of ethylene has the Mz/Mw of from 2.55 to 15.00.

3. The process according to claim 1 , wherein the multimodal copolymer of ethylene has a shear thinning index SHI 2.7/210 of at least 7.0.

4. The process according to claim 1 , wherein the multimodal copolymer of ethylene has a Mz of at least 250 000.

5. The process according to claim 1 , wherein the multimodal copolymer of ethylene comprises:
(A) from 30 to 70% by weight, based on the combined amount of components (A) and (B), of a low molecular weight (LMW) SSC derived ethylene polymer selected from ethylene homopolymer and a copolymer of ethylene and one or more alpha-olefins having from 3 to 20 carbon atoms, and
(B) from 30 to 70% by weight, based on the combined amount of components (A) and (B), of a high molecular weight (HMW) SSC derived copolymer of ethylene and one or more alpha-olefins having from 3 to 20 carbon atoms.

6. The process according to claim 5 , wherein the LMW SSC derived polymer (A) is a copolymer of ethylene with one or more alpha-olefins having from 4 to 10 carbon atoms, and the HMW SSC derived copolymer of ethylene (B) is a copolymer of ethylene with one or more alpha-olefins having from 4 to 10 carbon atoms.

7. The process according to claim 1 , wherein the multimodal copolymer of ethylene comprises a low molecular weight copolymer of ethylene (A) which is obtained by polymerising ethylene in the presence of a single site catalyst (SSC) and an activator for said catalyst, and a high molecular weight copolymer of ethylene (B) which is obtained by polymerising ethylene in the presence of a single site catalyst (SSC) and an activator for said catalyst.

8. The process according to claim 1 , wherein the multimodal copolymer of ethylene has at least one of the following properties:
(i) MWD (Mw/Mn) of from 4.5 to 10.0,
(ii) Density of from 905 to 925 kg/m 3 ,
(iii) Flexural modulus of less than 750 MPa,
(iv) MFR 2 of from 0.1 to 10.0 g/10 min, or
(v) The multimodal copolymer of ethylene is the LMW polymer (A) which has a density of less than 945 g/m 3 .

9. The process according to claim 8 , wherein the multimodal copolymer of ethylene has all the properties (i) to (iv).

10. The process of claim 1 , wherein the jacketing layer is applied by coextrusion.

11. The process according to claim 1 , wherein the jacketing layer is crosslinkable.

Assignees

• Borealis Ag
• Boreaus Ag

Inventors

• Ek Carl-Gustav
• Pakkanen Anneli
• Dix Albrecht
• Steffl Thomas
• Buryak Andrey

Classifications

• H01B3/44

  vinyl resins; acrylic resins (silicones H01B3/46) · CPC title

• C08L2205/02

  containing two or more polymers of the same C08L -group · CPC title

• C08F4/65912

  in combination with an organoaluminium compound · CPC title

• H01B13/14

  by extrusion {(extrusion in general B29C48/00)} · CPC title

• C08L23/08

  Copolymers of ethene (C08L23/16 takes precedence) · CPC title