Reactive composite foil

Patent metadata

Field	Value
Publication number	US-10087118-B2
Application number	US-201514954508-A
Country	US
Kind code	B2
Filing date	Nov 30, 2015
Priority date	Nov 28, 2014
Publication date	Oct 2, 2018
Grant date	Oct 2, 2018

Abstract

A reactive composite foil, including metallic fuel particles, oxidizer particles, and a diluent, which, when ignited, produces a self-propagating thermite reaction to produce a molten metal.

First claim

The invention claimed is:

1. A reactive composite foil, comprising:
a reactant powder comprising a plurality of metallic fuel particles and a plurality of oxidizer particles; and
a diluent,
wherein an average particle size of the plurality of metallic fuel particles and the plurality of oxidizer particles is less than 200 μm in diameter,
wherein, the reactive composite foil produces a thermite reaction to produce a molten metal when ignited,
wherein, the reactive composite foil has a first mass before the thermite reaction and a second mass after the thermite reaction, and
wherein, the diluent reduces an amount of gas during the thermite reaction, such that when ignited in an inert environment, the second mass is less than the first mass by 5% or less.

2. The reactive composite foil of claim 1 , wherein the diluent is configured to act as a heat sink to reduce a maximum reaction temperature of the thermite reaction.

3. The reactive composite foil of claim 1 , wherein thermite reaction is a self-propagating thermite reaction.

4. The reactive composite foil of claim 1 , wherein the reactive composite foil is configured to bond two materials via the thermite reaction without requiring pre-wetting or metallization of the materials to be bonded.

5. The reactive composite foil of claim 1 , wherein a thickness of the reactive composite foil is between 50 μm and 1500 μm.

6. The reactive composite foil of claim 1 , wherein, when ignited in an inert environment, the second mass is less than the first mass by 0.5% or less.

7. The reactive composite foil of claim 1 , wherein the plurality of oxidizer particles include metal oxides, and the diluent comprises the metal of said metal oxides.

8. The reactive composite foil of claim 1 , wherein the reactant powder comprises a plurality of composite particles formed of milled metallic fuel particles and oxidizer particles.

9. The reactive composite foil of claim 1 , wherein the plurality of oxidizer particles comprise a plurality of partially pre-oxidized (PPO) metal particles, the PPO metal particles comprising a metal and a metal oxide surrounding the metal.

10. The reactive composite foil of claim 9 , wherein the metal oxide of the PPO metal particles completely surrounds the metal of the PPO metal particles.

11. The reactive composite foil of claim 1 , further comprising a metallic clad layer.

12. The reactive composite foil of claim 11 , wherein, when the reactive composite foil is used to bond materials, the metallic clad layer is configured to wet the materials to be bonded and to act as a braze.

13. The reactive composite foil of claim 1 ,
wherein an average spacing between the metallic fuel particles and the oxidizer particles is less than 10 μm, and
wherein an average distance between the diluent and the reactant powder is less than 100 μm.

14. The reactive composite foil of claim 1 ,
wherein an average particle size of at least one of the plurality of metallic fuel particles and the plurality of oxidizer particles is less than 100 μm in diameter,
wherein an average spacing between the metallic fuel particles and the oxidizer particles is less than 5 μm,
wherein an average distance between the diluent and the reactant powder is less than 30 wherein a thickness of the reactive composite foil is between 50 μm and 800 μm, and
wherein, when ignited in an inert environment, the second mass is less than the first mass by 0.1% or less.

15. A reactive composite foil, comprising:
a reactant powder comprising a plurality of metallic fuel particles and a plurality of oxidizer particles; and
a diluent in an amount sufficient to reduce gas produced by a thermite reaction,
wherein an average spacing between the metallic fuel particles and the oxidizer particles is less than 10 μm,
wherein an average distance between the diluent and the reactant powder is less than 100 μm, and
wherein, the reactive composite foil produces the thermite reaction to produce a molten metal when ignited.

16. The reactive composite foil of claim 15 ,
wherein an average particle size of at least one of the plurality of metallic fuel particles and the plurality of oxidizer particles is less than 100 μm in diameter,
wherein the average spacing between the metallic fuel particles and the oxidizer particles is less than 5 μm,
wherein the average distance between the diluent and the reactant powder is less than 30 wherein a thickness of the reactive composite foil is between 50 μm and 800 μm,
wherein, the reactive composite foil has a first mass before the thermite reaction and a second mass after the thermite reaction, and
wherein, when ignited in an inert environment, the second mass is less than the first mass by 1% or less.

17. The reactive composite foil of claim 15 , wherein the diluent is configured to act as a heat sink to reduce a maximum reaction temperature of the thermite reaction of the reactive composite foil.

18. The reactive composite foil of claim 15 , wherein the plurality of oxidizer particles comprise a plurality of partially pre-oxidized (PPO) metal particles, the PPO metal particles comprising a metal and a metal oxide surrounding the metal.

Assignees

• Univ Johns Hopkins

Inventors

• Weihs Timothy P
• Kinsey Alex H
• Slusarski Kyle A
• Woll Karsten
• Gibbins David

Classifications

• C06B33/00 Primary

  Compositions containing particulate metal, alloy, boron, silicon, selenium or tellurium with at least one oxygen supplying material which is either a metal oxide or a salt, organic or inorganic, capable of yielding a metal oxide · CPC title

• B23K35/0238

  layered · CPC title

• B23K35/3033

  Ni as the principal constituent · CPC title

• B23K35/325

  Ti as the principal constituent · CPC title

• C06B21/0033

  Shaping the mixture · CPC title