Binder, method for manufacturing same and method for manufacturing casting sand mold
US-11932732-B2 · Mar 19, 2024 · US
US10086532B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10086532-B2 |
| Application number | US-201515305770-A |
| Country | US |
| Kind code | B2 |
| Filing date | Apr 28, 2015 |
| Priority date | May 15, 2014 |
| Publication date | Oct 2, 2018 |
| Grant date | Oct 2, 2018 |
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The present invention relates to a fiber board product comprising fibers in an amount from 50.0 to 99.0 parts by weight (d/d), at least one particulate calcium carbonate-containing material in an amount from 1.0 to 50.0 parts by weight (d/d), at least one binder in an amount from 0.05 to 25.0 parts by weight (d/d), at least one wax in an amount from 0 to 5.0 parts by weight (d/d), wherein the sum of the fibers and the at least one particulate calcium carbonate-containing material is 100.0 parts by weight (d/d), a process for manufacturing such a fiber board product as well as an use of at least one particulate calcium carbonate-containing material having a weight median particle size d 50 of 0.5 to 150.0 μm as fiber replacement in a fiber board product, preferably in a high-density fiber (HDF) board, medium-density fiber (MDF) board, low-density fiber (LDF) board or particle board.
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The invention claimed is: 1. A fiber board product comprising a) fibers in an amount from 50.0 to 99.0 parts by weight (d/d), based on the total dry weight of the fibers and at least one particulate calcium carbonate-containing material, wherein the fibers in an amount of i) 0 to 20.0 wt.-%, based on the total amount of dry fibers, are of a size which is fractioned at a mesh sieve width of 0.05 mm, ii) 50.0 to 90.0 wt.-%, based on the total amount of dry fibers, are of a size which is fractioned at a mesh sieve width of 1.0 mm, and iii) 70.0 to 100.0 wt.-%, based on the total amount of dry fibers, are of a size which is fractioned at a mesh sieve width of 3.0 mm, as determined by sieve analysis, b) at least one particulate calcium carbonate-containing material in an amount from 1.0 to 50.0 parts by weight (d/d), based on the total dry weight of the fibers and the at least one particulate calcium carbonate-containing material, the at least one particulate calcium carbonate-containing material having a weight median particle size d 50 of 0.5 to 150.0 μm, c) at least one binder in an amount from 0.05 to 25.0 parts by weight (d/d), based on the total dry weight of the fibers and the at least one particulate calcium carbonate-containing material, and d) at least one wax in an amount from 0 to 5.0 parts by weight (d/d), based on the total dry weight of the fibers and the at least one particulate calcium carbonate-containing material, wherein the sum of the amount of the fibers and the at least one particulate calcium carbonate-containing material is 100.0 parts by weight (d/d), based on the total dry weight of the fibers and the at least one particulate calcium carbonate-containing material. 2. The fiber board product according to claim 1 , wherein the at least one particulate calcium carbonate-containing material is selected from the group consisting of dolomite, at least one ground calcium carbonate (GCC), at least one precipitated calcium carbonate (PCC), and any mixture thereof. 3. The fiber board product according to claim 1 , wherein the at least one particulate calcium carbonate-containing material is ground calcium carbonate (GCC) selected from the group consisting of marble, chalk, limestone, and any mixture thereof. 4. The fiber board product according to claim 1 , wherein the at least one particulate calcium carbonate-containing material is d precipitated calcium carbonate (PCC) comprising one or more of aragonitic, vateritic and calcitic mineralogical crystal forms. 5. The fiber board product according to claim 1 , wherein the at least one particulate calcium carbonate-containing material has a) a weight median particle size d 50 from 0.7 μm to 100.0 μm, and/or b) a specific surface area of from 0.5 to 200.0 m 2 /g, as measured by the BET nitrogen method. 6. The fiber board product according to claim 1 , wherein the at least one particulate calcium carbonate-containing material has a) a weight median particle size d 50 from 1.0 μm to 50.0 μm, and/or b) a specific surface area of from 0.5 to 100.0 m 2 /g, as measured by the BET nitrogen method. 7. The fiber board product according to claim 1 , wherein the at least one particulate calcium carbonate-containing material has a) a weight median particle size d 50 from 2.1 μm to 40.0 μm, and/or b) a specific surface area of from 0.5 to 50.0 m 2 /g, as measured by the BET nitrogen method. 8. The fiber board product according to claim 1 , wherein the at least one particulate calcium carbonate-containing material consists of calcium carbonate in an amount of ≥50.0 wt.-%, based on the total dry weight of the calcium carbonate-containing material. 9. The fiber board product according to claim 1 , wherein the at least one particulate calcium carbonate-containing material consists of calcium carbonate in an amount of ≥90.0 wt.-%, based on the total dry weight of the calcium carbonate-containing material. 10. The fiber board product according to claim 1 , wherein the at least one particulate calcium carbonate-containing material consists of calcium carbonate in an amount of ≥95.0 wt.-%, based on the total dry weight of the calcium carbonate-containing material. 11. The fiber board product according to claim 1 , wherein the at least one particulate calcium carbonate-containing material consists of calcium carbonate in an amount of ≥97.0 wt.-%, based on the total dry weight of the calcium carbonate-containing material. 12. The fiber board product according to claim 1 , wherein the fibers originate from softwood tree species, hardwood tree species, non-wood fiber plants, and any mixture thereof. 13. The fiber board product according to claim 1 , wherein the fiber board product comprises a fiber material consisting of the fibers and the at least one particulate calcium carbonate-containing material having a weight fraction of fibers in said fiber material from 99.0 to 50.0 wt.-%, based on the total dry weight of the fibers and the at least one particulate calcium carbonate-containing material. 14. The fiber board product according to claim 1 , wherein the fiber board product comprises a fiber material consisting of the fibers and the at least one particulate calcium carbonate-containing material having a weight fraction of fibers in said fiber material from 99.0 to 75.0 wt.-%, based on the total dry weight of the fibers and the at least one particulate calcium carbonate-containing material. 15. The fiber board product according to claim 1 , wherein the fiber board product comprises a fiber material consisting of the fibers and the at least one particulate calcium carbonate-containing material having a weight fraction of fibers in said fiber material from 99.0 to 80.0 wt.-%, based on the total dry weight of the fibers and the at least one particulate calcium carbonate-containing material. 16. The fiber board product according to claim 1 , wherein the fiber board product comprises a fiber material consisting of the fibers and the at least one particulate calcium carbonate-containing material having a weight fraction of fibers in said fiber material from 97.0 to 88.0 wt.-%, based on the total dry weight of the fibers and the at least one particulate calcium carbonate-containing material. 17. The fiber board product according to claim 1 , wherein the fiber board product comprises the fibers in an amount from 75.0 to 99.0 parts by weight (d/d) and the at least one particulate calcium carbonate-containing material in an amount from 1.0 to 25.0 parts by weight (d/d), based on the total dry weight of the fibers and the at least one particulate calcium carbonate-containing material. 18. The fiber board product according to claim 1 , wherein the at least one binder is selected from the group consisting of phenol-formaldehyde resin (PF), urea-formaldehyde resin (UF), melamine-formaldehyde resin (MF), melamine-urea-formaldehyde resin (MUF), urea-melamine-formaldehyde resin (UMF), urea-melamine-phenol-formaldehyde resin (UMPF), epoxy resin, methylene diphenyl diisocyanate resin (MDI), polyurethane resin (PU), and any mixture thereof. 19. The fiber board product according to claim 1 , wherein the fiber board product further comprises at least one compound selected from the group consisting of colorants, filler, dispersants, biocides, hardener, and flame retardants. 20. The fiber board product according to claim 1 , wherein the fiber board product has a density from 35 to 1100 kg/m 3 , and/or a thickness from 1.0 to 300.0 mm. 21. The fiber board product according to claim 1 , wh
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