Method of preparing shape-controlled platinum based alloys

Patent metadata

Field	Value
Publication number	US-10086434-B2
Application number	US-201615084731-A
Country	US
Kind code	B2
Filing date	Mar 30, 2016
Priority date	Mar 30, 2016
Publication date	Oct 2, 2018
Grant date	Oct 2, 2018

Abstract

A method of preparing shape-controlled alloy particles includes dissolving a solvent in a surfactant selected to inhibit particle growth; adding a noble metal precursor and a transition metal precursor to form a mixture; irradiating the mixture with a microwave under reflux for about thirty minutes or less at an irradiation temperature of between 185° C. and 195° C.; cooling the mixture; and drying the mixture at a temperature of between 55° C. and 65° C. to obtain shape-controlled alloy particles having a uniform shape, the shape dependent upon the surfactant used.

First claim

What is claimed is:

1. A method of preparing shape-controlled alloy particles comprising:
dissolving a solvent in a surfactant selected to inhibit particle growth;
adding a noble metal precursor and a transition metal precursor to form a mixture;
irradiating the mixture with a microwave under reflux for about thirty minutes or less at an irradiation temperature of between 185° C. and 195° C.;
cooling the mixture; and
drying the mixture at a temperature of between 55° C. and 65° C. to obtain shape-controlled alloy particles having a uniform shape, the shape dependent upon the surfactant used.

2. The method of claim 1 , wherein the surfactant is benzoic acid, the solvent is benzyl alcohol, the noble metal precursor is platinum(II) acetylacetonate and the transition metal precursor is nickel(II) acetylacetonate.

3. The method of claim 2 wherein the shape-controlled alloy particles have an octahedral shape.

4. The method of claim 1 , wherein the solvent is 1,2-hexadecanediol, the surfactant is oleylamine, the noble metal precursor is platinum(II) acetylacetonate and the transition metal precursor is cobalt(II) acetylacetonate or dicobalt octacarbonyl.

5. The method of claim 4 , wherein the shape-controlled alloy particles have an octahedral shape.

6. The method of claim 1 , wherein the surfactant is aniline, the solvent is benzyl alcohol and the shape-controlled alloy particles have a truncated octahedral shape.

7. The method of claim 1 , wherein the surfactant is potassium bromide, the solvent is benzyl alcohol and the shape-controlled alloy particles have a cubic shape.

8. The method of claim 1 , further comprising:
filtering the mixture and washing the mixture with ethanol and acetone prior to drying.

9. A method of preparing shape-controlled platinum alloy particles comprising:
thoroughly dissolving benzyl alcohol in a surfactant selected to inhibit particle growth;
adding a platinum precursor and a nickel precursor to form a mixture;
irradiating the mixture with a microwave under reflux for about thirty minutes or less at an irradiation temperature of between 185° C. and 195° C.;
cooling the mixture; and
drying the mixture at a temperature of between 55° C. and
65° C. to obtain shape-controlled platinum alloy particles.

10. The method of claim 9 , further comprising:
filtering the mixture and washing the mixture with ethanol and acetone prior to drying.

11. The method of claim 9 , wherein the surfactant is benzoic acid and the shapecontrolled alloy particles have an octahedral shape.

12. The method of claim 9 , wherein the surfactant is aniline and the shapecontrolled alloy particles have a truncated octahedral shape.

13. The method of claim 1 , wherein the surfactant is potassium bromide and the shape-controlled alloy particles have a cubic shape.

Assignees

• Nissan North America Inc

Inventors

• Liu Ying
• Dale Nilesh

Classifications

• B22F2202/11

  Use of irradiation · CPC title

• B22F2301/15

  Nickel or cobalt · CPC title

• B22F2009/245

  Reduction reaction in an Ionic Liquid [IL] · CPC title

• B22F9/30 Primary

  with decomposition of metal compounds, e.g. by pyrolysis · CPC title

• B22F1/0007

  Operations & Transport · mapped topic